The present invention relates to an adhesive, a preparation method and application thereof, particularly the application for bonding glass fiber composites, and a bonded article obtained by using the adhesive. The adhesive comprises: a polyisocyanate having an isocyanate functionality of not less than 2; an epoxy-modified polyether polyol; a hydroxyl-containing acrylate; a redox catalyst; a silane coupling agent; optionally a polyol containing bisphenol A structure; and optionally a polymer polyol different from the epoxy-modified polyether polyol. The adhesive according to the present invention has the advantages of being insensitive to moisture, good bonding properties and a long pot life.

The invention provides an adhesive coating material which realizes excellent adhesive strength and moist-heat resistance at the time of bonding a solar cell sealing material and a base sheet, a polyol composition for the coating material, a cured object of the adhesive coating material, an adhesive sheet obtained by being coated with adhesive coating material, and a solar cell module using the sheet. As a polyol component of the adhesive coating material which forms an adhesive layer b in a back sheet E of the solar cell module illustrated in Figure, a hydroxyl group-containing (meth)acrylic resin (I) and unsaturated double bond-containing polyester polyol (II) are used as essential components.

The invention provides an adhesive coating material which realizes excellent adhesive strength and moist-heat resistance at the time of bonding a solar cell sealing material and a base sheet, a polyol composition for the coating material, a cured object of the adhesive coating material, an adhesive sheet obtained by being coated with adhesive coating material, and a solar cell module using the sheet. As a polyol component of the adhesive coating material which forms an adhesive layer b in a back sheet E of the solar cell module illustrated in Figure, a hydroxyl group-containing (meth)acrylic resin (I) and unsaturated double bond-containing polyester polyol (II) are used as essential components.

A urethane oligomer according to a) or b) has: a) at least two backbone residues R issued from a polyisocyanate without the NCO groups, linked between them with a diol residue R.sub.B (diol without the two OH groups) by two urethane bonds and each backbone residues R carrying (or linked to) at least two urethane segments each containing at least one terminal allyl group, b) at least one backbone residue R issued from a polyisocyanate without the NCO groups, the backbone residue R carrying (or linked to) at least two urethane segments each linked to R by one urethane bond with at least one urethane segment (arm) containing at least one terminal allyl group, and at least one urethane segment (arm) containing at least one terminal (meth)acrylate group. A curable composition containing the urethane oligomer reduces oxygen inhibition in coatings, adhesives, sealants or in resin matrix with good surface properties.

A urethane oligomer according to a) or b) has: a) at least two backbone residues R issued from a polyisocyanate without the NCO groups, linked between them with a diol residue R.sub.B (diol without the two OH groups) by two urethane bonds and each backbone residues R carrying (or linked to) at least two urethane segments each containing at least one terminal allyl group, b) at least one backbone residue R issued from a polyisocyanate without the NCO groups, the backbone residue R carrying (or linked to) at least two urethane segments each linked to R by one urethane bond with at least one urethane segment (arm) containing at least one terminal allyl group, and at least one urethane segment (arm) containing at least one terminal (meth)acrylate group. A curable composition containing the urethane oligomer reduces oxygen inhibition in coatings, adhesives, sealants or in resin matrix with good surface properties.

The present invention relates to a process for the preparation of a polyurethane comprising: E1) a stage of preparation of a polyurethane having NCO endings comprising the polyaddition reaction between: i) at least one polyisocyanate; ii) at least one polyol; and iii) at least one amine having the following formula (I) or (II):

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and E2) the reaction of the product formed on conclusion of stage E1) with at least one (meth)acrylate or allyl monomer M comprising at least one hydroxyl functional group.

A formaldehyde free adhesive composition and a plywood obtained from the adhesive composition is provided, and the plywood has a balanced performance, such as high adhesion strength, sufficient pot-life, and good workability.

Provided is a method of manufacturing a liquid crystal panel employing a photocurable adhesive composition which causes no damage to adherends during bonding and which, when used in bonding rugged adherends, can bond the adherends without forming a gap therebetween. The photocurable adhesive composition of the inventive method comprises (A) 100 parts by mass of a urethane (meth)acrylate oligomer having a weight-average molecular weight of 20,000 to 100,000, (B) 5 parts to 70 parts by mass of a phenoxy resin, and (C) 0.1 parts to 10 parts by mass of a photopolymerization initiator. The uncured composition has a loss tangent (loss modulus/storage modulus) of less than 1 at 25° C. and the temperature at which the loss tangent of the uncured composition reaches 1 or more is 80° C. or less.

A composition includes methyl methacrylate MMA, at least one elastomer or a core-shell polymer, and at least one radical former, as an adhesive, sealant or coaling for gluing, sealing or coaling substrates containing plasticized PVC.

A composition includes methyl methacrylate MMA, at least one elastomer or a core-shell polymer, and at least one radical former, as an adhesive, sealant or coaling for gluing, sealing or coaling substrates containing plasticized PVC.