A pressure sensitive adhesive comprising the polymerization product of a polymerizable composition comprising: (a) one or more (meth)acrylate ester monomers; (b) one or more hydrophilic non-acidic monomers; and (c) reactive, ionic surfactant. Also articles comprising such adhesives and methods for making such adhesives and such articles.

This invention pertains to a curable composition comprising a first component having β-ketoester and/or malonate functionalities and a second component having two or more aldehyde functionalities. The compositions can be cured at room temperature or low temperatures to yield crosslinked networks that are capable of providing desirable properties for coating and adhesive applications. The reactive functionalities of β-ketoester, malonate, and aldehyde can be either on polymers as the main binders or on small molecules as the crosslinkers. The curable compositions desirably are either solventless or organic solvent based.

This invention pertains to a curable composition comprising a first component having β-ketoester and/or malonate functionalities and a second component having two or more aldehyde functionalities. The compositions can be cured at room temperature or low temperatures to yield crosslinked networks that are capable of providing desirable properties for coating and adhesive applications. The reactive functionalities of β-ketoester, malonate, and aldehyde can be either on polymers as the main binders or on small molecules as the crosslinkers. The curable compositions desirably are either solventless or organic solvent based.

Provided is a multilayer adhesive tape having excellent step coverage and reworkability. The multilayer adhesive tape sequentially includes: a first outer adhesive layer; an intermediate adhesive layer; and a second outer adhesive layer, in which the intermediate adhesive layer includes an intermediate adhesive polymer including: a polymerization unit of an alkyl group-containing (meth)acrylate monomer; a polymerization unit of a carboxyl group-containing monomer; and a polymerization unit of an acrylamide-based monomer.

Provided is a multilayer adhesive tape having excellent step coverage and reworkability. The multilayer adhesive tape sequentially includes: a first outer adhesive layer; an intermediate adhesive layer; and a second outer adhesive layer, in which the intermediate adhesive layer includes an intermediate adhesive polymer including: a polymerization unit of an alkyl group-containing (meth)acrylate monomer; a polymerization unit of a carboxyl group-containing monomer; and a polymerization unit of an acrylamide-based monomer.

A composition is described comprising semicrystalline polylactic acid polymer; polyvinyl acetate polymer having a glass transition temperature (Tg) of at least 25° C.; plasticizer; and optionally amorphous polylactic acid polymer. In another embodiment the composition further comprises nucleating agent. Also described are films comprising the composition as well as articles, such as a tape or sheet, comprising the film described herein and a layer of pressure sensitive adhesive disposed on the film.

[Problem]

To provide a dental adhesive composition realizing excellent durable adhesive strength with respect to various dental restorative materials for cutting and machining such as glass ceramics containing lithium disilicate, a dental resin for cutting and machining, and a dental resin for cutting and machining made of a glass fiber reinforced resin in particular and with respect to a tooth substance, and having excellent storage stability simultaneously.

[Solution]

The dental adhesive composition of the present invention comprises a matrix containing (A1) silane coupling material represented by structural formula of [Chemical formula 1],

##STR00001##

(B) polymerizable monomer having an acidic group and (C) polymerizable monomer having no acidic group, and wherein the (C) polymerizable monomer having no acidic group contains (C1) polymerizable monomer having no acidic group and having one or more hydroxyl groups, the (A1) silane coupling material represented by structural formula of [Chemical formula 1] and the (C1) polymerizable monomer having no acidic group and having one or more hydroxyl groups coexist in at least one matrix, and the dental adhesive composition satisfies at least one of following formulas (1) and (2).

0.005≤Total amount of silane coupling material compounding amount index in matrix ((S1×W1)/M1)≤0.070   [Formula (1)]

0.001≤Total amount of silane coupling material compounding amount index in composition ((S2×W2)/M2)≤0.015   [Formula (2)]

[Problem]

To provide a dental adhesive composition realizing excellent durable adhesive strength with respect to various dental restorative materials for cutting and machining such as glass ceramics containing lithium disilicate, a dental resin for cutting and machining, and a dental resin for cutting and machining made of a glass fiber reinforced resin in particular and with respect to a tooth substance, and having excellent storage stability simultaneously.

[Solution]

The dental adhesive composition of the present invention comprises a matrix containing (A1) silane coupling material represented by structural formula of [Chemical formula 1],

##STR00001##

(B) polymerizable monomer having an acidic group and (C) polymerizable monomer having no acidic group, and wherein the (C) polymerizable monomer having no acidic group contains (C1) polymerizable monomer having no acidic group and having one or more hydroxyl groups, the (A1) silane coupling material represented by structural formula of [Chemical formula 1] and the (C1) polymerizable monomer having no acidic group and having one or more hydroxyl groups coexist in at least one matrix, and the dental adhesive composition satisfies at least one of following formulas (1) and (2).

0.005≤Total amount of silane coupling material compounding amount index in matrix ((S1×W1)/M1)≤0.070   [Formula (1)]

0.001≤Total amount of silane coupling material compounding amount index in composition ((S2×W2)/M2)≤0.015   [Formula (2)]

An adhesive composition having excellent adhesive properties and adhesiveness to a variety of plastics such as polypropylene, polyethylene, or a cycloolefin resin. The adhesive composition includes a polymer having a repeating unit derived from a polymerizable compound of the following formula (I):

##STR00001##

in which X.sup.1 and X.sup.2 each independently represent a C7 to C20 alkyl group or a C7 to C20 alkoxy group; n represents 0 or 1; Z.sup.1 and Z.sup.2 each independently represent a single bond or a C1 to C3 alkylene group; R each independently represents an organic group or a halogeno group; m1 and m2 each independently represent any integer of 0 to 4; and Y represents a polymerizable functional group.

An adhesive composition having excellent adhesive properties and adhesiveness to a variety of plastics such as polypropylene, polyethylene, or a cycloolefin resin. The adhesive composition includes a polymer having a repeating unit derived from a polymerizable compound of the following formula (I):

##STR00001##

in which X.sup.1 and X.sup.2 each independently represent a C7 to C20 alkyl group or a C7 to C20 alkoxy group; n represents 0 or 1; Z.sup.1 and Z.sup.2 each independently represent a single bond or a C1 to C3 alkylene group; R each independently represents an organic group or a halogeno group; m1 and m2 each independently represent any integer of 0 to 4; and Y represents a polymerizable functional group.