In a well in a subterranean formation, treatment fluids for time-released iron control are utilized. These treatment fluids contain a time-released form of a complexing agent, wherein the complexing agent forms an insoluble complex with iron. The time-released form prevents loss of the agent prior to delivery to the desired site and at the desired time(s). Methods for controlling iron in a well in a subterranean formation utilize these treatment fluids containing a time-released form of a complexing agent and these methods create insoluble complexes of the agent with the iron to control the iron from the formation and/or well.

In a well in a subterranean formation, treatment fluids for time-released iron control are utilized. These treatment fluids contain a time-released form of a complexing agent or reducing agent, wherein the agent forms a soluble product with iron. The time-released form prevents loss of the agent prior to delivery to the desired site and at the desired time(s). Methods for controlling iron in a well in a subterranean formation utilize these treatment fluids containing a time-released form of a complexing agent or reducing agent and these methods create soluble products when the agent interacts with the iron to control the iron from the formation and/or well.

In a well in a subterranean formation, treatment fluids for time-released iron control are utilized. These treatment fluids contain a time-released form of a complexing agent or reducing agent, wherein the agent forms a soluble product with iron. The time-released form prevents loss of the agent prior to delivery to the desired site and at the desired time(s). Methods for controlling iron in a well in a subterranean formation utilize these treatment fluids containing a time-released form of a complexing agent or reducing agent and these methods create soluble products when the agent interacts with the iron to control the iron from the formation and/or well.

Methods for delivering treatment chemicals into a subterranean formation using treatment fluids that include nanoemulsions are provided. In some embodiments, the methods include providing a treatment fluid including an aqueous base fluid and a nanoemulsion including a water-soluble internal phase, a water-soluble external phase, and a surfactant, the nanoemulsion being formed by mechanically-induced shear rupturing; and introducing the treatment fluid into at least a portion of a subterranean formation at or above a pressure sufficient to create or enhance at least one fracture in the subterranean formation.

Well treatment fluids may include solid particles comprising one or more components selected from the group consisting of urea, ammonium nitrate, ammonium chloride, barium hydroxide, and ammonium thiocyanate. These well treatment fluids may also include a carrier fluid, which may be an aqueous polymeric fluid, an oil, or combinations thereof. The aqueous polymeric fluid may include a polymer selected from the group consisting of guar gum, hydroxypropyl guar, carboxymethyl hydroxypropyl guar, cellulose, or polyacrylamide. The oil may include a material selected from the group consisting of diesel, mineral oil, and wax. Methods for reducing an acid carbonate reaction in a carbonate formation may include pumping a composition of solid particles into a formation; releasing the solid particles from the capsules or emulsion within the formation; and injecting an acid following the releasing step or during pumping, wherein the acid carbonate reaction is carried out at a reduced reaction rate.

Well treatment fluids may include solid particles comprising one or more components selected from the group consisting of urea, ammonium nitrate, ammonium chloride, barium hydroxide, and ammonium thiocyanate. These well treatment fluids may also include a carrier fluid, which may be an aqueous polymeric fluid, an oil, or combinations thereof. The aqueous polymeric fluid may include a polymer selected from the group consisting of guar gum, hydroxypropyl guar, carboxymethyl hydroxypropyl guar, cellulose, or polyacrylamide. The oil may include a material selected from the group consisting of diesel, mineral oil, and wax. Methods for reducing an acid carbonate reaction in a carbonate formation may include pumping a composition of solid particles into a formation; releasing the solid particles from the capsules or emulsion within the formation; and injecting an acid following the releasing step or during pumping, wherein the acid carbonate reaction is carried out at a reduced reaction rate.

A variety of methods, systems, and compositions are disclosed, including, in one embodiment, a method of servicing a borehole including providing a borehole servicing fluid in a borehole penetrating a subterranean formation, wherein the borehole servicing fluid includes a nucleophilic organic molecule and an electrophile. The method further may include reacting the nucleophilic organic molecule and the electrophile to generate at least an acidic species. The method further may include contacting an acid-soluble component in the subterranean formation with the acidic species such that the acidic species degrades the acid-soluble component.

A variety of methods, systems, and compositions are disclosed, including, in one embodiment, a method of servicing a borehole including providing a borehole servicing fluid in a borehole penetrating a subterranean formation, wherein the borehole servicing fluid includes a nucleophilic organic molecule and an electrophile. The method further may include reacting the nucleophilic organic molecule and the electrophile to generate at least an acidic species. The method further may include contacting an acid-soluble component in the subterranean formation with the acidic species such that the acidic species degrades the acid-soluble component.

An aqueous synthetic acid composition is disclosed for use in oil industry activities, the composition comprising: lysine and hydrogen chloride in a molar ratio ranging from 1 to 1:12.5, preferably from more than 1:5 to 1:8.5. The composition can also further comprise a metal iodide or iodate; an alcohol or derivative thereof. The composition demonstrates advantageous properties over known synthetic acids at temperatures above 90° C. The composition is useful in various oil and gas industry operations. Preferred embodiments of the composition provide substantial advantages in matrix acidizing by increasing the effectiveness of wormholing as compared to conventional mineral acids such as HCl.

An aqueous synthetic acid composition is disclosed for use in oil industry activities, the composition comprising: lysine and hydrogen chloride in a molar ratio ranging from 1 to 1:12.5, preferably from more than 1:5 to 1:8.5. The composition can also further comprise a metal iodide or iodate; an alcohol or derivative thereof. The composition demonstrates advantageous properties over known synthetic acids at temperatures above 90° C. The composition is useful in various oil and gas industry operations. Preferred embodiments of the composition provide substantial advantages in matrix acidizing by increasing the effectiveness of wormholing as compared to conventional mineral acids such as HCl.