Patent classifications
C09J175/06
Adhesive composition and preparation method and use thereof
The invention relates to an adhesive composition, the preparation and use of said composition, and an article obtained by bonding using said composition. The adhesive composition comprises: a. an anionic aqueous polyurethane dispersion, which contains a polyurethane with enthalpy of fusion of at least 3 J/g, wherein the enthalpy of fusion is measured by DSC at 20° C.-100° C. of the first heating curve according to DIN 65467; and wherein said aqueous polyurethane dispersion has a hydroxyl content of 0.001% by weight to 0.085% by weight, relative to the total weight of the aqueous polyurethane dispersion; and b. an aqueous polyacrylate primary dispersion with a hydroxyl content of 0.5% by weight to 1.8% by weight, relative to the total weight of the aqueous polyacrylate primary dispersion; wherein the amount of the aqueous polyurethane dispersion is 30% by weight to 91% by weight, and the amount of the aqueous polyacrylate primary dispersion is 9% by weight to 70% by weight, the above weight percentages being relative to the total weight of the adhesive composition. The adhesive composition of the present invention has good high-temperature resistance.
Adhesive composition and preparation method and use thereof
The invention relates to an adhesive composition, the preparation and use of said composition, and an article obtained by bonding using said composition. The adhesive composition comprises: a. an anionic aqueous polyurethane dispersion, which contains a polyurethane with enthalpy of fusion of at least 3 J/g, wherein the enthalpy of fusion is measured by DSC at 20° C.-100° C. of the first heating curve according to DIN 65467; and wherein said aqueous polyurethane dispersion has a hydroxyl content of 0.001% by weight to 0.085% by weight, relative to the total weight of the aqueous polyurethane dispersion; and b. an aqueous polyacrylate primary dispersion with a hydroxyl content of 0.5% by weight to 1.8% by weight, relative to the total weight of the aqueous polyacrylate primary dispersion; wherein the amount of the aqueous polyurethane dispersion is 30% by weight to 91% by weight, and the amount of the aqueous polyacrylate primary dispersion is 9% by weight to 70% by weight, the above weight percentages being relative to the total weight of the adhesive composition. The adhesive composition of the present invention has good high-temperature resistance.
Resin composition for adhesive, adhesive, and adhesion structure
The present invention provides a resin composition for an adhesive, being useful as a component of an adhesive having a favorable adhesion property to glass and giving favorable appearance after adhesion. The resin composition for an adhesive contains a polyhydroxyurethane resin. This polyhydroxyurethane resin contains a structural unit formed by polymerizing a compound (A) having at least two five-membered cyclic carbonate structures and a compound (B) having at least two primary amino groups, the polyurethane resin contains a urethane bond, a hydroxy group, and a secondary amino group in the structural unit. Further, this polyhydroxyurethane resin has an amine number of 1 to 50 mgKOH/g and has a hydroxyl number of 10 to 230 mgKOH/g.
Urethane adhesive cord treatment for power transmission belt and belt
A belt with a tensile cord embedded in an elastomeric body, having an adhesive composition impregnating the cord and coating the fibers. The adhesive composition is the reaction product of a polyisocyanate and a polyol, or a polyurethane prepolymer derived therefrom, and a polyamine curative and optionally additional polyol, and with optionally added plasticizer. At least one of the polyisocyanate, the prepolymer, and the polyamine are blocked with a blocking agent. The belt body may be of cast polyurethane, vulcanized rubber, or thermoplastic elastomer. The cord may have an adhesive overcoat.
Urethane adhesive cord treatment for power transmission belt and belt
A belt with a tensile cord embedded in an elastomeric body, having an adhesive composition impregnating the cord and coating the fibers. The adhesive composition is the reaction product of a polyisocyanate and a polyol, or a polyurethane prepolymer derived therefrom, and a polyamine curative and optionally additional polyol, and with optionally added plasticizer. At least one of the polyisocyanate, the prepolymer, and the polyamine are blocked with a blocking agent. The belt body may be of cast polyurethane, vulcanized rubber, or thermoplastic elastomer. The cord may have an adhesive overcoat.
ADHESIVE AGENT, LAMINATE, METHOD FOR MANUFACTURING LAMINATE, AND PACKAGING MATERIAL
Provided are a two-component curable adhesive which can be aged at room temperature and has favorable adhesiveness to various base materials, a laminate in which the adhesiveness between a base material and an adhesive is excellent even when aged at room temperature, and a packaging material including the laminate. The two-component curable adhesive includes a polyisocyanate composition (X) including a polyisocyanate compound (A) and a polyol composition (Y) including a polyol (B), in which a viscosity of the polyol composition at 50° C. is 20 mPa.Math.s or more and 180 mPa.Math.s or less.
USE OF DISPERSION ADHESIVES FOR FOAM BONDING
The invention relates to the use of an aqueous dispersion containing at least one polyurethane-polyurea polymer formed from (a) at least one difunctional polyester polyol having a number-average molecular weight of 400 to 5000 g/mol, (b) at least one difunctional polyol component having a number-average molecular weight of 762 to 399 g/mol, c) at least one diisocyanate and (d) at least one chain extender optionally having at least one ionic group, for the bonding of at least two substrates by application of the aqueous dispersion to at least one of the substrates to be bonded, subsequent drying of the dispersion present on the at least one substrate in order to obtain at least one adhesive layer, and contacting of the at least one adhesive layer with a further substrate or with an adhesive layer present on a further substrate at a pressure of from 0.1 to 5 bar(a) and a temperature of less than 40° C., wherein the polyurethane-polyurea polymer after the drying has a glass transition temperature Tg of from −65 to 10° C. and a melting point of from 40 to 80° C., to a corresponding process for joining at least two substrates, and to an adhesive composite obtained in this way and comprising at least two substrates and an adhesive layer present between every two substrates.
USE OF DISPERSION ADHESIVES FOR FOAM BONDING
The invention relates to the use of an aqueous dispersion containing at least one polyurethane-polyurea polymer formed from (a) at least one difunctional polyester polyol having a number-average molecular weight of 400 to 5000 g/mol, (b) at least one difunctional polyol component having a number-average molecular weight of 762 to 399 g/mol, c) at least one diisocyanate and (d) at least one chain extender optionally having at least one ionic group, for the bonding of at least two substrates by application of the aqueous dispersion to at least one of the substrates to be bonded, subsequent drying of the dispersion present on the at least one substrate in order to obtain at least one adhesive layer, and contacting of the at least one adhesive layer with a further substrate or with an adhesive layer present on a further substrate at a pressure of from 0.1 to 5 bar(a) and a temperature of less than 40° C., wherein the polyurethane-polyurea polymer after the drying has a glass transition temperature Tg of from −65 to 10° C. and a melting point of from 40 to 80° C., to a corresponding process for joining at least two substrates, and to an adhesive composite obtained in this way and comprising at least two substrates and an adhesive layer present between every two substrates.
AN AQUEOUS TWO-COMPONENT ADHESIVE
The invention relates to an aqueous two-component adhesive and use thereof, in particular to the use for laminating a rigid substrate and a plastic film, a laminated product comprising the adhesive, and a method for producing a laminated product. The aqueous two-component adhesive comprises component A and component B, the component A comprising more than 50% by weight and not more than 99% by weight of an aqueous polyurethane dispersion; the B component comprising 1% by weight to 16% by weight of water-dispersible modified polyisocyanate based on hexamethylene diisocyanate, the above weight percentage based on the amount of the adhesive being 100% by weight; wherein the aqueous polyurethane dispersion comprises polyurethane dispersed therein, the enthalpy of melting of the polyurethane being 26 to 100 J/g, preferably 30 to 100 J/g, particularly preferably 30 to 60 J/g, measured at 20° C. to 100° C. for the first heating curve by DSC according to DIN65467 (1999). The aqueous two-component adhesive has the advantages of safety and environmental protection, excellent performance and low laminating temperature.
RESIN COMPOSITION, LAYERED BODY INCLUDING RESIN COMPOSITION LAYER, LAYERED BODY, FLEXIBLE COPPER-CLAD LAMINATE, FLEXIBLE FLAT CABLE, AND ELECTROMAGNETIC WAVE SHIELDING FILM
A resin composition including a polyester polyurethane resin (A); and an epoxy resin (B), in which a molecular weight per a urethane bond of the polyester polyurethane resin (A) is from 200 to 8,000, and a layered body including a resin composition layer, a layered body, a flexible copper-clad laminate, a flexible flat cable, or an electromagnetic wave shielding film, each using the resin composition.