Methods of coating a substrate are disclosed. The methods comprise applying shear force to a coating composition either before or during application of the coating composition to the substrate. The coating composition comprises a water-borne or solvent-borne film-forming resin and a catalyst associated with a carrier, wherein at least some of the catalyst can be released from the carrier upon application of the shear force. Also provided are coated articles prepared by the methods.

A coating composition including: an aqueous dispersion of self-crosslinkable core-shell particles, where the core-shell particles include (1) a polymeric core at least partially encapsulated by (2) a polymeric shell having urethane linkages, keto and/or aldo functional groups, and hydrazide functional groups, where the polymeric core is covalently bonded to at least a portion of the polymeric shell, and an acrylic polymer, where the acrylic polymer is non-reactive with the polymeric core and the polymeric shell. A substrate coated with a coating formed from the coating composition and a method of improving stain resistance of a substrate are also disclosed.

A coating composition including: an aqueous dispersion of self-crosslinkable core-shell particles, where the core-shell particles include (1) a polymeric core at least partially encapsulated by (2) a polymeric shell having urethane linkages, keto and/or aldo functional groups, and hydrazide functional groups, where the polymeric core is covalently bonded to at least a portion of the polymeric shell, and an acrylic polymer, where the acrylic polymer is non-reactive with the polymeric core and the polymeric shell. A substrate coated with a coating formed from the coating composition and a method of improving stain resistance of a substrate are also disclosed.

Actinic radiation-curable compositions containing polythiols and urethane/urea-containing polyalkenyl prepolymers that can be used for aerospace coatings and sealants. The coatings can be applied to surfaces and rapidly cured.

Actinic radiation-curable compositions containing polythiols and urethane/urea-containing polyalkenyl prepolymers that can be used for aerospace coatings and sealants. The coatings can be applied to surfaces and rapidly cured.

Described herein are coated optical fibers including an optical fiber portion, wherein the optical fiber portion includes a glass core and cladding section that is configured to possesses certain mode-field diameters and effective areas, and a coating portion including a primary and secondary coating, wherein the primary coating is the cured product of a composition that possesses specified liquid glass transition temperatures, such as below 82 C., and/or a viscosity ratios, such as between 25 C. and 85 C., of less than 13.9. Also described are radiation curable coating compositions possessing reduced thermal sensitivity, methods of coating such radiation curable coating compositions to form coated optical fibers, and optical fiber cables comprising the coated optical fibers and/or radiation curable coating compositions elsewhere described.

Described herein are coated optical fibers including an optical fiber portion, wherein the optical fiber portion includes a glass core and cladding section that is configured to possesses certain mode-field diameters and effective areas, and a coating portion including a primary and secondary coating, wherein the primary coating is the cured product of a composition that possesses specified liquid glass transition temperatures, such as below 82 C., and/or a viscosity ratios, such as between 25 C. and 85 C., of less than 13.9. Also described are radiation curable coating compositions possessing reduced thermal sensitivity, methods of coating such radiation curable coating compositions to form coated optical fibers, and optical fiber cables comprising the coated optical fibers and/or radiation curable coating compositions elsewhere described.

Embodiments relate to a water soluble paint composition for a vehicle. The water soluble paint composition includes a core-shell microgel resin, a dimer-modified polyester resin, a (meth)acryl-modified polyurethane resin, a curing agent, a pigment, and water, wherein the dimer-modified polyester resin is included in an amount of 1 to 10 wt % with respect to 100 wt % of the water-soluble paint composition. When the water soluble paint composition according to various embodiments is used to paint a vehicle, air handling equipment and an oven are not needed, so that energy can be saved in the painting process, CO.sub.2 production can be reduced, costs can be saved for painting equipment and maintenance, and space for a painting line can be saved, and a paint layer can be formed having excellent smoothing, waterproofing, chipping resistance, and outer appearance.

Embodiments relate to a water soluble paint composition for a vehicle. The water soluble paint composition includes a core-shell microgel resin, a dimer-modified polyester resin, a (meth)acryl-modified polyurethane resin, a curing agent, a pigment, and water, wherein the dimer-modified polyester resin is included in an amount of 1 to 10 wt % with respect to 100 wt % of the water-soluble paint composition. When the water soluble paint composition according to various embodiments is used to paint a vehicle, air handling equipment and an oven are not needed, so that energy can be saved in the painting process, CO.sub.2 production can be reduced, costs can be saved for painting equipment and maintenance, and space for a painting line can be saved, and a paint layer can be formed having excellent smoothing, waterproofing, chipping resistance, and outer appearance.

The invention relates to a urethane oligomer which according to a) or b) as follows, has: a) at least two backbone residues R issued from a polyisocyanate without the NCO groups, linked between them with a diol residue R.sub.B (diol without the two OH groups) by two urethane bonds (NHCOO) and each of said backbone residues R carrying (or linked to) at least two urethane segments each one of which, contains at least one terminal allyl group, preferably from 1 to 5 terminal allyl groups, b) at least one backbone residue R issued from a polyisocyanate without the NCO groups, said backbone residue R carrying (or linked to) at least two urethane segments each linked to R by one urethane bond with at least one urethane segment (arm) containing at least one terminal allyl group (preferably from 1 to 5 terminal allyl groups), and at least one urethane segment (arm) containing at least one terminal (meth)acrylate group (preferably from 1 to 5 terminal (meth)acrylate groups). The present invention also relates to a curable composition containing the urethane oligomer, the method of preparing the urethane oligomer, and the use of the urethane oligomer or the curable composition in the presence of air, for good surface properties by reducing oxygen inhibition in coatings, adhesives, sealants or in resin matrix.