Amorphous propylene-ethylene copolymers are described herein that can include high amounts of ethylene and exhibit desirable softening points and needle penetrations. The desirable combinations of softening points and needle penetrations in these propylene-ethylene copolymers allow them to have a broad operating window. Due their broad operating window, the propylene-ethylene copolymers can be utilized in a wide array of applications and products, including hot melt adhesives.

A hydrogenated copolymer containing a hydrogenated copolymer (a) prepared by hydrogenating a copolymer of a vinyl aromatic compound and a conjugated diene compound, and a hydrogenated copolymer (b) prepared by hydrogenating a copolymer of a vinyl aromatic compound and a conjugated diene compound, wherein a mass ratio (a)/(b) of a content of the hydrogenated copolymer (a) to a content of the hydrogenated copolymer (b) is 5/95 to 95/5, the hydrogenated copolymer (a) has a hydrogenated polymer block (B1) and a hydrogenated polymer block (B2), the hydrogenated polymer block (B1) consists of a vinyl aromatic compound and a conjugated diene compound and has a content of the vinyl aromatic compound of 40 to 80 mass %, and the hydrogenated polymer block (B2) mainly contains a conjugated diene compound and has a vinyl bond content of 60 to 100 mol % before hydrogenation.

A hydrogenated copolymer containing a hydrogenated copolymer (a) prepared by hydrogenating a copolymer of a vinyl aromatic compound and a conjugated diene compound, and a hydrogenated copolymer (b) prepared by hydrogenating a copolymer of a vinyl aromatic compound and a conjugated diene compound, wherein a mass ratio (a)/(b) of a content of the hydrogenated copolymer (a) to a content of the hydrogenated copolymer (b) is 5/95 to 95/5, the hydrogenated copolymer (a) has a hydrogenated polymer block (B1) and a hydrogenated polymer block (B2), the hydrogenated polymer block (B1) consists of a vinyl aromatic compound and a conjugated diene compound and has a content of the vinyl aromatic compound of 40 to 80 mass %, and the hydrogenated polymer block (B2) mainly contains a conjugated diene compound and has a vinyl bond content of 60 to 100 mol % before hydrogenation.

Hot melt adhesives comprising (i) styrene butadiene copolymer, (ii) olefin block copolymer (OBC), and (iii) water white hydrogenated hydrocarbon resin are described. The adhesives exhibit high optical clarity and are relatively clear over a wide range of temperatures. The adhesives also exhibit good adhesion at cold temperatures. Also described are laminates of the adhesive with polymeric films, such as adhesive labels that can be used in labeling containers. In addition, various goods such as containers labeled using the adhesives are described.

Hot melt adhesives comprising (i) styrene butadiene copolymer, (ii) olefin block copolymer (OBC), and (iii) water white hydrogenated hydrocarbon resin are described. The adhesives exhibit high optical clarity and are relatively clear over a wide range of temperatures. The adhesives also exhibit good adhesion at cold temperatures. Also described are laminates of the adhesive with polymeric films, such as adhesive labels that can be used in labeling containers. In addition, various goods such as containers labeled using the adhesives are described.

The present invention is a hot melt adhesive sheet including an adhesive layer including a hot melt adhesive, in which the hot melt adhesive includes either a styrene-ethylene-ethylene-propylene-styrene block copolymer or a styrene-ethylene-propylene-styrene block copolymer, and a hydrogenated alicyclic hydrocarbon petroleum resin, and the hot melt adhesive sheet has a glass transition temperature falling within a range of −10° C. or more and 10° C. or less.

The present invention is a hot melt adhesive sheet including an adhesive layer including a hot melt adhesive, in which the hot melt adhesive includes either a styrene-ethylene-ethylene-propylene-styrene block copolymer or a styrene-ethylene-propylene-styrene block copolymer, and a hydrogenated alicyclic hydrocarbon petroleum resin, and the hot melt adhesive sheet has a glass transition temperature falling within a range of −10° C. or more and 10° C. or less.

Provided is a block copolymer containing 10 mass % or more of a polymer (A1) having a multi-branched structure having four or more polymer chains, the polymer chain having a polymer block A containing 70 mass % or more of a structural unit derived from a conjugated diene compound and a polymer block B containing 70 mass % or more of a structural unit derived from an aromatic vinyl compound, the block copolymer having a functional group F containing at least one element selected from the group consisting of nitrogen, silicon, oxygen, and sulfur in a part or all of terminals of the four or more polymer chains, and the block copolymer having a value α of 0.75 or more represented by the following equation (i), when p, q, r, and s are defined as component proportions (molar proportions) of structural unit represented by the following formula (1) to formula (4), in the polymer, respectively.

##STR00001##

Provided is a block polymer including two or more polymer block As each having a value β of 0.20 or less and a functional group F containing at least one element selected from a group consisting of nitrogen, silicon, oxygen, and sulfur in a part or all of terminals of the two or more polymer block As, in which the block polymer has a value α of 0.75 or more, when p, q, r and s are defined as a component proportion (molar proportion) of a structural unit represented by Formula (1), a component proportion of a structural unit represented by Formula (2), a component proportion of a structural unit represented by Formula (3), and a component proportion of a structural unit represented by Formula (4), in the polymer, respectively.

##STR00001##

A method of producing a roll-shaped body comprises: obtaining an adhesive agent sheet having an embossed shape at both surfaces thereof by imparting an embossed shape on both surfaces of an adhesive agent sheet containing a thermoplastic resin as a main component; overlapping a protective sheet having releasability from the adhesive agent sheet to at least one surface of the adhesive agent sheet having the embossed shape at both surfaces thereof; and obtaining the roll-shaped body by wounding the adhesive agent sheet having the embossed shape at both surfaces thereof and the protective sheet that are overlapped facing one another.