Provided are reactive silicon group-containing polymers and a curable composition containing said polymers. The curable composition provides a cured product having a low modulus, flexibility, excellent tensile strength, tensile elongation, and tear strength. The curable composition can also exhibit excellent rapid curing properties even when a low-activity catalyst has been added. In the reactive silicon group-containing polymer, a reactive silicon group, indicated by general formula (1): (Si(R.sup.1).sub.3-a(X).sub.a), is bonded to the molecular chain of the polymer and an atom adjacent to the reactive silicon group has an unsaturated bond. In general formula (1), each R.sup.1 can independently indicate a C1-20 hydrocarbon group, and the R.sup.1 hydrocarbon groups can be substituted and a hetero-containing group can be used. X can be a hydroxyl group or a hydrolyzable group, and a is 1, 2, or 3.

Provided are reactive silicon group-containing polymers and a curable composition containing said polymers. The curable composition provides a cured product having a low modulus, flexibility, excellent tensile strength, tensile elongation, and tear strength. The curable composition can also exhibit excellent rapid curing properties even when a low-activity catalyst has been added. In the reactive silicon group-containing polymer, a reactive silicon group, indicated by general formula (1): (Si(R.sup.1).sub.3-a(X).sub.a), is bonded to the molecular chain of the polymer and an atom adjacent to the reactive silicon group has an unsaturated bond. In general formula (1), each R.sup.1 can independently indicate a C1-20 hydrocarbon group, and the R.sup.1 hydrocarbon groups can be substituted and a hetero-containing group can be used. X can be a hydroxyl group or a hydrolyzable group, and a is 1, 2, or 3.

Provided is a method of producing a pressure-sensitive adhesive containing a cured product of a curable composition containing a crosslinkable silicon group-containing organic polymer and an adhesion-imparting resin as a pressure-sensitive adhesive layer; curing of the curable composition does not proceed when heated during production, i.e., the curable composition has excellent stability when heated, and the crosslinking reaction of the curable composition proceeds by some sort of trigger. The pressure-sensitive adhesive contains, as a pressure-sensitive adhesive layer, a cured product of a curable composition containing (A) a crosslinkable silicon group-containing organic polymer, (B) an adhesion-imparting resin, (C) a SiF bond-containing silicon compound, and (D) a photobase generator.

Provided is a method of producing a pressure-sensitive adhesive containing a cured product of a curable composition containing a crosslinkable silicon group-containing organic polymer and an adhesion-imparting resin as a pressure-sensitive adhesive layer; curing of the curable composition does not proceed when heated during production, i.e., the curable composition has excellent stability when heated, and the crosslinking reaction of the curable composition proceeds by some sort of trigger. The pressure-sensitive adhesive contains, as a pressure-sensitive adhesive layer, a cured product of a curable composition containing (A) a crosslinkable silicon group-containing organic polymer, (B) an adhesion-imparting resin, (C) a SiF bond-containing silicon compound, and (D) a photobase generator.

The present invention relates to a multicomponent adhesive composition comprising: a composition A comprising: at least one silyl polymer comprising at least one hydrolyzable alkoxysilane group; at least one tackifying resin; a composition B comprising: at least one catalyst; at least one compound C chosen from: a compound C1 with a number-average molecular mass ranging from 300 g/mol to 500 000 g/mol; and a compound C2 with a vapor pressure at 20 C. of greater than or equal to 0.08 kPa; and mixtures thereof;
the composition A:composition B mass ratio ranging from 99.98:0.02 to 60:40, the total content of catalyst ranging from 0.01% to 10% relative to the total weight of said adhesive composition.

A method for producing crosslinkable compositions (M) by mixing (A) 100 parts by weight of compounds of the formula Y[(CR.sup.1.sub.2).sub.bSiR.sub.a(OR.sup.2).sub.3-a].sub.x (I) and (B) 0.1 to 75 parts by weight of at least one thixotropic agent. The at least one thixotropic agent is selected from fatty acid amides, polyamide waxes, polyamide wax derivatives, hydrogenated castor oil, hydrogenated castor oil derivatives, polyester amides, polyureas, oxidized polyethylenes and metal soaps and optionally further components. The period of time from the start of the mixing step of (A) and (B) to the end of storage of the crosslinkable composition (M) is at least 7 days and during this period all process steps are carried out at temperatures below 59 C.

A method for producing crosslinkable compositions (M) by mixing (A) 100 parts by weight of compounds of the formula Y[(CR.sup.1.sub.2).sub.bSiR.sub.a(OR.sup.2).sub.3-a].sub.x (I) and (B) 0.1 to 75 parts by weight of at least one thixotropic agent. The at least one thixotropic agent is selected from fatty acid amides, polyamide waxes, polyamide wax derivatives, hydrogenated castor oil, hydrogenated castor oil derivatives, polyester amides, polyureas, oxidized polyethylenes and metal soaps and optionally further components. The period of time from the start of the mixing step of (A) and (B) to the end of storage of the crosslinkable composition (M) is at least 7 days and during this period all process steps are carried out at temperatures below 59 C.

Disclosed is a moisture curable silane modified terpolymer comprising a polyether segment, a segment of polytetrahydrofuran or polycarbonate, a polysiloxane segment and terminal amino silane groups joined to the terpolymer via urethane linkages and wherein the polyether segment comprises at least 70% by weight based on the total weight of the silane modified terpolymer. Also disclosed is a method of forming moisture curable silane modified terpolymer.

Disclosed is a moisture curable silane modified terpolymer comprising a polyether segment, a segment of polytetrahydrofuran or polycarbonate, a polysiloxane segment and terminal amino silane groups joined to the terpolymer via urethane linkages and wherein the polyether segment comprises at least 70% by weight based on the total weight of the silane modified terpolymer. Also disclosed is a method of forming moisture curable silane modified terpolymer.

An adhesive which includes at least one silane-functional polymer P; at least one catalyst for crosslinking silane-functional polymers, the catalyst being selected from the group including organo-titanate, organo-zirconate, and organo-aluminate; at least one base; and at least one adhesive selected from alkoxy mercaptosilane and amino alkoxysilane, for filling wood joints. The adhesive filled into the joints is preferably sanded after the curing process. The adhesive exhibits a high UV stability and a stability against warm humid climates. The adhesive is therefore suitable for naval applications in particular, such as in the construction of boats and ships. The adhesive can be formulated so as to be black, white, or gray for example.