Disclosed is a moisture reactive polyurethane hot melt adhesive composition prepared from a mixture comprising a polyisocyanate, a polyester polyol, a polyether polyol; a thermoplastic polymer; inorganic filler; optionally a MA-SCA acid; and optionally one or more additives; wherein the polyester polyol is polymerized from a diacid and a diol; wherein the structure of the diacid is HOOC—(CH.sub.2).sub.m—COOH; wherein the structure of the diol is HO—(CH.sub.2).sub.n—OH; wherein the sum of (m+n) is equal to or less than 8; and wherein the acid number of the polyester polyol is less than 0.9. The disclosed reactive hot melt adhesive composition has improved thermal stability compared to conventional moisture reactive polyurethane hot melt adhesive compositions while maintaining their desirable properties.

Disclosed is a moisture reactive polyurethane hot melt adhesive composition prepared from a mixture comprising a polyisocyanate, a polyester polyol, a polyether polyol; a thermoplastic polymer; inorganic filler; optionally a MA-SCA acid; and optionally one or more additives; wherein the polyester polyol is polymerized from a diacid and a diol; wherein the structure of the diacid is HOOC—(CH.sub.2).sub.m—COOH; wherein the structure of the diol is HO—(CH.sub.2).sub.n—OH; wherein the sum of (m+n) is equal to or less than 8; and wherein the acid number of the polyester polyol is less than 0.9. The disclosed reactive hot melt adhesive composition has improved thermal stability compared to conventional moisture reactive polyurethane hot melt adhesive compositions while maintaining their desirable properties.

Provided herein are materials, methods of making materials, and methods of use, wherein the materials have switchable adhesive properties. Materials of the present disclosure can reversibly change coloration in conjunction with the changing adhesive state. The films, made from a porous polymer material, can be reversibly changed from a smooth state to a rough state, allowing for reversible and tunable gripping and/or adhesive properties.

Provided herein are materials, methods of making materials, and methods of use, wherein the materials have switchable adhesive properties. Materials of the present disclosure can reversibly change coloration in conjunction with the changing adhesive state. The films, made from a porous polymer material, can be reversibly changed from a smooth state to a rough state, allowing for reversible and tunable gripping and/or adhesive properties.

A method of using a self-stick insulation. The method includes providing a piece of insulation product with an adhesive coating. The adhesive coating includes polystyrene-maleic anhydride (SMA) and/or polyacrylic acid (PAA); an alcohol amine; and at least one of a polyvinyl alcohol and a starch. The adhesive coating is then activated with liquid water. Once the adhesive coating is active, the insulation product is attached to a surface with the adhesive coating.

A method of using a self-stick insulation. The method includes providing a piece of insulation product with an adhesive coating. The adhesive coating includes polystyrene-maleic anhydride (SMA) and/or polyacrylic acid (PAA); an alcohol amine; and at least one of a polyvinyl alcohol and a starch. The adhesive coating is then activated with liquid water. Once the adhesive coating is active, the insulation product is attached to a surface with the adhesive coating.

A dry shape memory adhesive material for adhering a target surface in the presence of fluid and for providing tunable mechanical contraction of an adhered surface. The dry shape memory adhesive material is pre-stretched and dried to provide an adhesive structure that implements a hydration-based shape memory mechanism to achieve both uniaxial and biaxial contractions of the adhered surface. According to preferred embodiments, the shape memory adhesive material includes a combination of one or more hydrophilic polymers or copolymers, one or more amine coupling group, and one or more cross linkers.

A dry shape memory adhesive material for adhering a target surface in the presence of fluid and for providing tunable mechanical contraction of an adhered surface. The dry shape memory adhesive material is pre-stretched and dried to provide an adhesive structure that implements a hydration-based shape memory mechanism to achieve both uniaxial and biaxial contractions of the adhered surface. According to preferred embodiments, the shape memory adhesive material includes a combination of one or more hydrophilic polymers or copolymers, one or more amine coupling group, and one or more cross linkers.

A flexible inkjet-printed article is prepared by: A′) providing an ink receptive medium having a substrate and an aqueous-based ink-receptive layer. This layer has: (a) a water-soluble salt of a multivalent metal cation; (b) one or both of a polyvinyl alcohol and a polyvinyl amine (or a copolymer derived from a vinyl alcohol and a vinyl amine) at 0.5-30 weight %; and optionally, (c) a crosslinking agent and (d) silica particles. At least one aqueous pigment-based ink is deposited directly on the aqueous-based ink-receptive layer, each having: a) an anionically-stabilized pigment colorant; and b) a water-miscible humectant at 1-20 weight %, each having a carbon to oxygen atom ratio of ≥1.0:1.0 and only two hydroxy groups. After drying, a functional layer with adhesive composition is formed on the inkjet-printed image and a flexible material is laminated to the functional layer, to form a flexible inkjet printed article.

A flexible inkjet-printed article is prepared by: A′) providing an ink receptive medium having a substrate and an aqueous-based ink-receptive layer. This layer has: (a) a water-soluble salt of a multivalent metal cation; (b) one or both of a polyvinyl alcohol and a polyvinyl amine (or a copolymer derived from a vinyl alcohol and a vinyl amine) at 0.5-30 weight %; and optionally, (c) a crosslinking agent and (d) silica particles. At least one aqueous pigment-based ink is deposited directly on the aqueous-based ink-receptive layer, each having: a) an anionically-stabilized pigment colorant; and b) a water-miscible humectant at 1-20 weight %, each having a carbon to oxygen atom ratio of ≥1.0:1.0 and only two hydroxy groups. After drying, a functional layer with adhesive composition is formed on the inkjet-printed image and a flexible material is laminated to the functional layer, to form a flexible inkjet printed article.