Drilling fluid compositions and methods for using drilling fluid compositions are provided with enhanced anti-bit balling properties that include an aqueous-based fluid, one or more drilling fluid additives, and an anti-bit balling additive. The anti-bit balling additive may be an epoxidized α-olefin and the drilling fluid may include the anti-bit balling additive in an amount ranging from about 0.5 ppb to about 20 ppb. Methods for using the drilling fluid compositions may further include mixing an aqueous base fluid with one or more drilling fluid additives and an anti-bit balling additive, wherein the anti-bit balling additive includes epoxidized α-olefin and the drilling fluid may include the anti-bit balling additive in an amount ranging from about 0.5 ppb to about 20 ppb, and introducing the drilling fluid to a subterranean formation.

The present disclosure provides water-based well treatment fluids for use in treating subterranean formations to prevent swelling and/or migration of fines. The water-based well treatment fluid contains an aqueous continuous phase, a clay stabilizing agent consisting of an alkylated polyetheramine and a weighting material. In addition to inhibiting swelling and/or migration, the water-based well treatment fluids are thermally stable, are toxicologically safe, and have exceptional handling properties.

The present disclosure provides water-based well treatment fluids for use in treating subterranean formations to prevent swelling and/or migration of fines. The water-based well treatment fluid contains an aqueous continuous phase, a clay stabilizing agent consisting of an alkylated polyetheramine and a weighting material. In addition to inhibiting swelling and/or migration, the water-based well treatment fluids are thermally stable, are toxicologically safe, and have exceptional handling properties.

Drilling fluid compositions include invert emulsion fluids having an oleaginous phase, an aqueous phase, and an emulsifier composition that includes an ethoxylated alcohol compound and a polyaminated fatty acid compound. The ethoxylated alcohol compound has the formula R.sup.1—(OCH.sub.2CH.sub.2).sub.n—OH, where R.sup.1 is a hydrocarbyl group having from 8 to 22 carbon atoms and n is from 1 to 8. The ethoxylated alcohol compound has a Hydrophilic-Lipophilic Balance (HLB) of less than or equal to 6. The polyaminated fatty acid compound has the formula R.sup.2—CO—NH—CH.sub.2—CH.sub.2—N(COR.sup.2)—CH.sub.2—CH.sub.2—NH—CO—R.sup.3, where R.sup.2 is a hydrocarbyl group having from 1 to 20 carbon atoms and R.sup.3 is a hydrocarbyl group having from 1 to 10 carbon atoms or an alkylene carboxylate group having formula —R.sup.4—COOH, where R.sup.4 is a saturated or unsaturated hydrocarbylene having from 1 to 10 carbon atoms. Methods of drilling wells include operating a drill in a wellbore in the presence of drilling fluid compositions.

Drilling fluid compositions include invert emulsion fluids having an oleaginous phase, an aqueous phase, and an emulsifier composition that includes an ethoxylated alcohol compound and a polyaminated fatty acid compound. The ethoxylated alcohol compound has the formula R.sup.1—(OCH.sub.2CH.sub.2).sub.n—OH, where R.sup.1 is a hydrocarbyl group having from 8 to 22 carbon atoms and n is from 1 to 8. The ethoxylated alcohol compound has a Hydrophilic-Lipophilic Balance (HLB) of less than or equal to 6. The polyaminated fatty acid compound has the formula R.sup.2—CO—NH—CH.sub.2—CH.sub.2—N(COR.sup.2)—CH.sub.2—CH.sub.2—NH—CO—R.sup.3, where R.sup.2 is a hydrocarbyl group having from 1 to 20 carbon atoms and R.sup.3 is a hydrocarbyl group having from 1 to 10 carbon atoms or an alkylene carboxylate group having formula —R.sup.4—COOH, where R.sup.4 is a saturated or unsaturated hydrocarbylene having from 1 to 10 carbon atoms. Methods of drilling wells include operating a drill in a wellbore in the presence of drilling fluid compositions.

Working fluids, such as drilling fluids, may remove heat from other fluids, tools, equipments and environments and transfer it to other locations by using reversible phase change elements. The heat removal occurs through the absorption of heat by one or more phase transitions or a sequence of phase transitions in the elements of the working fluid. For instance, heat is absorbed when the phase change portions of the reversible phase change elements change phase including, but not necessarily limited to, a change from solid to smectic liquid crystal, from solid to nematic liquid crystal, from smectic liquid crystal to isotropic liquid, from nematic liquid crystal to isotropic liquid, from solid to isotropic liquid, and sequences and combinations thereof. Heat is released when the phase change reverses. These phase changes are first-order transitions and are associated with a latent heat or enthalpy.

Working fluids, such as drilling fluids, may remove heat from other fluids, tools, equipments and environments and transfer it to other locations by using reversible phase change elements. The heat removal occurs through the absorption of heat by one or more phase transitions or a sequence of phase transitions in the elements of the working fluid. For instance, heat is absorbed when the phase change portions of the reversible phase change elements change phase including, but not necessarily limited to, a change from solid to smectic liquid crystal, from solid to nematic liquid crystal, from smectic liquid crystal to isotropic liquid, from nematic liquid crystal to isotropic liquid, from solid to isotropic liquid, and sequences and combinations thereof. Heat is released when the phase change reverses. These phase changes are first-order transitions and are associated with a latent heat or enthalpy.

Drilling fluid compositions and methods for using drilling fluid compositions are provided with enhanced anti-bit balling properties that include an aqueous-based fluid, one or more drilling fluid additives, and an anti-bit balling additive. The anti-bit balling additive may be an epoxidized α-olefin and the drilling fluid may include the anti-bit balling additive in an amount ranging from about 0.5 ppb to about 20 ppb. Methods for using the drilling fluid compositions may further include mixing an aqueous base fluid with one or more drilling fluid additives and an anti-bit balling additive, wherein the anti-bit balling additive includes epoxidized α-olefin and the drilling fluid may include the anti-bit balling additive in an amount ranging from about 0.5 ppb to about 20 ppb, and introducing the drilling fluid to a subterranean formation.

Disclosed herein are compositions and methods for increasing recovery, or flowback, of hydrocarbon compounds from hydrocarbon-containing subterranean fractured rock formations (tight shale reservoirs). The flowback compositions include an anionic dimer surfactant, an anionic monomer surfactant, and a demulsifier. The flowback compositions convert oil-wet rocks to water-wet, yet exhibit a low tendency of composition components to sorb to the rock. The flowback compositions do not cause formation of emulsions with hydrocarbon compounds within the subterranean fractured rock formations. The flowback composition are useful for increasing the yield of hydrocarbons recovered from tight shale reservoirs.

Disclosed herein are compositions and methods for increasing recovery, or flowback, of hydrocarbon compounds from hydrocarbon-containing subterranean fractured rock formations (tight shale reservoirs). The flowback compositions include an anionic dimer surfactant, an anionic monomer surfactant, and a demulsifier. The flowback compositions convert oil-wet rocks to water-wet, yet exhibit a low tendency of composition components to sorb to the rock. The flowback compositions do not cause formation of emulsions with hydrocarbon compounds within the subterranean fractured rock formations. The flowback composition are useful for increasing the yield of hydrocarbons recovered from tight shale reservoirs.