In accordance with the present invention refrigerant compositions are disclosed. The compositions comprise HFC-32, HFC-125, HFO-1234yf, HFC-134a, and CO.sub.2. The refrigerant compositions are useful in processes to produce cooling and heating, in methods for replacing refrigerant R-410A or R-22, and in refrigeration, air conditioning or heat pump systems. These inventive compositions are non-flammable and match cooling performance for R-22 and R-410A within 15%. Additionally, these compositions may serve as replacements for R-404A, R-507, R407A, R407C and/or R-407F in refrigeration, air conditioning or heat pump systems. The compositions as described herein have unexpected flammability properties.

The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be an epoxide, fluorinated epoxide or oxetane, or a mixture thereof with other stabilizers. The stabilized compositions may be useful in cooling to apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.

The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be an epoxide, fluorinated epoxide or oxetane, or a mixture thereof with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.

The invention provides a refrigerating machine oil comprising as a base oil at least one oxygen-containing oil having a carbon/oxygen molar ratio of 2.5 or more and 5.8 or less, and being used in combination with a (Z)-1,1,1,4,4,4-hexafluoro-2-butene refrigerant.

The present invention relates to heat transfer compositions comprising refrigerant, lubricant and stabilizer, wherein the refrigerant comprises from about 5% by weight to 100% by weight of trans-1,2-difluorethylene (R1132(E)), and wherein said lubricant comprises polyol ester (POE) lubricant and/or polyvinyl ether (PVE) lubricant, and wherein said stabilizer comprises an alkylated naphthalene and optionally but preferably an acid depleting moiety.

Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of HFO-E-1,3,4,4,4-pentafluoro-3-trifluoromethyl-1-butene with a second compound selected from the group consisting of methyl formate and HFO-E-1,1,1,4,4,4-hexafluoro-2-butene. Also disclosed are processes of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents; of producing refrigeration by using such azeotropic or azeotrope-like compositions; of producing cooling; of producing heating; of using such azeotropic or azeotrope-like compositions as solvents; of producing an aerosol product by using such azeotropic or azeotrope-like compositions; of using such azeotropic or azeotrope-like compositions as heat transfer media; of extinguishing or suppressing a fire by using such azeotropic or azeotrope-like compositions; and of using such azeotropic or azeotrope-like compositions as dielectrics.

The present invention relates to a cooling mixture comprising a fluorinated compound and a non-fluorinated compound, wherein the fluorinated compound is a hydrofluoroether and the non-fluorinated compound includes a carbonyl function, which has a flash point no lower than 23 C. and which is characterised by having low relative volatility. The present invention likewise relates to the use of such a mixture as a coolant in a heat-exchange device.

Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of HFO-E-1,3,4,4,4-pentafluoro-3-trifluoromethyl-1-butene with a second compound selected from the group consisting of methyl formate and HFO-E-1,1,1,4,4,4-hexafluoro-2-butene. Also disclosed are processes of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents; of producing refrigeration by using such azeotropic or azeotrope-like compositions; of producing cooling; of producing heating; of using such azeotropic or azeotrope-like compositions as solvents; of producing an aerosol product by using such azeotropic or azeotrope-like compositions; of using such azeotropic or azeotrope-like compositions as heat transfer media; of extinguishing or suppressing a fire by using such azeotropic or azeotrope-like compositions; and of using such azeotropic or azeotrope-like compositions as dielectrics.

A system and method for retrofitting a refrigeration system containing an HCFC refrigerant and a compatible lubricant, with an HFC refrigerant, comprising providing a transport container containing a mixture of a miscible lubricant and the HFC refrigerant, removing the HCFC refrigerant from the refrigeration system while maintaining at least a portion of a lubricant immiscible with the HFC refrigerant, and charging the refrigeration system with the mixture. The polyol ester lubricant may be present in a range exceeding about 5-15% by weight, e.g., 8%.

A system and method for retrofitting a refrigeration system containing an HCFC refrigerant and a compatible lubricant, with an HFC refrigerant, comprising providing a transport container containing a mixture of a miscible lubricant and the HFC refrigerant, removing the HCFC refrigerant from the refrigeration system while maintaining at least a portion of a lubricant immiscible with the HFC refrigerant, and charging the refrigeration system with the mixture. The polyol ester lubricant may be present in a range exceeding about 5-15% by weight, e.g., 8%.