The present invention provides a flame-retardant engineering plastic and a preparation method thereof. The flame-retardant engineering plastic contains a halogen-free flame retardant represented by the formula I as a component of raw materials. The addition of the flame retardant gives good flame retardancy and excellent mechanical properties to the engineered plastic. The engineering plastic is prepared by the raw materials comprising the following components in parts by mass: 40-60 parts of PC, 20-40 parts of epoxy resin, 10-20 parts of ABS and 5-15 parts of flame retardant. The engineering plastic prepared by the present invention has a bending strength which can be up to 82.4-84 MPa, a tensile strength of up to 65.7-66.6 MPa, a notched impact strength of up to 26.3-27 J/m, a melt index of 12.6-15, and an oxygen index of 26.2-27.5%, and thus has excellent mechanical properties and good flame retardancy.

Disclosed is a composition that can impart a drip preventing effect together with an excellent heat release suppressing effect to a resin, and that enables the resin to exhibit an excellent color tone, by being mixed with the resin. The composition includes a component (A) and/or a component (B), and a component (C). It is preferable that the composition contains the component (C) in an amount of 0.1 to 50 parts by mass relative to 100 parts by mass of a total of the components (A) and (B). The component (A) is a (poly)phosphate compound represented by General Formula (1). ##STR00001## The component (B) is a (poly)phosphate compound represented by General Formula (3). ##STR00002## The component (C) is a hydrous magnesium silicate.

Disclosed is a composition that can impart a drip preventing effect together with an excellent heat release suppressing effect to a resin, and that enables the resin to exhibit an excellent color tone, by being mixed with the resin. The composition includes a component (A) and/or a component (B), and a component (C). It is preferable that the composition contains the component (C) in an amount of 0.1 to 50 parts by mass relative to 100 parts by mass of a total of the components (A) and (B). The component (A) is a (poly)phosphate compound represented by General Formula (1). ##STR00001## The component (B) is a (poly)phosphate compound represented by General Formula (3). ##STR00002## The component (C) is a hydrous magnesium silicate.

Modified lignin products, processes for making them, and their use to produce rigid polyurethane or polyisocyanurate foams are disclosed. The processes comprise heating a lignin source with a nitrogen source and a starved concentration of a C.sub.1-C.sub.5 aldehyde to give a reaction mixture comprising a Mannich condensation product, neutralizing the reaction mixture, and isolating the modified lignin product. The process is performed at a mass ratio of lignin source to nitrogen source within the range of 1:1 to 1:5 and at a molar ratio of nitrogen source to C.sub.1-C.sub.5 aldehyde within the range of 3.5:1 to 1:1. Polyol blends and performance additives that contain the modified lignin products are described. Rigid foams that process well and incorporate up to 60 wt.%, based on the amount of polyol component, of the modified lignin contribute to excellent flame retardancy and low-temperature R-value performance.

The invention provides a flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 20% to 99.7% by weight of phosphinic salt of the formula (I), (I), in which R.sub.1 and R.sub.2 are each ethyl, M is Al and m is 3; as component B 0.2% to 16% by weight of aluminium salts of ethylbutylphosphinic acid, of dibutylphosphinic acid, of ethylhexylphosphinic acid, of butylhexylphosphinic acid and/or of dihexylphosphinic acid; as component C 0.1% to 80% by weight of a salt of phosphorous acid having the general formula (II) [HP(═O)O.sub.2].sup.2−M.sup.m+(II) in which M is Zn and m is 2; as component D 0% to 80% by weight of a salt of phosphorous acid having the general formula (III) [HP(═O)O.sub.2].sup.2−.sub.3 M.sup.m+.sub.2 (III) in which M is Al and m is 3; as component E 0% to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus-containing and/or nitrogen-containing flame retardant; as component F 0% to 10% by weight of an inorganic synergist selected from zinc borate, zinc stannate, boehmite and/or hydrotalcite; as component G 0% to 3% by weight of an organic phosphonite and/or a mixture of an organic phosphonite and an organic phosphite and as component H 0% to 3% by weight of an ester and/or salt of long-chain aliphatic carboxylic acids (fatty acids) typically having chain lengths of C.sub.14 to C.sub.40, where the sum total of the components is always 100% by weight.

##STR00001##

The invention provides a flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 20% to 99.7% by weight of phosphinic salt of the formula (I), (I), in which R.sub.1 and R.sub.2 are each ethyl, M is Al and m is 3; as component B 0.2% to 16% by weight of aluminium salts of ethylbutylphosphinic acid, of dibutylphosphinic acid, of ethylhexylphosphinic acid, of butylhexylphosphinic acid and/or of dihexylphosphinic acid; as component C 0.1% to 80% by weight of a salt of phosphorous acid having the general formula (II) [HP(═O)O.sub.2].sup.2−M.sup.m+(II) in which M is Zn and m is 2; as component D 0% to 80% by weight of a salt of phosphorous acid having the general formula (III) [HP(═O)O.sub.2].sup.2−.sub.3 M.sup.m+.sub.2 (III) in which M is Al and m is 3; as component E 0% to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus-containing and/or nitrogen-containing flame retardant; as component F 0% to 10% by weight of an inorganic synergist selected from zinc borate, zinc stannate, boehmite and/or hydrotalcite; as component G 0% to 3% by weight of an organic phosphonite and/or a mixture of an organic phosphonite and an organic phosphite and as component H 0% to 3% by weight of an ester and/or salt of long-chain aliphatic carboxylic acids (fatty acids) typically having chain lengths of C.sub.14 to C.sub.40, where the sum total of the components is always 100% by weight.

##STR00001##

The present disclosure relates to a novel flame retardant and stabilizer additive composition for thermoplastic polymers, the additive composition including at least one phosphorus-containing flame retardant and at least one epoxide, as described herein. The presently disclosed additive compositions are useful over a wide range of thermoplastic applications, particularly in thermoplastic polymers that are processed and/or used at high temperatures.

The present disclosure relates to a novel flame retardant and stabilizer additive composition for thermoplastic polymers, the additive composition including at least one phosphorus-containing flame retardant and at least one epoxide, as described herein. The presently disclosed additive compositions are useful over a wide range of thermoplastic applications, particularly in thermoplastic polymers that are processed and/or used at high temperatures.

A curable epoxy composition suitable for surface application, comprising one or more epoxy resin (s); 2, 4, 6-tribromophenyl end-capped tetrabromobisphenol A epoxy-based flame retardant; and phosphorus-containing compound selected from the group consisting of one or more of: ammonium polyphosphate; resorcinol bis (diphenyl phosphate); and liquid alkylated triphenyl phosphate ester. The composition is substantially Sb.sub.2O.sub.3-free.

A curable epoxy composition suitable for surface application, comprising one or more epoxy resin (s); 2, 4, 6-tribromophenyl end-capped tetrabromobisphenol A epoxy-based flame retardant; and phosphorus-containing compound selected from the group consisting of one or more of: ammonium polyphosphate; resorcinol bis (diphenyl phosphate); and liquid alkylated triphenyl phosphate ester. The composition is substantially Sb.sub.2O.sub.3-free.