C09D183/12

Nanocomposite Material Made of a Polymer-Matrix Comprising PEO-Containing Polymers and Salts of Luminescent Polyanionic Metal Clusters

The present invention concerns a solid nanocomposite material consisting of a polymer-matrix in which are dispersed alkali metal, hydronium or ammonium salts of polyanionic components,

wherein the polymer-matrix comprises at least a linear or branched polymer or copolymer containing one or several poly(ethylene oxide) (PEO) chains, said polymer or copolymer being optionally crosslinked and each PEO chain having at least 4 ethylene oxide monomer units.

The present invention relates also to a photonic, e.g. optoelectronic, device comprising such a nanocomposite material.

Such material and device can be used as phosphorescence emitter, for crop growth lighting or for generating singlet oxygen.

Nanocomposite Material Made of a Polymer-Matrix Comprising PEO-Containing Polymers and Salts of Luminescent Polyanionic Metal Clusters

The present invention concerns a solid nanocomposite material consisting of a polymer-matrix in which are dispersed alkali metal, hydronium or ammonium salts of polyanionic components,

wherein the polymer-matrix comprises at least a linear or branched polymer or copolymer containing one or several poly(ethylene oxide) (PEO) chains, said polymer or copolymer being optionally crosslinked and each PEO chain having at least 4 ethylene oxide monomer units.

The present invention relates also to a photonic, e.g. optoelectronic, device comprising such a nanocomposite material.

Such material and device can be used as phosphorescence emitter, for crop growth lighting or for generating singlet oxygen.

FLUOROPOLYETHER GROUP-CONTAINING POLYMER-MODIFIED ORGANIC SILICON COMPOUND, SURFACE TREATMENT AGENT, AND ARTICLE

This surface treatment agent using a compound represented by formula (1) or (2) can, even without having a hydrolyzable group, form a water repellent and oil repellent layer having excellent abrasion resistance under mild conditions such as at room temperature.

##STR00001##

[Rf represents a monovalent or divalent fluorooxyalkylene group-containing polymer residue, Y.sub.1 and Y.sub.2 each represent a single bond or a divalent hydrocarbon group, Q represents a group that has a Si-containing structure having a valence of 2-4, Si, or C, X represents an epoxy-containing group, k represents 0-2, m represents 1-5, n represents 1-3, Z represents H, —SiR.sub.3 (R represents an alkyl group or a phenyl group), or -W.sub.1-Q′-W.sub.2-X′ (X′ represents X or —SiR.sub.3, W.sub.1 and W.sub.2 each represent a single bond or a divalent hydrocarbon group, Q′ represents a divalent group having a Si-containing structure), and a represents 1 or 2].

FLUORINE-CONTAINING COATING AGENT COMPOSITION, SURFACE TREATMENT AGENT CONTAINING SAID COMPOSITION, AND ARTICLE

This fluorine-containing coating agent composition contains: (A) an organic silicon compound containing a hydrolyzable group or a hydroxy group modified by a fluorooxyalkylene group-containing polymer residue, and/or a partial (hydrolyzed) condensate thereof; and (B) an organic silicon compound containing a polyether group and a hydrolyzable group or a hydroxy group modified by a fluorooxyalkylene group-containing polymer residue, and/or a partial (hydrolyzed) condensate thereof, wherein the mixture mass ratio of component (A) and component (B) is 15:85-85:15. When the composition is applied as a surface treatment agent, the surface treatment agent containing the fluorine-containing coating agent composition can form a cured coating film which has excellent water repellency and oil repellency, and which has both excellent steel wool abrasion resistance and eraser rubber abrasion resistance.

Low temperature cure coating formed via resin-facilitated catalyst migration between layers in a double layer curing mechanism

A double coating, curing method, cured coating, and kit are provided. A first layer of the double coating can be a first cure coating composition, which has a first hydroxy-functional resin, a first crosslinking agent, and a first catalyst. A second layer of a second cure coating composition can have a low hydrophilicity acrylic resin as a second hydroxy-functional resin, a second crosslinking agent, and a second catalyst. The first catalyst catalyzes crosslinking between the second hydroxy-functional resin and crosslinking agent, and not between the first hydroxy-functional resin and crosslinking agent. The second catalyst catalyzes crosslinking between the first hydroxy-functional resin and crosslinking agent, and not between the second hydroxy-functional resin and crosslinking agent. The first and/or second hydroxy functional resins can facilitate catalyst migration from one layer to the other. The separate compositions can be shelf-stable and/or the curing can occur at low temperature.

SILICONE-BASED ELECTRODEPOSITABLE COATING COMPOSITION

The present invention is directed towards an electrodepositable coating composition comprising, consisting essentially of, or consisting of an ionic salt group-containing silicone-based main film-forming polymer comprising functional groups; and a curing agent reactive with the functional groups of the ionic salt group-containing silicone-based main film-forming polymer. Also disclosed are coatings, coated substrates, and methods of coating a substrate.

SILICONE-BASED ELECTRODEPOSITABLE COATING COMPOSITION

The present invention is directed towards an electrodepositable coating composition comprising, consisting essentially of, or consisting of an ionic salt group-containing silicone-based main film-forming polymer comprising functional groups; and a curing agent reactive with the functional groups of the ionic salt group-containing silicone-based main film-forming polymer. Also disclosed are coatings, coated substrates, and methods of coating a substrate.

Anti-icing coatings

An anti-icing coating can include an amphiphilic copolymer on a surface of an article.

Anti-icing coatings

An anti-icing coating can include an amphiphilic copolymer on a surface of an article.

Antifouling structure precursor, antifouling structure, and surface modification method

An antifouling structure precursor, comprising: a modification layer that contains a modifier having a perfluoropolyether chain; and an oxide layer that has a surface entirely covered with the modification layer, wherein the modification layer has an uneven film thickness and comprises a comparatively thick area and a comparatively thin area that is dispersed in the comparatively thick area, and a coverage rate of covering the oxide layer with the comparatively thick area is equal to or greater than 10%. An antifouling structure, comprising: an antifouling structure precursor; and a lubricant oil on a surface of the antifouling structure precursor.