A moisture curable resin composition has excellent adhesiveness to aluminum, and it also has excellent rapid curability and thick film curability by moisture without using an organic tin catalyst. A moisture curable resin composition contains the following (A) to (C) components: (A) component: a polyoxyalkylene having a hydrolyzable silyl group at both terminals; (B) component: a zinc-based catalyst; and (C) component: a compound having one hydrolyzable silyl group and at least one amino group in one molecule. The (B) component is contained in a predetermined amount per 100 parts by mass of the (A) component.

A moisture curable resin composition has excellent adhesiveness to aluminum, and it also has excellent rapid curability and thick film curability by moisture without using an organic tin catalyst. A moisture curable resin composition contains the following (A) to (C) components: (A) component: a polyoxyalkylene having a hydrolyzable silyl group at both terminals; (B) component: a zinc-based catalyst; and (C) component: a compound having one hydrolyzable silyl group and at least one amino group in one molecule. The (B) component is contained in a predetermined amount per 100 parts by mass of the (A) component.

This curable fluoropolyether adhesive composition contains specific amounts of (A) a straight-chain polyfluoro compound having two or more alkenyl groups per molecule, and having a perfluoropolyether structure in the main chain thereof, (B) a fluorine-containing organohydrogen siloxane having, per molecule, a perfluoroalkyl group, a perfluoro oxyalkyl group, a perfluoro alkylene group, or perfluoro oxyalkylene group, and two or more SiH groups, and not having an epoxy group or an alkoxy group directly bonded to a silicon atom. (C) sodium fluoride. (D) a platinum-group metal catalyst, and (E) an organopolysiloxane having, per molecule, a SiH group, a perfluoroalkyl group or a perfluoro oxyalkyl group, and an epoxy group and/or a trialkoxysilyl group.

A cured product of the composition has good light transmission properties and good adhesion properties, and excellent rubber strength.

Provided is a curable silicone composition for a release agent which can form a release film having a silicone adhesive with a low release force even when thin and which does not reduce the adhesive strength of the silicone adhesive to other substrates upon releasing the release film. A release film and laminate are also provided. The curable silicone composition comprises: (A) a fluorine-containing organopolysiloxane mixture obtained by mixing the following components (A1) and (A2) at a mass ratio of 1/99 to 45/55: (A1) a fluoro(poly)ether modified organopolysiloxane having at least two alkenyl groups per molecule along with a fluoro(poly)ether-containing organic group; (A2) a fluoroalkyl group-containing organopolysiloxane having at least two alkenyl groups per molecule along with a fluoroalkyl group having 1 to 12 carbon atoms; (B) an organopolysiloxane having at least three silicon atom-bonded hydrogen atoms per molecule; (C) a hydrosilylation reaction catalyst; and (D) an organic solvent.

The present invention relates a hydroxyl-functionalized unimodal polysiloxane polyalkyleneglycol brush copolymer of the structure [A(-X—B)].sub.s, wherein: A represents said polysiloxane backbone; B represents said polyalkyleneglycol side chain; X is a linker group characterized by including the moiety Si—C—C— of which said Si is a part of the polysiloxane backbone A; and s is an integer of from 1 to 100, wherein the polysiloxane backbone A contains less than 500 ppm mol % of SiH moiety based on the total moles of the silicon atom which constitutes the polysiloxane backbone, and said copolymer has a polydispersity index of from 1.3 to 5.0; and a method for producing said hydroxyl-functionalized unimodal polysiloxane polyalkyleneglycol brush copolymer.

The invention relates to a curable composition comprising: a) at least one polymer having at least one silicon-containing group of formula —Si(R.sup.1).sub.k(Y).sub.3-k as defined herein, and b) at least one hydroxyl-functionalized polysiloxane polyalkyleneglycol brush copolymer of the structure [A(-X—B)].sub.s as defined herein; and an adhesive, sealant, or coating material comprising said curable composition and use thereof.

The invention relates to a curable composition comprising: a) at least one polymer having at least one silicon-containing group of formula —Si(R.sup.1).sub.k(Y).sub.3-k as defined herein, and b) at least one hydroxyl-functionalized polysiloxane polyalkyleneglycol brush copolymer of the structure [A(-X—B)].sub.s as defined herein; and an adhesive, sealant, or coating material comprising said curable composition and use thereof.

The invention relates to a curable composition comprising: a) at least one polymer having at least one silicon-containing group of formula —Si(R.sup.1).sub.k(Y).sub.3-k as defined herein, and b) at least one hydroxyl-functionalized polysiloxane polyalkyleneglycol brush copolymer of the structure [A(-X—B)].sub.s as defined herein; and an adhesive, sealant, or coating material comprising said curable composition and use thereof.

Provided is a curable composition that can, when cured, form a cured product having adhesiveness and adhesion to an adherend at excellent levels. The curable composition contains a polyorganosilsesquioxane and one of (A) a compound represented by Formula (X); and (B) a polymerization stabilizer, where Formula (X) is expressed as follows: ##STR00001##
wherein r1 represents an integer from 4 to 20; L represents a group containing epoxy, oxetanyl or vinyl ether group; R.sup.11 and R.sup.12 each represent an optionally substituted hydrocarbon group; s1 represents an integer from 1 to 3; t1 represents an integer from 0 to 2, where s1 plus t1 equals 3; and R.sup.13 and R.sup.14 are selected from hydrogen and an optionally substituted hydrocarbon group. The polyorganosilsesquioxane has a number-average molecular weight of 1000 to 3000 and a molecular-weight dispersity of 1.0 to 3.0, includes a constitutional unit represented by Formula (1), has a ratio of a constitutional unit represented by Formula (I) to a constitutional unit represented by Formula (II) of 5 or more, and has a total proportion of the constitutional unit represented by Formula (1) and a constitutional unit represented by Formula (4) of 55 to 100 mole percent of all siloxane constitutional units. [R.sup.1SiO.sub.3/2] (1), [R.sup.aSiO.sub.3/2] (I), [R.sup.bSiO.sub.2/2(OR.sup.c)] (II), [R.sup.1SiO.sub.2/2(OR.sup.c)] (4), where R.sup.1 represents an epoxy-containing group; R.sup.a and R.sup.b are each selected from an epoxy-containing group, substituted or unsubstituted aryl, substituted or unsubstituted aralkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkyl, substituted or unsubstituted alkenyl, and hydrogen; and R.sup.c is selected from hydrogen and C.sub.1-C.sub.4 alkyl.

Provided is a curable composition that can, when cured, form a cured product having adhesiveness and adhesion to an adherend at excellent levels. The curable composition contains a polyorganosilsesquioxane and one of (A) a compound represented by Formula (X); and (B) a polymerization stabilizer, where Formula (X) is expressed as follows: ##STR00001##
wherein r1 represents an integer from 4 to 20; L represents a group containing epoxy, oxetanyl or vinyl ether group; R.sup.11 and R.sup.12 each represent an optionally substituted hydrocarbon group; s1 represents an integer from 1 to 3; t1 represents an integer from 0 to 2, where s1 plus t1 equals 3; and R.sup.13 and R.sup.14 are selected from hydrogen and an optionally substituted hydrocarbon group. The polyorganosilsesquioxane has a number-average molecular weight of 1000 to 3000 and a molecular-weight dispersity of 1.0 to 3.0, includes a constitutional unit represented by Formula (1), has a ratio of a constitutional unit represented by Formula (I) to a constitutional unit represented by Formula (II) of 5 or more, and has a total proportion of the constitutional unit represented by Formula (1) and a constitutional unit represented by Formula (4) of 55 to 100 mole percent of all siloxane constitutional units. [R.sup.1SiO.sub.3/2] (1), [R.sup.aSiO.sub.3/2] (I), [R.sup.bSiO.sub.2/2(OR.sup.c)] (II), [R.sup.1SiO.sub.2/2(OR.sup.c)] (4), where R.sup.1 represents an epoxy-containing group; R.sup.a and R.sup.b are each selected from an epoxy-containing group, substituted or unsubstituted aryl, substituted or unsubstituted aralkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkyl, substituted or unsubstituted alkenyl, and hydrogen; and R.sup.c is selected from hydrogen and C.sub.1-C.sub.4 alkyl.