A two-pack polyurethane adhesive for semi-structural and structural adhesive bonds which are applied in melt form and have a high handling strength wherein the two-pack polyurethane adhesive includes a first pack A containing at least one polyester A1 which is solid at room temperature and at least one polyol A2 having a hydroxyl group functionality greater than 2.0, and a second pack B containing polyurethane prepolymers having isocyanate groups.

The present invention relates to an aqueous polyurethane dispersion and a process for preparing the same, an adhesive containing the same, and an adhesion article obtained by bonding with the adhesive. The aqueous polyurethane dispersion comprises a polyurethane having an anionic group dispersed therein, the polyurethane has a fusion enthalpy of 3 J/g-100 J/g at 20° C.-100° C. of the first temperature rising curve measured with the DSC according to DIN 65467, a weight-average molecular weight of 31,000-95,000, and the aqueous polyurethane dispersion has an acid value of 0.5 mg KOH/g-8.5 mg KOH/g. The adhesive comprising the aqueous polyurethane dispersion of the present invention has an excellent initial bonding force.

The present invention relates to an aqueous polyurethane dispersion and a process for preparing the same, an adhesive containing the same, and an adhesion article obtained by bonding with the adhesive. The aqueous polyurethane dispersion comprises a polyurethane having an anionic group dispersed therein, the polyurethane has a fusion enthalpy of 3 J/g-100 J/g at 20° C.-100° C. of the first temperature rising curve measured with the DSC according to DIN 65467, a weight-average molecular weight of 31,000-95,000, and the aqueous polyurethane dispersion has an acid value of 0.5 mg KOH/g-8.5 mg KOH/g. The adhesive comprising the aqueous polyurethane dispersion of the present invention has an excellent initial bonding force.

The two-part curable adhesive composition contains a main agent (A) containing a urethane prepolymer (a1) and a residual polyisocyanate (a2), and a curing agent (B) containing a polyol compound (b1) and a polyamine compound (b2). The urethane prepolymer (a1) is made by reacting in an equivalent ratio of an isocyanate group in a raw material polyisocyanate to a hydroxy group in a polycarbonate polyol being 2.05 or greater. The equivalent ratio of an isocyanate group in the main agent (A) to an active hydrogen group in the curing agent (B) is from 0.5 to 4.

A two-part curable adhesive composition includes a main agent (A) containing a urethane prepolymer (a1) and a remaining polyisocyanate (a2), and a curing agent (B) containing a non-crystalline polyol compound (b1) and a polyamine compound (b2). An equivalent ratio of an isocyanate group in a raw polyisocyanate to a hydroxyl group in the polyol compound is from 2.05 to 12. The equivalent ratio of the isocyanate group in the main agent (A) to an amino group in the polyamine compound (b2) is from 1.2 to 6. The equivalent ratio of the isocyanate group in the main agent (A) to the hydroxyl group in the non-crystalline polyol compound (b1) is from 2 to 12.

The present invention provides a laminate obtained by arranging a composition to be in contact with a rubber, wherein the composition is prepared by blending a polythiol compound (A), an isocyanate group-containing compound (B) and a radical generator (C), and wherein the ratio of the total molar number of the isocyanate group contained in the isocyanate-containing compound (B) to the total molar number of the thiol group contained in the polythiol compound (A) (isocyanate group/thiol group) is from 0.2 to 0.78, and provides a method for producing the laminate. The present invention thus provides a laminate, in which the rubber layer is adhered using at least one of an adhesive or an adhesive sheet capable of strongly adhering a rubber member, especially a vulcanized rubber member, and provides a laminate adhering to a rubber article using at least one of a coating agent and a coating sheet.

The present invention provides a laminate obtained by arranging a composition to be in contact with a rubber, wherein the composition is prepared by blending a polythiol compound (A), an isocyanate group-containing compound (B) and a radical generator (C), and wherein the ratio of the total molar number of the isocyanate group contained in the isocyanate-containing compound (B) to the total molar number of the thiol group contained in the polythiol compound (A) (isocyanate group/thiol group) is from 0.2 to 0.78, and provides a method for producing the laminate. The present invention thus provides a laminate, in which the rubber layer is adhered using at least one of an adhesive or an adhesive sheet capable of strongly adhering a rubber member, especially a vulcanized rubber member, and provides a laminate adhering to a rubber article using at least one of a coating agent and a coating sheet.

Adhesive compositions comprise a polyester polyol that includes residues of at least one 2, 2, 4, 4-tetraalkylcyclobutane-1, 3-diol, including, for example, 2, 2, 4, 4-tetramethylcyclobutane-1, 3-diol (TMCD). Adhesive compositions as described herein exhibit enhanced properties as compared to conventional adhesive compositions, and may be suitable for a wide variety of end use applications, including, flexible packaging, woodworking, automotive uses, and electronics.

Adhesive compositions comprise a polyester polyol that includes residues of at least one 2, 2, 4, 4-tetraalkylcyclobutane-1, 3-diol, including, for example, 2, 2, 4, 4-tetramethylcyclobutane-1, 3-diol (TMCD). Adhesive compositions as described herein exhibit enhanced properties as compared to conventional adhesive compositions, and may be suitable for a wide variety of end use applications, including, flexible packaging, woodworking, automotive uses, and electronics.

An adhesive agent produced by crosslinking an adhesive agent composition containing a polyester resin (i) having a structural portion derived from a polycarboxylic acid compound (a) and a structural portion derived from a polyol component (b), wherein the polyester resin (i) contains a structural portion derived from at least one selected from the group consisting of a dimer acid compound, a sebacic acid compound, and a dimer diol in a proportion of not less than 60 wt. % based on the weight of the polyester resin (i), wherein the polyol component (b) includes a glycol (b1) having an even carbon number (excluding the dimer diol), wherein the polyester resin (i) has an ester group concentration of not less than 2 mmol/g. The adhesive agent has an adhesive force (α) of not less than 1 N/25 mm as measured under predetermined conditions.