The present disclosure relates to an optical fiber comprising a glass fiber including a core and a clad; a primary resin layer that coats the glass fiber by being in contact with the glass fiber; and a secondary resin layer that coats the primary resin layer, in which the secondary resin layer is formed from a cured product of a resin composition that includes a base resin containing a urethane (meth)acrylate oligomer, a monomer, and a photopolymerization initiator; and inorganic oxide particles, a volume average particle size of the inorganic oxide particles as measured by a small angle X-ray scattering method is 800 nm or less, and a standardized dispersion of the volume average particle size is 60% or less.

The present disclosure relates to an optical fiber comprising a glass fiber including a core and a clad; a primary resin layer that coats the glass fiber by being in contact with the glass fiber; and a secondary resin layer that coats the primary resin layer, in which the secondary resin layer is formed from a cured product of a resin composition that includes a base resin containing a urethane (meth)acrylate oligomer, a monomer, and a photopolymerization initiator; and inorganic oxide particles, a volume average particle size of the inorganic oxide particles as measured by a small angle X-ray scattering method is 800 nm or less, and a standardized dispersion of the volume average particle size is 60% or less.

An adhesive resin and an adhesive composition for an optical member including the same is provided. The adhesive resin includes an acrylic copolymer formed by polymerizing a monomer mixture including a monomer represented by [Formula 1], a (meth)acrylic monomer having a cross-linkable functional group, and an alkyl (meth)acrylate-based monomer.

The present application relates to the technical field of floor surface decoration materials, and particularly provides a multi-coating radiation-cured pre-coating film and a preparation method therefor. The first aspect of the present application provides the multi-coating radiation-cured pre-coating film, which sequentially comprises a flexible transparent film layer and a radiation-cured coating from bottom to top, wherein the radiation-cured coating sequentially comprises a radiation-cured elastic primer layer and a radiation-cured wear-resistant finish paint layer from bottom to top, the at least one radiation-cured elastic primer layer and the at least one radiation-cured wear-resistant finish paint layer are arranged, and the radiation-cured elastic primer layer equentially comprises a radiation-cured elastic wear-resistant primer layer and a radiation-cured elastic matte/bright primer layer from bottom to top.

The present application relates to the technical field of floor surface decoration materials, and particularly provides a multi-coating radiation-cured pre-coating film and a preparation method therefor. The first aspect of the present application provides the multi-coating radiation-cured pre-coating film, which sequentially comprises a flexible transparent film layer and a radiation-cured coating from bottom to top, wherein the radiation-cured coating sequentially comprises a radiation-cured elastic primer layer and a radiation-cured wear-resistant finish paint layer from bottom to top, the at least one radiation-cured elastic primer layer and the at least one radiation-cured wear-resistant finish paint layer are arranged, and the radiation-cured elastic primer layer equentially comprises a radiation-cured elastic wear-resistant primer layer and a radiation-cured elastic matte/bright primer layer from bottom to top.

The present invention provides alternative polyurethane composition comprising the reaction product of an azidated polyol and a poly(alkynyl carbamate) prepolymer, wherein the poly(alkynyl carbamate) prepolymer comprises the reaction product of a polyisocyanate, an alkynol, and an oxysilane. The reaction of the polyol and the prepolymer may occur in the presence of a catalyst or at a temperature of from 20° C. to 120° C. The inventive oxysilane and azido-alkyne hybrid click formulations provide comparable performance, and in some cases better performance, to/than urethane and azido-alkyne control click formulations in terms of pencil hardness, MEK double rubs, and glass transition temperature. The inventive alternative polyurethane compositions may be used to provide coatings, adhesives, sealants, films, elastomers, castings, and composites.

An alternative polyurethane composition is provided which comprises the reaction product of a poly(alkynyl carbamate) prepolymer and an azidated polyol, wherein reaction occurs without a catalyst at a temperature of from 100° C. to 200° C., or occurs in the presence of a Cu.sup.I-containing catalyst at a temperature of from 20° C. to 140° C. The inventive alternative polyurethane compositions may be used to provide solventborne or waterborne coatings, adhesives, sealants, films, elastomers, castings, foams, and composites.

An alternative polyurethane composition is provided which comprises the reaction product of a poly(alkynyl carbamate) prepolymer and an azidated polyol, wherein reaction occurs without a catalyst at a temperature of from 100° C. to 200° C., or occurs in the presence of a Cu.sup.I-containing catalyst at a temperature of from 20° C. to 140° C. The inventive alternative polyurethane compositions may be used to provide solventborne or waterborne coatings, adhesives, sealants, films, elastomers, castings, foams, and composites.

An alternative polyurethane composition is provided which comprises a reaction product of an azidated polyol and a poly(alkynyl carbamate) prepolymer, wherein reaction occurs at a temperature of from 20° C. to 200° C., optionally in the presence of a Cu.sup.I-containing catalyst and wherein the poly(alkynyl carbamate) prepolymer comprises a reaction product of a polyisocyanate, an alkynol, and a glycol ether, wherein from 1 mol % to 33 mol % of isocyanate groups are reacted with glycol ether and the remaining isocyanate groups are reacted with the alkynol. The inclusion of glycol ethers into the polyisocyanate chain of the poly(alkynyl carbamate) prepolymer at a level of from 1 mol % to 33 mol %, is efficient in reducing the viscosity of the composition without compromising its performance in coatings, adhesives, sealants, films, elastomers, castings, foams, and composites made with the inventive alternative polyurethane compositions.

An alternative polyurethane composition is provided which comprises a reaction product of an azidated polyol and a poly(alkynyl carbamate) prepolymer reacted at a temperature of from 20° C. to 120° C., wherein the poly(alkynyl carbamate) prepolymer comprises a reaction product of a polyisocyanate and a stoichiometric equivalent of an alkynol of the formula (I),

HC≡C—R.sup.1R.sup.2—OH  (I),

and wherein R.sup.1 is an electron-withdrawing group selected from the group consisting of carbonyl, ester, amide, and urethane and R.sup.2 is a linear or branched alkyl chain having from 1 to 15 carbon atoms. The inventive alternative polyurethane composition position may be used to provide adhesives, sealants, films, elastomers, castings, foams, and composites.