Polymers are disclosed that incorporate portions of secondary or tertiary polyamide segments connected with polyisocyanates. These polymers have enhanced matting properties. The enhanced matting properties are from creating an inherently matt surface from the polymer without the use of any separate fine particle size matting additives. Conventional matting agents such as fine particle size silica usually results in loss of physical properties such as haze development and porosity in the coating from the matting agent. Composites and hybrids of these polymers and other polyamides, polyurethane with vinyl polymers (acrylates) are also disclosed and claimed.

Embodiments of the present disclosure are directed towards solventless compositions that include a reaction product formed by reacting a polyol and an aminopolycarboxylic compound.

Embodiments of the present disclosure are directed towards solvent-based compositions that include a reaction product formed by reacting a polyol and an aminopolycarboxylic compound.

A process for preparing a crosslinkable composition comprising at least one alkoxysilane-terminated silyl polymer P, and at least one catalytic system B comprises: a. preparing an alkoxysilane-terminated silyl polymer P comprising: a-1) the polyaddition reaction between a composition of polyol(s) and a composition of polyisocyanate(s), in the presence of a catalyst A chosen from carboxylates based on bismuth and/or zinc, in order to prepare an NCO-terminated polymer; a-2) the reaction of the NCO-terminated polymer obtained in step a-1) with an organosilane compound having at least one function that is reactive with the —NCO function of the NCO-terminated polymer; and b. bringing the silyl polymer P obtained in step a) into contact with a catalytic crosslinking system B which is a mixture of zinc-based carboxylate(s) and cyclic amidine. The process is carried out in the absence of a tin-based catalyst.

The present invention relates to thermoset polymer solution, such as a polyurethanes and/or polyureas that include sufficient polyamide to give polyamide strength, adhesion, and durability, wherein the polymer solutions can be prepared as a one-component or two component solvent-borne coating composition. The polyamides give a harder, more chemical resistant, and often tougher thermoset, than similar water-borne polyurethanes rich in polyamide. The compositions of this disclosure differ from other polyamides as they have been formulated to be appropriate viscosity to use as coatings and then have crosslinking technology to form hard thermoset films.

The present invention relates to thermoset polymer solution, such as a polyurethanes and/or polyureas that include sufficient polyamide to give polyamide strength, adhesion, and durability, wherein the polymer solutions can be prepared as a one-component or two component solvent-borne coating composition. The polyamides give a harder, more chemical resistant, and often tougher thermoset, than similar water-borne polyurethanes rich in polyamide. The compositions of this disclosure differ from other polyamides as they have been formulated to be appropriate viscosity to use as coatings and then have crosslinking technology to form hard thermoset films.

A two-component adhesive composition is provided. The two-component adhesive composition comprises an isocyanate component, an isocyanate-reactive component and an polyether amine-epoxy silane adduct, and can achieve superior adhesion strength between the adhesive and a substrate like metal alloy substrate. A laminated article prepared with said composition, a method for preparing the article and the use of the polyether amine-epoxy silane adduct as adhesion promoter in a two-component polyurethane adhesive composition are also provided.

The present invention relates to a modified polyisocyanate and use thereof, in particular as a crosslinking component of water-soluble or water-dispersible coatings. The modified polyisocyanate is obtained by a reaction of a system comprising the following components: at least an aminosulfonic acid; at least a polyisocyanate; at least a tertiary amine; and optionally a polyether alcohol containing an ethylene oxide group. The modified polyisocyanate comprises at least an iminooxadiazinedione structure and at least an isocyanurate structure, the weight ratio of the iminooxadiazinedione structure to the isocyanurate structure being 1:300 to 1:5. The amount of sulfonate group of the modified polyisocyanate is 0.75% by weight to 1.1% by weight, based on the amount of the modified polyisocyanate as 100% by weight. The viscosity thereof is 500 mPa.Math.s to 10000 mPa.Math.s, as determined according to DIN EN ISO 3219:1994-10 at a temperature of 23° C. and a shear rate of 10 s.sup.−1. The coating comprising the modified polyisocyanate of the present invention can be manually stirred well, and the resulting coating layer has high gloss and good transparency.

The present invention relates to a modified polyisocyanate and use thereof, in particular as a crosslinking component of water-soluble or water-dispersible coatings. The modified polyisocyanate is obtained by a reaction of a system comprising the following components: at least an aminosulfonic acid; at least a polyisocyanate; at least a tertiary amine; and optionally a polyether alcohol containing an ethylene oxide group. The modified polyisocyanate comprises at least an iminooxadiazinedione structure and at least an isocyanurate structure, the weight ratio of the iminooxadiazinedione structure to the isocyanurate structure being 1:300 to 1:5. The amount of sulfonate group of the modified polyisocyanate is 0.75% by weight to 1.1% by weight, based on the amount of the modified polyisocyanate as 100% by weight. The viscosity thereof is 500 mPa.Math.s to 10000 mPa.Math.s, as determined according to DIN EN ISO 3219:1994-10 at a temperature of 23° C. and a shear rate of 10 s.sup.−1. The coating comprising the modified polyisocyanate of the present invention can be manually stirred well, and the resulting coating layer has high gloss and good transparency.

The use of an organocarbonate-modified prepolymer having at least an average of 1.5 carbonate, thiocarbonate, carbamate or thiocarbamate groups bonded directly to the polymer backbone each via an oxygen atom, where each of these oxygen atoms has its origin in the reaction of a primary, secondary or tertiary hydroxyl group of the polymer backbone and a reactive compound selected from the group consisting of a diorganocarbonate, a diorganothiocarbonate, a cyclic carbonate, a cyclic thiocarbonate, an N,N-diheterocyclourea derivative and an N,N-diheterocyclothiourea derivative. Also, the preparation of the alkoxysilane polymers.