An autohesive polymer material that includes: at least one polymer having at least two terminal silyl groups of the Formula (1) given by:
Si(R.sup.1).sub.a(R.sup.2).sub.b  (1).
Each of the radicals R.sup.1 comprises an alkyl, alkenyl or aryl group or a hydrogen atom. Each of the radicals R.sup.2 comprises a group that can be eliminated with water, b is 1, 2 or 3, and a is 3−b. The polymer material further includes at least one condensation catalyst. Further, the polymer material is chemically precrosslinked and further crosslinkable with moisture. In addition, the polymer material is configured for use as a layer body that can be applied to a substrate. The polymer material of this kind can also be used for producing permanent bonds.

This invention relates to adhesive compositions comprising a polyester polyol that includes residues of at least one 2, 2, 4, 4-tetraalkylcyclobutane-1, 3-diol, including, for example, 2, 2, 4, 4-tetramethylcyclobutane-1, 3-diol (TMCD). Adhesive compositions as described herein exhibit enhanced properties as compared to conventional adhesive compositions, and may be suitable for a wide variety of end use applications, including, flexible packaging, woodworking, automotive uses, and electronics.

A moisture-curing polyurethane composition including: at least one isocyanate-functional polymer with a content of monomeric isophorone diisocyanate of below 0.5 weight-%, obtained from the reaction of isophorone diisocyanate and at least one polyol, and at least one aldimine of formula (I). The composition has a low toxicity, good shelf life stability and cures quickly to an elastic material of low surface tack and good mechanical properties, particularly in terms of high tensile strength and modulus of elasticity at high elongation. It enables coatings, sealants and adhesives with excellent stability under outdoor weathering conditions and high UV load. The aldimine of formula (I) allows to overcome the drawbacks caused by the removal of most of the monomeric isophorone diisocyanate in terms of cure speed, surface tackiness and final strength of such compositions.

One-component, moisture-curable polyurethane adhesives exhibit excellent handling strength before being fully cured, and excellent creep properties after curing. The adhesives include an isocyanate-terminated prepolymer made from polyols that include a crystalline polyester and hydroquinone bis (2-hydroxyethyl) ether, and a polyoxazolidine compound.

Disclosed is a moisture reactive polyurethane hot melt adhesive composition prepared from a mixture comprising a polyisocyanate, a polyester polyol, a polyether polyol; a thermoplastic polymer; inorganic filler; optionally a MA-SCA acid; and optionally one or more additives; wherein the polyester polyol is polymerized from a diacid and a diol; wherein the structure of the diacid is HOOC—(CH.sub.2).sub.m—COOH; wherein the structure of the diol is HO—(CH.sub.2).sub.n—OH; wherein the sum of (m+n) is equal to or less than 8; and wherein the acid number of the polyester polyol is less than 0.9. The disclosed reactive hot melt adhesive composition has improved thermal stability compared to conventional moisture reactive polyurethane hot melt adhesive compositions while maintaining their desirable properties.

Provided herein are materials, methods of making materials, and methods of use, wherein the materials have switchable adhesive properties. Materials of the present disclosure can reversibly change coloration in conjunction with the changing adhesive state. The films, made from a porous polymer material, can be reversibly changed from a smooth state to a rough state, allowing for reversible and tunable gripping and/or adhesive properties.

A dry shape memory adhesive material for adhering a target surface in the presence of fluid and for providing tunable mechanical contraction of an adhered surface. The dry shape memory adhesive material is pre-stretched and dried to provide an adhesive structure that implements a hydration-based shape memory mechanism to achieve both uniaxial and biaxial contractions of the adhered surface. According to preferred embodiments, the shape memory adhesive material includes a combination of one or more hydrophilic polymers or copolymers, one or more amine coupling group, and one or more cross linkers.

A labeling system for use with containers, comprising at least one linerless label, wherein the at least one linerless label is adapted to receive printing thereon; a substrate for receiving the label and to which the label becomes permanently bound after the label has been attached to the substrate; a first adhesive, wherein the first adhesive is a repositionable adhesive; a second adhesive, wherein the second adhesive is a remoistenable adhesive that includes predetermined amounts of polyvinyl alcohol, dextrin, and at least one humectant, and wherein the adhesives are deposited on the label prior to attaching the label to the substrate.

A labeling system for use with containers, including at least one linerless label, wherein the at least one linerless label is configured to receive printing thereon; a substrate for receiving the label and to which the label becomes permanently bound after the label has been attached to the substrate; at least one adhesive, wherein the adhesive is either substantially dry or tacky prior to being activated; moist or wet after being activated; or wet prior to application, and wherein the adhesive may be deposited on the label or on the substrate prior to attaching the label to the substrate; and where necessary, an activator for activating the adhesive and controlling the rate of drying thereof.

Described herein is a polyurethane having an isocyanate group and having C—C double bonds on a side chain, a process for preparing such a polyurethane, and an UV-moisture dual cure polyurethane reactive hotmelt including the polyurethane.