Patent classifications
C09K8/82
Latent curing agent compatible with low pH frac fluids
A method of treating a subterranean formation including providing a treatment fluid comprising a hardenable acid curable resin and a hydrolysable strong acid ester. The treatment fluid is combined with a diluent fluid and is introduced into a subterranean formation. Upon the hydrolyzing of the ester in the formation and the contacting of unconsolidated proppants, the treatment method produces consolidated proppants.
SMART FRACTURING FLUID
Among the methods provided is a method comprising: providing a fracturing fluid that comprises a base fluid and an additive having a high dielectric constant; and introducing the fracturing fluid into least a portion of a subterranean formation.
ENHANCEMENTS OF GELLED HYDROCARBON SYSTEMS
Gelled hydrocarbon fracturing fluids and their methods of preparation and use are provided. The gelled hydrocarbon fracturing fluid includes a hydrocarbon fluid, a phosphate ester, a crosslinker and a viscosifier. The crosslinker may include iron, aluminum, or combinations thereof and the viscosifier may include clay, graphite, carbon nanotubes, metallic oxide nanoparticles, and combinations thereof. The method of preparation includes combining a hydrocarbon fluid, phosphate ester, and crosslinker to form a baseline fluid. A viscosifier is added to the baseline fluid to form a gelled hydrocarbon fracturing fluid. The method of use includes treating a subterranean formation by contacting a subterranean formation with a gelled hydrocarbon fracturing fluid and generating at least one fracture in the subterranean formation.
Dual-purpose viscosifier and surface active additives and methods of use
Dual-purpose additives that may be used as viscosifying agents and surface active agents in fluids, subterranean treatments and oilfield operations are provided. In one embodiment, the methods comprise: providing a treatment fluid comprising a base fluid and a polymeric dual-purpose additive comprising a base polymer comprising a plurality of monomer units, and one or more hydrophobic groups bonded to at least one of the monomer units; introducing the treatment fluid into at least a portion of a subterranean formation; and depolymerizing at least a portion of the dual-purpose additive to form one or more surface active fragments, each of the surface active fragments comprising one or more of the hydrophobic groups bonded to one or more of the monomer units.
Dual-purpose viscosifier and surface active additives and methods of use
Dual-purpose additives that may be used as viscosifying agents and surface active agents in fluids, subterranean treatments and oilfield operations are provided. In one embodiment, the methods comprise: providing a treatment fluid comprising a base fluid and a polymeric dual-purpose additive comprising a base polymer comprising a plurality of monomer units, and one or more hydrophobic groups bonded to at least one of the monomer units; introducing the treatment fluid into at least a portion of a subterranean formation; and depolymerizing at least a portion of the dual-purpose additive to form one or more surface active fragments, each of the surface active fragments comprising one or more of the hydrophobic groups bonded to one or more of the monomer units.
Drilling fluid additives and fracturing fluid additives containing cellulose nanofibers and/or nanocrystals
This disclosure provides drilling fluids and additives as well as fracturing fluids and additives that contain cellulose nanofibers and/or cellulose nanocrystals. In some embodiments, hydrophobic nanocellulose is provided which can be incorporated into oil-based fluids and additives. These water-based or oil-based fluids and additives may further include lignosulfonates and other biomass-derived components. Also, these water-based or oil-based fluids and additives may further include enzymes. The drilling and fracturing fluids and additives described herein may be produced using the AVAP® process technology to produce a nanocellulose precursor, followed by low-energy refining to produce nanocellulose for incorporation into a variety of drilling and fracturing fluids and additives.
Drilling fluid additives and fracturing fluid additives containing cellulose nanofibers and/or nanocrystals
This disclosure provides drilling fluids and additives as well as fracturing fluids and additives that contain cellulose nanofibers and/or cellulose nanocrystals. In some embodiments, hydrophobic nanocellulose is provided which can be incorporated into oil-based fluids and additives. These water-based or oil-based fluids and additives may further include lignosulfonates and other biomass-derived components. Also, these water-based or oil-based fluids and additives may further include enzymes. The drilling and fracturing fluids and additives described herein may be produced using the AVAP® process technology to produce a nanocellulose precursor, followed by low-energy refining to produce nanocellulose for incorporation into a variety of drilling and fracturing fluids and additives.
Compositions of and methods for using hydraulic fracturing fluid for petroleum production
A hydraulic fracturing fluid for use in oilfield applications, where the hydraulic fracturing fluid includes a spherical bead-forming liquid composition, the spherical bead-forming liquid composition comprising a micellar forming surfactant, a bead-forming compound, a non-solids bearing liquid solvent, a pH control agent, and a curing agent.
Compositions of and methods for using hydraulic fracturing fluid for petroleum production
A hydraulic fracturing fluid for use in oilfield applications, where the hydraulic fracturing fluid includes a spherical bead-forming liquid composition, the spherical bead-forming liquid composition comprising a micellar forming surfactant, a bead-forming compound, a non-solids bearing liquid solvent, a pH control agent, and a curing agent.
Emulsified Acidic Treatment Fluid With Surface Modification Agents
Surface modification agents may be included in emulsified acidic treatment fluids to leave surfaces in carbonate formations water wet after acidizing operations. A method of acidizing a subterranean formation, comprising: providing a treatment fluid in the form of an invert emulsion, wherein the treatment fluid comprises: a hydrocarbon phase comprising an oil-soluble liquid and an emulsifier; and an aqueous acidic phase comprising water, an acid, and a surface modification agent; and introducing the treatment fluid into a wellbore.