Disclosed is a preparation method of an all-weather self-healing stretchable conductive material, which uses acrylic acid and modified polyglutamic acid as a substrate, adds Fe.sup.3+ to form coordination, adjusts the volume ratio of water and glycerin, and heats to generate radical polymerization, so as to obtain a uniform double-layer three-dimensional network structure. The obtained polyacrylic acid and polyglutamic acid composite hydrogel has good mechanical properties and characteristics of rapid self-healing. A composite carbon film is prepared by depositing a metal layer of 20 nm to 80 nm thick on a single-layer aligned carbon film by magnetron sputtering, and then the composite hydrogel is adhered to each of the upper and lower sides of the composite carbon film respectively to form an all-weather self-healing stretchable conductive material of a sandwich structure. The preparation method of the invention is simple, the source of raw materials is plenty, and the obtained materials have good electrical and mechanical properties and have broad application prospects in the fields of flexible stretchable devices, wearable devices, and soft-bodied robots and the like.

Embodiments of this invention relate to adhesives, and more particularly to biomimetic heteropolymer adhesive compositions. Certain embodiments relate to biomimetic terpolymer adhesive compositions including dopamine methacrylamide, 3,4-dihydroxyphenylalanine, or 3,4-dihydroxystyrene, mimicking moieties found in marine mussel adhesive proteins. In some embodiments, elastic moduli of the adhesives are preferably selected to match the elastic moduli of the substrates to minimize stress concentrations, to increase the ductility of the adhesive-substrate system, or both.

Embodiments of this invention relate to adhesives, and more particularly to biomimetic heteropolymer adhesive compositions. Certain embodiments relate to biomimetic terpolymer adhesive compositions including dopamine methacrylamide, 3,4-dihydroxyphenylalanine, or 3,4-dihydroxystyrene, mimicking moieties found in marine mussel adhesive proteins. In some embodiments, elastic moduli of the adhesives are preferably selected to match the elastic moduli of the substrates to minimize stress concentrations, to increase the ductility of the adhesive-substrate system, or both.

The present invention is intended to provide a gel sheet having a formulation providing an adhesive force on the skin side suitable for the skin (i.e., a gel having a low adhesive force and being able to withstand a tip pressure of a terminal and the like), and concurrently having a sufficient adhesive force against an electrode element on the side opposite to the skin side. The present invention is a gel sheet having a laminated structure of a layer A and a layer B, characterized in that the storage elastic modulus of the layer A at 23° C. and 10 Hz is 12,000 to 40,000 Pa, and the storage elastic modulus of the layer B at 23° C. and 10 Hz is 2,000 to 10,000 Pa.

The present invention is intended to provide a gel sheet having a formulation providing an adhesive force on the skin side suitable for the skin (i.e., a gel having a low adhesive force and being able to withstand a tip pressure of a terminal and the like), and concurrently having a sufficient adhesive force against an electrode element on the side opposite to the skin side. The present invention is a gel sheet having a laminated structure of a layer A and a layer B, characterized in that the storage elastic modulus of the layer A at 23° C. and 10 Hz is 12,000 to 40,000 Pa, and the storage elastic modulus of the layer B at 23° C. and 10 Hz is 2,000 to 10,000 Pa.

Provided are a thermally crosslinkable binder aqueous solution for a lithium-ion battery, a thermally crosslinkable slurry for a lithium-ion battery negative electrode, a negative electrode for a lithium-ion battery, a lithium-ion battery negative electrode material, as well as a lithium-ion battery and a method for producing the same. The present disclosure provides a thermally crosslinkable binder aqueous solution for a lithium-ion battery, containing water-soluble poly(meth)acrylamide (A) and having a pH of 5 to 7, wherein the water-soluble poly(meth)acrylamide (A) is a polymer of a monomer group containing, with respect to 100 mol % of the monomer group, 2 mol % to 60 mol % of a (meth)acrylamide group-containing compound (a), 10 mol % to 50 mol % of one or more unsaturated acids selected from the group consisting of unsaturated carboxylic acids and unsaturated sulfonic acids or an inorganic salt thereof (b), and 15 mol % to 78 mol % of hydroxyalkyl(meth)acrylate (c) having a hydroxyalkyl group having 2 to 4 carbon atoms.

Provided are a thermally crosslinkable binder aqueous solution for a lithium-ion battery, a thermally crosslinkable slurry for a lithium-ion battery negative electrode, a negative electrode for a lithium-ion battery, a lithium-ion battery negative electrode material, as well as a lithium-ion battery and a method for producing the same. The present disclosure provides a thermally crosslinkable binder aqueous solution for a lithium-ion battery, containing water-soluble poly(meth)acrylamide (A) and having a pH of 5 to 7, wherein the water-soluble poly(meth)acrylamide (A) is a polymer of a monomer group containing, with respect to 100 mol % of the monomer group, 2 mol % to 60 mol % of a (meth)acrylamide group-containing compound (a), 10 mol % to 50 mol % of one or more unsaturated acids selected from the group consisting of unsaturated carboxylic acids and unsaturated sulfonic acids or an inorganic salt thereof (b), and 15 mol % to 78 mol % of hydroxyalkyl(meth)acrylate (c) having a hydroxyalkyl group having 2 to 4 carbon atoms.

An adhesive composition of the present application includes the following components (A) to (C): (A) a radically polymerizable compound; (B) a polymer having a weight-average molecular weight of 35,000 to 110,000 and having a repeat unit derived from a polymerizable compound of formula (I) (wherein X.sup.1 and X.sup.2 each independently represent a C7 to C20 alkyl group or a C7 to C20 alkoxy group, n represents 0 or 1, Z.sup.1 and Z.sup.2 each independently represent a single bond or a Cl to C3 alkylene group, each R independently represents an organic group or a halogeno group, m1 and m2 each independently represent any integer of 0 to 4, and Y represents a polymerizable functional group); and (C) a radical polymerization initiator.

##STR00001##

An adhesive composition of the present application includes the following components (A) to (C): (A) a radically polymerizable compound; (B) a polymer having a weight-average molecular weight of 35,000 to 110,000 and having a repeat unit derived from a polymerizable compound of formula (I) (wherein X.sup.1 and X.sup.2 each independently represent a C7 to C20 alkyl group or a C7 to C20 alkoxy group, n represents 0 or 1, Z.sup.1 and Z.sup.2 each independently represent a single bond or a Cl to C3 alkylene group, each R independently represents an organic group or a halogeno group, m1 and m2 each independently represent any integer of 0 to 4, and Y represents a polymerizable functional group); and (C) a radical polymerization initiator.

##STR00001##

A sheet for thermal bonding which has a tensile modulus of 10 to 3,000 MPa and contains fine metal particles in an amount in the range of 60-98 wt % and which, when heated from 23° C. to 400° C. in the air at a heating rate of 10° C./min and then examined by energy dispersive X-ray spectrometry, has a carbon concentration of 15 wt % or less.