Patent classifications
C09D183/12
SURFACE TREATING AGENT
A surface-treating agent including at least one fluoropolyether group-containing compound of the following formula (1) or (2) as defined herein and a chlorine ion, wherein a chlorine ion concentration in the surface-treating agent is 0.1 ppm by mass or more and 1.0 ppm by mass or less. Also disclosed is a pellet including the surface-treating agent and an article including a base material and a layer which is formed on a surface of the base material from the surface-treating agent:
R.sup.F1.sub.α—X.sup.A—R.sup.Si.sub.β (1)
R.sup.Si.sub.γ—X.sup.A—R.sup.F2—X.sup.A—R.sup.Si.sub.γ (2).
STAIN-PROOF BASE MATERIAL
A method for producing an article including a substrate and a surface-treating layer formed from a surface-treating agent containing a fluorine-containing silane compound formed thereon, the method including: simultaneously depositing Si and another metal on the substrate to form an intermediate layer containing a composite oxide containing Si; and forming a surface-treating layer directly on the intermediate layer, wherein, the fluorine-containing silane compound is at least one fluoropolyether group-containing compound represented by the following formula (1) or (2):
R.sup.F1.sub.α—X.sup.A—R.sup.Si.sub.β (1)
R.sup.Si.sub.γ—X.sup.A—R.sup.F2—X.sup.A—R.sup.Si.sub.γ (2)
where R.sup.F1, R.sup.F2, R.sup.Si, X.sup.A, α, β and γ are as defined herein.
STAIN-PROOF BASE MATERIAL
A method for producing an article including a substrate and a surface-treating layer formed from a surface-treating agent containing a fluorine-containing silane compound formed thereon, the method including: simultaneously depositing Si and another metal on the substrate to form an intermediate layer containing a composite oxide containing Si; and forming a surface-treating layer directly on the intermediate layer, wherein, the fluorine-containing silane compound is at least one fluoropolyether group-containing compound represented by the following formula (1) or (2):
R.sup.F1.sub.α—X.sup.A—R.sup.Si.sub.β (1)
R.sup.Si.sub.γ—X.sup.A—R.sup.F2—X.sup.A—R.sup.Si.sub.γ (2)
where R.sup.F1, R.sup.F2, R.sup.Si, X.sup.A, α, β and γ are as defined herein.
BIO-ELECTRODE COMPOSITION, BIO-ELECTRODE, METHOD FOR MANUFACTURING BIO-ELECTRODE, POLYMER COMPOUND, AND COMPOSITE
A bio-electrode composition contains (A) a composite of an ionic polymer material and particles. The component (A) contains the particles bonding to the polymer containing a repeating unit having a structure selected from the group consisting of salts of ammonium, lithium, sodium, potassium, and silver formed with any of fluorosulfonic acid, fluorosulfonimide, and N-carbonyl-fluorosulfonamide. Thus, the present invention provides: a bio-electrode composition capable of forming a living body contact layer for a bio-electrode which is excellent in electric conductivity and biocompatibility, light-weight, and manufacturable at low cost, and which prevents significant reduction in the electric conductivity even when wetted with water or dried; a bio-electrode including a living body contact layer formed of the bio-electrode composition; and a method for manufacturing the bio-electrode.
BIO-ELECTRODE COMPOSITION, BIO-ELECTRODE, METHOD FOR MANUFACTURING BIO-ELECTRODE, POLYMER COMPOUND, AND COMPOSITE
A bio-electrode composition contains (A) a composite of an ionic polymer material and particles. The component (A) contains the particles bonding to the polymer containing a repeating unit having a structure selected from the group consisting of salts of ammonium, lithium, sodium, potassium, and silver formed with any of fluorosulfonic acid, fluorosulfonimide, and N-carbonyl-fluorosulfonamide. Thus, the present invention provides: a bio-electrode composition capable of forming a living body contact layer for a bio-electrode which is excellent in electric conductivity and biocompatibility, light-weight, and manufacturable at low cost, and which prevents significant reduction in the electric conductivity even when wetted with water or dried; a bio-electrode including a living body contact layer formed of the bio-electrode composition; and a method for manufacturing the bio-electrode.
Anti-coalescing agent for three-dimensional printing
An example of an anti-coalescing agent for a three-dimensional (3D) printing process includes a vehicle and an anti-coalescing polymer dispersed in the vehicle. The vehicle includes a co-solvent, a surfactant, a humectant, and water. The anti-coalescing polymer has a mean particle size ranging from about 50 nm to about 195 nm, and the anti-coalescing polymer is to coat polymeric build material particles to prevent the polymeric build material particles from coalescing during electromagnetic radiation exposure of the 3D printing process.
Universal slip and flow control additives with recoatable quality
A universal slip and levelling additive having a recoatable or reprintable property contains polyoxyalkylene-polysiloxane copolymers of general formula (I)
##STR00001##
wherein R.sup.1=identical and/or different alkyl radicals having 1 to 8 carbon atoms, preferably having 1-4 carbon atoms, particularly preferably having 1 or 2 carbon atoms; R═R.sup.1 and/or —C.sub.pH.sub.2pO[(C.sub.2H.sub.4O).sub.x(C.sub.3H.sub.6O).sub.y]R.sup.2, where p=2, 3 or 4, with the proviso that at least one R═—C.sub.pH.sub.2pO[(C.sub.2H.sub.4O).sub.x(C.sub.3H.sub.6O).sub.y]—; R.sup.2=alkyl radical having 1 to 3 carbon atoms; n≥45; m=1 to 5; and wherein x and y are selected such that the molecular weight of the polyoxyalkylene block [(C.sub.2H.sub.4O).sub.x(C.sub.3H.sub.6O).sub.y] is >3000 g/mol and the molar weight ratio of x to y is <0.8.
Solvent stable slip additive composition
A composition contains a polyorganosiloxane dispersed in a combination of a condensation product of a polysiloxane resin and a polyoxyalkylene polymer, and a non-aqueous fluid carrier; wherein the weight-ratio of non-aqueous fluid carrier to condensation product is 0.5 or more and 10 or less; the weight-ratio of the combination of condensation product and non-aqueous fluid carrier to polyorganosiloxane is 0.01 or more and 0.50 or less; and wherein the composition contains less than one weight-part aromatic solvent per million weight parts composition.
WATER-REPELLENT, OIL-REPELLENT MEMBER AND METHOD FOR MANUFACTURING WATER-REPELLENT, OIL-REPELLENT MEMBER
This water-repellent, oil-repellent member is obtained via, inter alia, a method having: a step for wet-coating a substrate surface with a solution that contains a solvent and an organosilicon compound comprising multiple silanol groups in the molecule; a step for drying the solvent to form and laminate a primer layer on the substrate surface; a step for wet-coating the outer surface of the primer layer with a solution containing a hydrolyzable fluorine-containing compound and a solvent, and subsequently drying the solvent, or dry-coating the outer surface of the primer layer with a hydrolyzable fluorine-containing compound obtained by evaporating the solvent from the solution; and a step for curing the hydrolyzable fluorine-containing compound to form and laminate a water-repellent, oil-repellent layer on the outer surface of the primer layer. The water-repellent, oil-repellent member is obtained by providing, on various substrates: a primer layer of a specific thickness that contains, as a main component, an organosilicon compound having multiple silanol groups in the molecule; and, on the outer surface of the primer layer, a water-repellent, oil-repellent layer of a specific thickness that contains, as a main component, the cured hydrolyzable fluorine-containing compound. The water-repellent, oil-repellent member makes it possible for a water-repellent, oil-repellent coating exhibiting superior abrasion resistance and antistatic properties to be stably and straightforwardly formed on various substrates.
Fluorine-containing coating film and water- and oil-repellent coating composition
It is an object of the present invention to provide a coating film capable of realizing satisfactory sliding properties in addition to water- and oil-repellent properties and wear resistance evaluated by a static contact angle, and a coating composition for obtaining the coating film. The present invention is directed to a fluorine-containing coating film which has a root mean square roughness of less than 3.5 nm and has a perfluoropolyether structure. It is preferred that the coating film has a polysiloxane backbone and further has a structure in which a fluoroalkyl group is directly bonded to a silicon atom of the polysiloxane backbone, and that a sliding angle of 6 μL of a water droplet is 24.3° or less, or a speed of 20 μL of a water droplet sliding on a coating film inclined at 32° is 0.1 cm/second or more.