Working fluids, such as drilling fluids, may remove heat from other fluids, tools, equipments and environments and transfer it to other locations by using reversible phase change elements. The heat removal occurs through the absorption of heat by one or more phase transitions or a sequence of phase transitions in the elements of the working fluid. For instance, heat is absorbed when the phase change portions of the reversible phase change elements change phase including, but not necessarily limited to, a change from solid to smectic liquid crystal, from solid to nematic liquid crystal, from smectic liquid crystal to isotropic liquid, from nematic liquid crystal to isotropic liquid, from solid to isotropic liquid, and sequences and combinations thereof. Heat is released when the phase change reverses. These phase changes are first-order transitions and are associated with a latent heat or enthalpy.

Some embodiments described herein relate to methods comprising providing a proposed invert emulsion formulation, wherein the proposed invert emulsion formulation comprises an oil phase, an aqueous phase, and a particulates fraction comprising a first sub-fraction and a second sub-fraction, wherein the first sub-fraction comprises high-gravity particulates and the second sub-fraction comprises low-gravity particulates; calculating an initial associative stability value of the proposed invert emulsion based on the degree of association between the aqueous phase and the particulates fraction comprising both the first sub-fraction and the second sub-fraction; manipulating the proposed invert emulsion based on the initial associative stability value so as to produce an associatively stable invert emulsion having a final associative stability value in the range of between about 50% and about 100%; and introducing the associatively stable invert emulsion into a subterranean formation.

Some embodiments described herein relate to methods comprising providing a proposed invert emulsion formulation, wherein the proposed invert emulsion formulation comprises an oil phase, an aqueous phase, and a particulates fraction comprising a first sub-fraction and a second sub-fraction, wherein the first sub-fraction comprises high-gravity particulates and the second sub-fraction comprises low-gravity particulates; calculating an initial associative stability value of the proposed invert emulsion based on the degree of association between the aqueous phase and the particulates fraction comprising both the first sub-fraction and the second sub-fraction; manipulating the proposed invert emulsion based on the initial associative stability value so as to produce an associatively stable invert emulsion having a final associative stability value in the range of between about 50% and about 100%; and introducing the associatively stable invert emulsion into a subterranean formation.

A method for recovering hydrocarbon material from a subterranean formation includes introducing a treatment fluid into the subterranean formation. One treatment fluid includes at least one organometallic material having a metal or metalloid from Group III of the Periodic Table or a transition metal. An optional second fluid having an organophosphorous material can also be introduced. Another treatment fluid includes the reaction product of a transition metal compound and a silicon-containing material.

A method for recovering hydrocarbon material from a subterranean formation includes introducing a treatment fluid into the subterranean formation. One treatment fluid includes at least one organometallic material having a metal or metalloid from Group III of the Periodic Table or a transition metal. An optional second fluid having an organophosphorous material can also be introduced. Another treatment fluid includes the reaction product of a transition metal compound and a silicon-containing material.

Various embodiments disclosed related to compositions and methods of using the same for treating subterranean formations. In various embodiments, the present invention provides a method of treating a subterranean formation. The method includes placing in a subterranean formation a composition that includes a viscosifier and that also includes a hydrophobically-modified polymer including at least one nitrogen-containing repeating unit.

Various embodiments disclosed relate to compositions including a viscosifier polymer and a polyamine viscosity modifier and methods of using the same for treatment of subterranean formations. In various embodiments, the present invention provides a method of treating a subterranean formation. The method includes placing in a subterranean formation a composition including a viscosifier polymer and a polyamine viscosity modifier.

Various embodiments disclosed relate to compositions including a viscosifier polymer and a polyamine viscosity modifier and methods of using the same for treatment of subterranean formations. In various embodiments, the present invention provides a method of treating a subterranean formation. The method includes placing in a subterranean formation a composition including a viscosifier polymer and a polyamine viscosity modifier.

Provided herein are methods systems and compositions of a fracturing fluid comprising an associative polymer and clay nanoparticles. A method may comprise: providing a fracturing fluid comprising: a carrier fluid; an associative polymer; and clay nanoparticles; and injecting the fracturing fluid into a subterranean formation at or above a fracture gradient.

Compositions and methods comprising certain microemulsions and certain clay control additives for enhancing clay swelling protection and persistency in treating swelling clay of a subterranean formation of oil and/or gas wells are generally provided. The combination of certain microemulsions and certain clay control additives exhibit synergistic effects by enhancing clay swelling protection and persistency in treating swelling clay. The well treatment composition may use up to four times less concentration of clay control additive compared to using the same clay control additive alone, while still providing the same, similar, or higher degree of clay swelling protection and enhanced persistency. The microemulsion and the clay control additive may be added to a carrier fluid to form the well treatment composition, which is injected into the subterranean formation to provide enhanced clay swelling protection and persistency of continuing to provide clay swelling protection for a longer period of time during flowback.