C09J153/025

Hydrogenated block copolymer, resin composition, pressure-sensitive adhesive, adhesive, molded object, liquid-packaging container, medical tool, medical tube, corner member for weather seal, and weather seal

Provided are a hydrogenated block copolymer capable of giving a resin composition having good moldability and sufficient mechanical strength and excellent in flexibility, kink resistance and transparency and also excellent in pressure sensitive adhesiveness, adhesiveness and weather resistance, and a resin composition containing the hydrogenated block copolymer, as well as a pressure sensitive adhesive, an adhesive, a molded article, a liquid-packaging container, a medical tool, a medical tube, a corner member for weather seal, and a weather seal that are produced using these. Specifically, the hydrogenated block copolymer is a hydrogenated block copolymer prepared by hydrogenating a block copolymer that contains at least a polymer block (A) consisting mainly of a structural unit derived from an aromatic vinyl compound, and a polymer block (B) consisting mainly of a structural unit derived from isoprene, a structural unit derived from butadiene, or a structural unit derived from a mixture of isoprene and butadiene, wherein the content of the polymer block (A) is 1% by mass or more and less than 5% by mass relative to the total amount of the hydrogenated block copolymer, the total content of the 1,2-bond and the 3,4-bond of the polymer block (B) is 30 to 85 mol %, the hydrogenation rate of the polymer block (B) is 80 mol % or more, and the weight average molecular weight of the hydrogenated block copolymer is 150,000 to 800,000.

Hydrogenated block copolymer, resin composition, pressure-sensitive adhesive, adhesive, molded object, liquid-packaging container, medical tool, medical tube, corner member for weather seal, and weather seal

Provided are a hydrogenated block copolymer capable of giving a resin composition having good moldability and sufficient mechanical strength and excellent in flexibility, kink resistance and transparency and also excellent in pressure sensitive adhesiveness, adhesiveness and weather resistance, and a resin composition containing the hydrogenated block copolymer, as well as a pressure sensitive adhesive, an adhesive, a molded article, a liquid-packaging container, a medical tool, a medical tube, a corner member for weather seal, and a weather seal that are produced using these. Specifically, the hydrogenated block copolymer is a hydrogenated block copolymer prepared by hydrogenating a block copolymer that contains at least a polymer block (A) consisting mainly of a structural unit derived from an aromatic vinyl compound, and a polymer block (B) consisting mainly of a structural unit derived from isoprene, a structural unit derived from butadiene, or a structural unit derived from a mixture of isoprene and butadiene, wherein the content of the polymer block (A) is 1% by mass or more and less than 5% by mass relative to the total amount of the hydrogenated block copolymer, the total content of the 1,2-bond and the 3,4-bond of the polymer block (B) is 30 to 85 mol %, the hydrogenation rate of the polymer block (B) is 80 mol % or more, and the weight average molecular weight of the hydrogenated block copolymer is 150,000 to 800,000.

LAMINATE PRODUCTION METHOD

A laminate production method is provided which can sufficiently prevent the occurrence of blocking without causing deterioration in the outstanding characteristics of acrylic block copolymers such as adhesive performance, and can also ensure excellent processability during extrusion. The laminate production method includes a step (1) of bringing raw pellets of an acrylic block copolymer (A) into contact with an aqueous dispersion (C) containing acrylic resin particles (B) and no surfactants, the acrylic block copolymer (A) including at least one polymer block (a1) including acrylic acid alkyl ester units and at least one polymer block (a2) including methacrylic acid alkyl ester units, a step (2) of removing water attached to the pellets and thereby obtaining pellets (D), and a step (3) of preparing an adhesive composition using an adhesive feedstock including the pellets (D) from the step (2), and extruding the adhesive composition to form an adhesive layer and thereby producing a laminate including the adhesive layer and a substrate layer.

LAMINATE PRODUCTION METHOD

A laminate production method is provided which can sufficiently prevent the occurrence of blocking without causing deterioration in the outstanding characteristics of acrylic block copolymers such as adhesive performance, and can also ensure excellent processability during extrusion. The laminate production method includes a step (1) of bringing raw pellets of an acrylic block copolymer (A) into contact with an aqueous dispersion (C) containing acrylic resin particles (B) and no surfactants, the acrylic block copolymer (A) including at least one polymer block (a1) including acrylic acid alkyl ester units and at least one polymer block (a2) including methacrylic acid alkyl ester units, a step (2) of removing water attached to the pellets and thereby obtaining pellets (D), and a step (3) of preparing an adhesive composition using an adhesive feedstock including the pellets (D) from the step (2), and extruding the adhesive composition to form an adhesive layer and thereby producing a laminate including the adhesive layer and a substrate layer.

Hot-Melt Adhesive Composition and Manufacturing Method Therefor
20220089921 · 2022-03-24 · ·

A hot melt adhesive composition is provided that includes: a diblock copolymer including a styrene-based monomer-derived unit and a conjugated diene-based monomer-derived unit; a triblock copolymer which is a coupled polymer of the diblock copolymer; and a crosslinked block copolymer including a crosslinking agent-derived crosslinked part crosslinked with two or more of the diblock copolymer and the triblock copolymer. The conjugated diene-based monomer-derived unit includes an isoprene-derived unit and an epoxidized isoprene rubber.

Hot-Melt Adhesive Composition and Manufacturing Method Therefor
20220089921 · 2022-03-24 · ·

A hot melt adhesive composition is provided that includes: a diblock copolymer including a styrene-based monomer-derived unit and a conjugated diene-based monomer-derived unit; a triblock copolymer which is a coupled polymer of the diblock copolymer; and a crosslinked block copolymer including a crosslinking agent-derived crosslinked part crosslinked with two or more of the diblock copolymer and the triblock copolymer. The conjugated diene-based monomer-derived unit includes an isoprene-derived unit and an epoxidized isoprene rubber.

Ultrahigh melt flow styrenic block copolymers
11279821 · 2022-03-22 · ·

A selectively hydrogenated block copolymer of general formula S-E-S, (S-E.sub.1).sub.nX, or mixtures thereof is disclosed, where n has a value of 2-6, and X is a coupling agent residue. Before hydrogenation, S is a polystyrene block having a molecular weight of 4,400-5,600 g/mol, and E and E1 are polydiene blocks having molecular weights of 18,000-36,000 g/mol and 9,000 to 18,000 g/mol, respectively, selected from polybutadiene, polyisoprene and mixtures thereof, and having a total vinyl content of 60-85 mol %. After hydrogenation, the block copolymer has 0-10 percent of styrene double bonds reduced and at least 80 percent of conjugated diene double bonds reduced. The block copolymer has a solution viscosity of less than 80 centipoise (cP); a polystyrene content of 25-40 wt. % and up to 50 wt. % of diblock units of general formula S-E or S-E.sub.1.

COMPOSITION FOR STRUCTURAL ADHESIVES
20210332266 · 2021-10-28 ·

The invention relates to an acrylic structural adhesive composition containing (meth)acrylate monomers at least 20% of which is a mixture of 1,3-Dioxan-5-yl methacrylate and 1,3-Dioxolan-4-ylmethyl methacrylate, as well as block copolymers, elastomers and particles formed of a thermoplastic shell and an elastomeric core.

Hot melt composition

The present technology provides a hot melt composition containing: styrene-based thermoplastic elastomer having a weight average molecular weight of 300000 or more; tackifier; a first paraffin oil having a weight average molecular weight of 1000 or more; and a second paraffin oil having a weight average molecular weight of less than 1000.

HOT-MELT ADHESIVE, REINFORCING TAPE, AND FLEXIBLE FLAT CABLE HAVING REINFORCED AT CONDUCTOR TERMINAL WITH REINFORCING TAPE
20210317339 · 2021-10-14 ·

A hot-melt adhesive for reinforcing a conductor terminal of a flexible flat cable, said hot-melt adhesive comprising at least one member selected from the group consisting of (P1) a hydrogenated product of a block copolymer of an aromatic vinyl compound and a conjugated diene compound, wherein the content of a structural unit derived from the aromatic vinyl compound is not more than 65 mass % relative to the sum of the content of the structural unit derived from the aromatic vinyl compound and the content of a structural unit derived from the conjugated diene compound, (P2) a hydrogenated product of a random copolymer of an aromatic vinyl compound and a conjugated diene compound, (P3) an acid-modified hydrogenated product of a copolymer of an aromatic vinyl compound and a conjugated diene compound, and (P4) an amine-modified hydrogenated product of a copolymer of an aromatic vinyl compound and a conjugated diene compound; and a reinforcing tape wherein a layer of the hot-melt adhesive is formed on one surface of an insulating film.