The object of the present invention is to provide an oxide-based phosphor comprising elements other than rare earth elements as light-emitting elements, with low material costs, while achieving high luminous efficacy. The means for achieving the object is a phosphor comprising the following (1) to (3): (1) zirconium oxide, (2) titanium, and (3) at least one element selected from the group consisting of phosphorus, selenium, boron, and silicon.

The object of the present invention is to provide an oxide-based phosphor comprising elements other than rare earth elements as light-emitting elements, with low material costs, while achieving high luminous efficacy. The means for achieving the object is a phosphor comprising the following (1) to (3): (1) zirconium oxide, (2) titanium, and (3) at least one element selected from the group consisting of phosphorus, selenium, boron, and silicon.

Embodiments provide a light emitting device package including a package body having a through-hole; a radiator disposed in the through-hole and including an alloy layer having Cu; and a light emitting device disposed on the radiator, wherein the alloy layer includes at least one of W or Mo, and wherein the package body includes cavity including a sidewall and a bottom surface, and wherein the through-hole is formed in the bottom surface.

Embodiments provide a light emitting device package including a package body having a through-hole; a radiator disposed in the through-hole and including an alloy layer having Cu; and a light emitting device disposed on the radiator, wherein the alloy layer includes at least one of W or Mo, and wherein the package body includes cavity including a sidewall and a bottom surface, and wherein the through-hole is formed in the bottom surface.

A lighting device for adjusting the color temperature of white light emitted by a luminescent material is disclosed. The lighting device comprises: a luminescent material configured to emit white light when being exposed to electromagnetic radiation of a preselected wavelength range; at least one excitation unit configured to expose the luminescent material to electromagnetic radiation of a first wavelength range selected from the range of 230-330 nm; at least one excitation unit configured to expose the luminescent material to electromagnetic radiation of a second wavelength range, different from the first wavelength range, selected from the range of 300-600 nm; a metering unit configured to adjust the ratio of the irradiances of electromagnetic radiation of first wavelength range and of electromagnetic radiation of second wavelength range that is exposed on the luminescent material.

Ligand-capped inorganic particles, films composed of the ligand-capped inorganic particles, and methods of patterning the films are provided. Also provided are electronic, photonic, and optoelectronic devices that incorporate the films. The ligands that are bound to the inorganic particles are composed of a cation/anion pair. The anion of the pair is bound to the surface of the particle and at least one of the anion and the cation is photosensitive.

A lighting device for adjusting the color temperature of white light emitted by a luminescent material is disclosed. The lighting device comprises: a luminescent material configured to emit white light when being exposed to electromagnetic radiation of a preselected wavelength range; at least one excitation unit configured to expose the luminescent material to electromagnetic radiation of a first wavelength range selected from the range of 230-330 nm; at least one excitation unit configured to expose the luminescent material to electromagnetic radiation of a second wavelength range, different from the first wavelength range, selected from the range of 300-600 nm; a metering unit configured to adjust the ratio of the irradiances of electromagnetic radiation of first wavelength range and of electromagnetic radiation of second wavelength range that is exposed on the luminescent material.

In a surface modification method for fluoride luminescent materials, an inorganic coating layer A.sub.xMF.sub.y coated substrate A.sub.xMF.sub.y:Mn.sup.4+ is mixed with an organic solution containing a metal phosphate, an alkoxysilane, an organic carboxylic acid or an organic amine. The solution is evaporated to give the organic-inorganic coating layer coated surface-modified fluoride luminescent material. The phosphor photoluminescence intensity and quantum efficiency of the modified phosphors can be maintained at 85%-95% under high temperature and high humidity conditions. After being coated with the inorganic coating layer, the surface defects of the phosphor are reduced, and the photoluminescence intensity and quantum yield of the phosphor are increased by 5%-15%. After being coated with the organic coating layer, the photoluminescence intensity of the phosphor is reduced <3%.

In a surface modification method for fluoride luminescent materials, an inorganic coating layer A.sub.xMF.sub.y coated substrate A.sub.xMF.sub.y:Mn.sup.4+ is mixed with an organic solution containing a metal phosphate, an alkoxysilane, an organic carboxylic acid or an organic amine. The solution is evaporated to give the organic-inorganic coating layer coated surface-modified fluoride luminescent material. The phosphor photoluminescence intensity and quantum efficiency of the modified phosphors can be maintained at 85%-95% under high temperature and high humidity conditions. After being coated with the inorganic coating layer, the surface defects of the phosphor are reduced, and the photoluminescence intensity and quantum yield of the phosphor are increased by 5%-15%. After being coated with the organic coating layer, the photoluminescence intensity of the phosphor is reduced <3%.

A fluoride fluorescent material includes a composition including K, Ge, Mn.sup.4+, and F and having a molar ratio of K of 2, a total molar ratio of Ge and Mn.sup.4+ of 1, a molar ratio of Mn.sup.4+ of more than 0 and less than 0.2, and a molar ratio of F of 6 in 1 mol of the composition, has a light emission spectrum having a first light emission peak in a range of 615 nm or more and less than 625 nm having a full width at half maximum of 6 nm or less, and a second light emission peak in a range of 625 nm or more and less than 635 nm, and has an internal quantum of 85% or more efficiency under excitation of light having a wavelength of 450 nm.