Patent classifications
C10G1/042
Process for treating high paraffin diluted bitumen
A paraffinic solvent recovery process for treating high paraffin diluted bitumen includes supplying the latter to flashing apparatus; separating into flashed paraffinic solvent and diluted bitumen underflow; and returning a portion of the underflow as returned diluted bitumen into the high paraffin diluted bitumen prior to introduction into the flashing apparatus, at temperature and amount to shift asphaltene precipitation equilibrium to reduce asphaltene precipitation. The process includes pre-heating the high paraffin diluted bitumen by transferring heat from hot dry bitumen, flashed paraffinic solvent and/or a portion of diluted bitumen underflow. Flashed paraffinic solvent may contain residual light end bitumen contaminants that increase asphaltenes solubility and the process may include removing contaminants to produce reusable paraffinic solvent at given solvent-to-bitumen ratio range to maintain given asphaltene precipitation. The process may also include a bitumen fractionation column producing hot dry bitumen underflow containing at most 0.5 wt % paraffinic solvent
Biomass Liquefaction to Produce Refinery-Ready Bio-Oil
A bio-oil product is produced from biomass material by subjecting the biomass material to a first stage liquefaction process, where the first stage liquefaction process includes combining the biomass material with a co-solvent including methanol and water to form a first slurry mixture, providing the slurry mixture within a first liquefaction reactor and maintaining the first slurry mixture at a sufficient temperature and pressure so as to convert a portion of the biomass material into a first liquefied bio-oil product as well as form a first aqueous product and a first solid product, and separating the first liquefied bio-oil product from the aqueous and solid products. The solid product obtained from the first stage liquefaction process is subjected to a second stage liquefaction process, where the second stage liquefaction process includes combining the first solid product with methane to form a second slurry mixture, and providing the second slurry mixture within a second liquefaction reactor and maintaining the second slurry mixture at a sufficient temperature and pressure so as to convert a portion of the first solid product to a second liquefied bio-oil product as well as form a second aqueous product and a second solid product.
Biocarbon compositions with optimized compositional parameters, and processes for producing the same
In some variations, the disclosure provides a renewable biocarbon composition comprising from 50 wt % to 99 wt % total carbon, wherein the biocarbon composition is characterized by a base-acid ratio selected from 0.1 to 10, an iron-calcium ratio selected from 0.05 to 5, iron-plus-calcium parameter selected from 5 to 50 wt %, a slagging factor selected from 0.001 to 1, and/or a fouling factor or modified fouling factor selected from 0.1 to 10. Some variations provide a process comprising: providing a biomass feedstock; pyrolyzing the biomass feedstock to generate an intermediate biocarbon stream; washing or treating the intermediate biocarbon stream with an acid, a base, a salt, a metal, H.sub.2, H.sub.2O, CO, CO.sub.2, or a combination thereof, and/or introducing an additive in the process, to adjust a base-acid ratio or other compositional parameter; and recovering a biocarbon composition comprising from 50 wt % to 99 wt % total carbon and optimized for a compositional parameter.
Method for obtaining a stable lignin: polar organic solvent composition via mild solvolytic modifications
A process the production of a crude liquid lignin oil (CLO), the process includes the steps of providing a lignin-rich solid feedstock and subjecting the lignin-rich solid feedstock to a treatment in a polar organic solvent in the absence of an effective amount of added reaction promoter, such as a heterogeneous and/or homogeneous catalyst and/or hydrogen, and providing a lignin composition, the treatment includes a step of contacting the lignin-rich solid feedstock with a polar organic solvent under operating conditions of an operating temperature up to 210? C., an operating pressure lower than 50 bar and a residence time up to 240 minutes, wherein the ratio (w/v) of lignin (in lignin-rich feedstock) to polar organic solvent ranges between 1:1.5 and 1:15, or between 1:2 and 1:10 or between 1:2 and 1:5.
Composition For Solubilization Of Organic Residues
Composition for solubilization of organic residues of raw materials of fossil origin including a mixture of fatty acid esters of formula R1COOR2 in which R1 represents a linear or branched C5 to C23 carbon-based chain, optionally including one or more unsaturations, R2 represents a linear or branched C1 to C10 carbon-based chain, optionally including one or more unsaturations; the composition includes: a) at least 18% by weight of C6 to C10 fatty acid esters, b) at least 18% by weight of C18 to C24, in particular C18 to C22 fatty acid esters, including at least one double bond. The invention also relates to the use of the compositions.
BIOCARBON COMPOSITIONS WITH OPTIMIZED COMPOSITIONAL PARAMETERS, AND PROCESSES FOR PRODUCING THE SAME
In some variations, the disclosure provides a renewable biocarbon composition comprising from 50 wt % to 99 wt % total carbon, wherein the biocarbon composition is characterized by a base-acid ratio selected from 0.1 to 10, an iron-calcium ratio selected from 0.05 to 5, iron-plus-calcium parameter selected from 5 to 50 wt %, a slagging factor selected from 0.001 to 1, and/or a fouling factor or modified fouling factor selected from 0.1 to 10. Some variations provide a process comprising: providing a biomass feedstock; pyrolyzing the biomass feedstock to generate an intermediate biocarbon stream; washing or treating the intermediate biocarbon stream with an acid, a base, a salt, a metal, H.sub.2, H.sub.2O, CO, CO.sub.2, or a combination thereof, and/or introducing an additive in the process, to adjust a base-acid ratio or other compositional parameter; and recovering a biocarbon composition comprising from 50 wt % to 99 wt % total carbon and optimized for a compositional parameter.
PROCESS FOR PRODUCING LIQUID HYDROCARBON
The invention relates to a continuous process for converting carbonaceous material contained in one or more feedstocks into a liquid hydrocarbon product, said feedstocks including the carbonaceous material being in a feed mixture including one or more fluids, said fluids including water and further liquid organic compounds at least partly produced by the process in a concentration of at least 1% by weight, where the process comprises convert ing at least part of the carbonaceous material by pressurising the feed mixture to a pressure in the range 250-400 bar; heating the feed mixture to a temperature in the range 370-450 C., and maintaining said pressurized and heated feed mixture in the desired pressure and temperature ranges in a reaction zone for a predefined time; cooling the feed mixture to a temperature in the range 25-200 C. and expanding the feed mixture to a pressure in the range of 1-70 bar, thereby causing the carbonaceous material to be converted to a liquid hydrocarbon product and separating from the converted feed mixture a fraction comprising liquid hydrocarbon product.
PROCESS AND APPARATUS FOR PRODUCING LIQUID HYDROCARBON
The invention relates to a continuous process for converting carbonaceous material contained in one or more feedstocks into a liquid hydrocarbon product, said feedstocks including the carbonaceous material being in a feed mixture including one or more fluids, said fluids including water and further liquid organic compounds at least partly produced by the process in a concentration of at least 1% by weight, where the process comprises converting at least part of the carbonaceous material by pressurising the feed mixture to a pressure in the range 250-400 bar; heating the feed mixture to a temperature in the range 370-450 C., and maintaining said pressurized and heated feed mixture in the desired pressure and temperature ranges in a reaction zone for a predefined time; cooling the feed mixture to a temperature in the range 25-200 C. and expanding the feed mixture to a pressure in the range of 1-70 bar, thereby causing the carbonaceous material to be converted to a liquid hydrocarbon product and separating from the converted feed mixture a fraction comprising liquid hydrocarbon product.
Process and apparatus for producing liquid hydrocarbon
The invention relates to a continuous process for converting carbonaceous material contained in at least two feedstocks into a liquid hydrocarbon product, said feedstocks including at least one feedstock of biomass and at least one feedstock of lignite and/or peat, said feedstocks including the carbonaceous material being in a feed mixture including one or more fluids, said fluids including water and further liquid organic compounds at least partly produced by the process in a concentration of at least 1% by weight, where the process comprises converting at least part of the carbonaceous material by pressurizing the feed mixture to a pressure in the range 50-400 bar, heating the feed mixture to a temperature in the range 250-500 C., and maintaining said pressurized and heated feed mixture in the desired pressure and temperature ranges in a reaction zone for a predefined time; cooling the feed mixture to a temperature in the range 25-200 C. and expanding the feed mixture to a pressure in the range of 1-70 bar, thereby causing the carbonaceous material to be converted to a liquid hydrocarbon product; and separating a fraction comprising liquid hydrocarbon product and leaving a residual fraction.
Petroleum substitute comprised of an organic solvent extract of a woody tree biomass
A hydrocarbon composition that is produced through a solvent extraction of woody tree material is provided. The composition is suitable for use as a petroleum substitute. The woody tree material is sourced from hydrocarbon-bearing trees or shrubs containing relatively low molecular weight hydrocarbons. Suitable tree species include pine and eucalyptus trees. A raw woody tree biomass is processed into solvent-permeable particles and chips. Naturally occurring hydrocarbons found in the wood particles are extracted using an organic solvent extraction process. The organic solvent utilized is a mixture of organic solvents that includes a non-polar solvent and a polar solvent. The extracted hydrocarbons are separated from the solvent mixture and may be used as a petroleum substitute, while the solvent may be reused in the extraction operation.