Disclosed is a method for preparing a solid-state helical photonic crystal structure. The method includes: mixing a nonreactive chiral dopant with a reactive nematic mesogen, followed by curing to form a helical cholesteric liquid crystal; and removing the chiral dopant from the cholesteric liquid crystal while maintaining the helical structure of the cholesteric liquid crystal, to form a solid-state helical liquid crystal.

Disclosed is a method for preparing a solid-state helical photonic crystal structure. The method includes: mixing a nonreactive chiral dopant with a reactive nematic mesogen, followed by curing to form a helical cholesteric liquid crystal; and removing the chiral dopant from the cholesteric liquid crystal while maintaining the helical structure of the cholesteric liquid crystal, to form a solid-state helical liquid crystal.

A light modulation element comprising, preferably consisting of a cholesteric liquid crystalline medium sandwiched between two opposing substrates, an electrode arrangement, which is capable to allow the application of an electric field, which is substantially perpendicular to the main plane of substrate or the layer of the cholesteric liquid-crystalline medium, characterized in that one of the substrates is provided with a processed alignment layer adjacent to the cholesteric liquid crystalline medium and the other substrate is either provided with an unprocessed alignment layer adjacent to the cholesteric liquid crystalline medium or is not provided with an alignment layer. The invention is further related to a method of production of said light modulation element and to the use of said light modulation element in various types of optical and electro-optical devices, such as electro-optical displays, liquid crystal displays (LCDs), non-linear optic (NLO) devices, and optical information storage devices.

A light modulation element comprising, preferably consisting of a cholesteric liquid crystalline medium sandwiched between two opposing substrates, an electrode arrangement, which is capable to allow the application of an electric field, which is substantially perpendicular to the main plane of substrate or the layer of the cholesteric liquid-crystalline medium, characterized in that one of the substrates is provided with a processed alignment layer adjacent to the cholesteric liquid crystalline medium and the other substrate is either provided with an unprocessed alignment layer adjacent to the cholesteric liquid crystalline medium or is not provided with an alignment layer. The invention is further related to a method of production of said light modulation element and to the use of said light modulation element in various types of optical and electro-optical devices, such as electro-optical displays, liquid crystal displays (LCDs), non-linear optic (NLO) devices, and optical information storage devices.

A complex (10) includes a liquid crystal component (13) and a support (11, 12) of the liquid crystal component (13), in which a lubricating interface derivation region (16) is formed between the liquid crystal component (13) and the support (11, 12). An optical element includes a pair of substrates (11, 12) having electrodes (18, 19) on at least one substrate (11), and a liquid crystal component (13) with which a space between the pair of substrates (11, 12) is filled, in which a lubricating interface derivation region (16) is formed between the pair of substrates (11, 12) and the liquid crystal component (13). It is preferable that the lubricating interface deriving agent (14) is present in the lubricating interface derivation region.

A method for fabricating micro-cell structures is provided and has providing a liquid crystal mixture; performing a heating step on the liquid crystal mixture at a temperature ranging from 45 C. to 150 C., performing a heat induced phase separation step on the liquid crystal mixture at a thermal phase separation temperature for a thermal phase separation titre such that the liquid crystal mixture forms liquid crystal particles and a network light-curing adhesive, wherein the thermal phase separation temperature and the thermal phase separation time are determined by a changing rate of a bright area ratio of the liquid crystal mixture; and performing a photo-curing step on the liquid crystal mixture by emitting an ultraviolet light so that a plurality of micro-cell structures are formed. The micro-cell structures with different transparency are fabricated based on different values of the thermal phase separation temperature and the thermal phase separation time.

A method for fabricating micro-cell structures is provided and has providing a liquid crystal mixture; performing a heating step on the liquid crystal mixture at a temperature ranging from 45 C. to 150 C., performing a heat induced phase separation step on the liquid crystal mixture at a thermal phase separation temperature for a thermal phase separation titre such that the liquid crystal mixture forms liquid crystal particles and a network light-curing adhesive, wherein the thermal phase separation temperature and the thermal phase separation time are determined by a changing rate of a bright area ratio of the liquid crystal mixture; and performing a photo-curing step on the liquid crystal mixture by emitting an ultraviolet light so that a plurality of micro-cell structures are formed. The micro-cell structures with different transparency are fabricated based on different values of the thermal phase separation temperature and the thermal phase separation time.

Shown is a compound represented by formula (1). For example, R.sup.1 is alkyl having 1 to 15 carbons; MES is a mesogen group having at least one ring; Sp.sup.1 is a single bond or alkylene having 1 to 10 carbons; M.sup.1 is methyl; and R.sup.2, M.sup.2 and M.sup.3 are hydrogen. ##STR00001##

Shown is a compound represented by formula (1). For example, R.sup.1 is alkyl having 1 to 15 carbons; MES is a mesogen group having at least one ring; Sp.sup.1 is a single bond or alkylene having 1 to 10 carbons; M.sup.1 is methyl; and R.sup.2, M.sup.2 and M.sup.3 are hydrogen. ##STR00001##

A liquid crystal display device includes a pair of substrates, a negative liquid crystal layer held between the pair of substrates, a seal portion held between the pair of substrates and disposed around the liquid crystal layer, and a pair of alignment layers each of which is disposed on a surface, adjacent to the liquid crystal layer, of a corresponding one of the substrates. The negative liquid crystal layer includes a liquid crystal composition including a compound having a functional group represented by the formula (A) below, the seal portion includes a radical polymerization initiator, the alignment layers include a polymer including polyimide, the polyimide is prepared from polyamic acid as a precursor, and the imidization ratio of the polyimide is not less than 60% with respect to the whole polymer.

##STR00001##

(where X: oxygen radical, hydroxyl group, C.sub.1-20 linear alkyl group, or C.sub.3-20 branched alkyl group, Y1 to Y4: C.sub.1-4 linear alkyl group or C.sub.3-4 branched alkyl group)