A hydrocarbon formation treatment micellar solution fluid and its use in treating underperforming hydrocarbon formations is described and claimed. A hydrocarbon formation treatment micellar solution fluid wherein the micellar solution fluid comprises water, a non-terpene oil-based moiety, a brine resistant aqueous colloidal silica sol; and optionally a terpene or a terpenoid, wherein the brine resistant aqueous colloidal silica sol has silica particles with a surface that is functionalized with at least one moiety selected from the group consisting of a hydrophilic organosilane, a mixture of hydrophilic and hydrophobic organosilanes, or a polysiloxane oligomer, wherein the brine resistant aqueous colloidal silica sol passes at least two of three of these brine resistant tests: API Brine Visual, 24 Hour Seawater Visual and API Turbidity Meter, and wherein, when a terpene or terpenoid is present, the ratio of total water to terpene or terpenoid is at least about 15 to 1.

A stabilized composition for use as a well fluid is provided. The stabilized composition includes a brine, a polyol, the polyol in an amount operable to inhibit solid formation, the polyol further operable to dissolve within the brine; and a stabilization compound, the stabilization compound operable to stabilize the polyol, such that the polyol does not degrade at a bottom hole temperature.

This invention describes and claims the stimulation of several Wolfcamp and Bone Springs targeted wells in the northern Delaware Basin using fracturing treatments and a new method employing relatively small pre-pad pill volumes of Brine Resistant Silicon Dioxide Nanoparticle Dispersions ahead of each stage of treatment have been successfully performed. The invention includes a method of extending an oil and gas system ESRV comprising the steps of adding a Brine Resistant Silicon Dioxide Nanoparticle Dispersion (BRINE RESISTANT SDND) to conventional oil well treatment fluids. The invention also includes a method of increasing initial production rates of an oil well by over 20.0% as compared to wells either not treated with the BRINE RESISTANT SDND technology or treated by conventional nano-emulsion surfactants. The Method focuses on the steps of adding a Brine Resistant Silicon Dioxide Nanoparticle Dispersion to conventional oil well treatment fluids.

This invention describes and claims the stimulation of several Wolfcamp and Bone Springs targeted wells in the northern Delaware Basin using fracturing treatments and a new method employing relatively small pre-pad pill volumes of Brine Resistant Silicon Dioxide Nanoparticle Dispersions ahead of each stage of treatment have been successfully performed. The invention includes a method of extending an oil and gas system ESRV comprising the steps of adding a Brine Resistant Silicon Dioxide Nanoparticle Dispersion (BRINE RESISTANT SDND) to conventional oil well treatment fluids. The invention also includes a method of increasing initial production rates of an oil well by over 20.0% as compared to wells either not treated with the BRINE RESISTANT SDND technology or treated by conventional nano-emulsion surfactants. The Method focuses on the steps of adding a Brine Resistant Silicon Dioxide Nanoparticle Dispersion to conventional oil well treatment fluids.

Discrete, individualized carbon nanotubes having targeted, or selective, oxidation levels and/or content on the interior and exterior of the tube walls can be used for nanotube-mediated controlled delivery of degradative molecules, such as oxidizers and enzymes, for oil-field drilling applications. A manufacturing process using minimal acid oxidation for carbon nanotubes may also be used which provides higher levels of oxidation compared to other known manufacturing processes.

Heavy fluids are made from calcium bromide and at least one hydrogen bond donor such as a low molecular weight polyol or an organic acid. The combination of a hydrogen bond donor and calcium bromide as a hydrogen bond acceptor in an appropriate molar ratio forms a higher density clear completion fluid at a low temperature not otherwise obtainable with heavy aqueous solutions of calcium bromide such as are used in oilfield wells. A method of making the fluid comprises mixing calcium bromide with the polyol(s) in the presence of water and then reducing the water content, thus forming a heavy fluid. A crystallization inhibitor such as nitrilitriacetamide or a particulate silicate is included in the formulation. When the heavy fluid freezes, its physical form is somewhat amorphous and pumpable rather than crystalline. The heavy fluid is useful as a drilling fluid as well as a completion fluid and for other purposes in oil recovery processes where extreme density is beneficial.

Gas hydrates are formed in treatment fluid in situ within the wellbore. Foaming of the treatment fluid can occur both during the introduction of the gas treatment fluid to form hydrates and downhole near the subterranean reservoir where the heat of the reservoir will cause the gas hydrates to revert back to a gaseous state. The method involves preparing a treatment fluid comprising an aqueous base fluid, and a viscosifying agent at the surface. This treatment fluid is then introduced into the wellbore. Also, at the surface, a liquefied natural gas is pressurized and then vaporized to produce a vaporized natural gas. The vaporized natural gas is introduced into the wellbore so as to mix with the treatment fluid also being introduced. The introduction is such that gas hydrates are formed from the natural gas in the treatment fluid in situ within the wellbore.

A method of using a high temperature treatment fluid containing nanocellulose including: providing a treatment fluid that includes a base fluid, a synthetic crosslinked polymer composition including a plurality of monomeric units, and at least one crosslinker, and a nanocellulose. The treatment fluid is introduced into at least a portion of a well bore penetrating at least a portion of a subterranean formation.

Provided are compositions, methods, and systems that relate to use of crystallization temperature reduction additives in treatment fluids. A treatment fluid for use in subterranean operations, the treatment fluid comprising: a bromide brine having a first true crystallization temperature; a true crystallization temperature reduction additive, the first true crystallization temperature is the true crystallization temperature of the bromide brine without inclusion of the true crystallization temperature reduction additive; the treatment fluid has a second true crystallization temperature that is lower than the first true crystallization temperature. A method for treating a wellbore, wherein the method comprises: disposing a treatment fluid in the wellbore, wherein the treatment fluid comprises: a bromide brine and a first true crystallization temperature; a true crystallization temperature reduction additive, the treatment fluid has a second true crystallization temperature that is lower than the first true crystallization temperature.

A variety of systems, methods, and compositions are disclosed, including, a method for treating a subterranean formation, the method comprising: injecting a pad fluid into the subterranean formation at a pressure sufficient to create at least one fracture in the subterranean formation; injecting a first treatment fluid into the at least one fracture, wherein the first treatment fluid comprises: an aqueous base fluid, and a first proppant particulate; allowing the first proppant particulate to gravitationally migrate into a portion of the at least one fracture; injecting a second treatment fluid into the at least one fracture, wherein the second treatment fluid comprises: a suspension base fluid comprising a viscosity of about 50 cP to about 10,000 cP, and a second proppant particulate; and allowing the fracture to close, thereby forming a full proppant pack and a partial proppant pack in the at least one fracture.