There is provided a process and systems for producing fuels via pyrolysis of carbonaceous feedstock under pressure and temperature in an efficient manner using a circulating fluidized bed with catalyst(s). The pressure and temperature are selected to provoke supercritical conditions, and pyrolysis, hydropyrolysis, hydrotreating, and optionally reforming treatment of the carbonaceous feedstock is carried out simultaneously in one reactor on a recirculating fluidized bed containing catalysts.

Disclosed herein are processes, systems, and catalysts for improving pyrolysis technology. The disclosed processes and systems utilize a catalyst to increase pyrolysis gas (py-gas) and decrease bio-oil yields in pyrolysis reactions. The disclosed catalysts may include biochar derived from pyrolysis of industrial residuals, such as pyrolysis of wastewater biosolids (WB) and paper mill sludge (PMS). The disclosed catalysts also may include ash derived from incineration of wastewater biosolids (biosolids incineration ash (BIA)).

The present invention relates to a process for manufacturing an upgraded bio-oil derived from black liquor, comprising the following steps: Providing black liquor, which comes from the pulp and paper manufacturing industry; Subjecting black liquor to a pyrolysis treatment with formation of a pyrolyzed black liquor gas and a solid mass, which comprises char and salts; Catalytic conversion of said pyrolyzed black liquor gas by contacting at least part of the latter with a bi-metallic modified zeolite catalyst with formation of the upgraded bio-oil, which comprises benzene, toluene, xylene (BTX), naphthalene and non-BTX products.

The present invention addresses to a hydrothermal liquefaction process capable of generating a liquid stream, rich in renewable molecules, with lower oxygen content, lower percentage of water and lower acidity compared to other products of thermochemical processes of biomass conversion. In order to effectively carry out this process, a catalyst was developed, obtained from the calcination of castor bean hull, to be used in the field of biofuels in order to provide an environmentally friendly alternative for the production of fuels.

The invention provides a catalyst system and method for the deoxygenation of hydrocarbons, such as bio-oil, using a sulphide-sulfate or an oxide-carbonate (LDH) system. The invention extends to a pyrolysis process of a carbonaceous bio-mass wherein a first combustion zone is carried out in one or more combustion fluidised beds in which a particulate material including chemically looping deoxygenation catalyst particles is fluidised and heated, and a second pyrolysis zone carried out in one or more pyrolysis fluidised beds in which the hot particles, including the catalyst particles, heated in the combustion zone are used for pyrolysis of the bio-mass, said combustion zone being operated at a temperature of from 250 C. to 1100 C., typically around 900 C., and the pyrolysis zone being operated at a temperature of from 250 C. to 900 C., typically 450 C. to 600 C., said catalyst particles being oxygenated in the pyrolysis zone in the presence of oxygenates in the pyrolysis oil and regenerated in the combustion zone either by calcining to drive off the carbon oxides, such as CO.sub.2, or by reduction to its form which is active for deoxygenation of the pyrolysis oil.

The present invention provides a process for producing liquid hydrocarbon products from a solid biomass feedstock, said process comprising the steps of: a) providing in a first hydropyrolysis reactor vessel a first hydropyrolysis catalyst composition; b) contacting the solid biomass feedstock with said first hydropyrolysis catalyst composition and molecular hydrogen in said first hydropyrolysis reactor vessel to produce a product stream comprising partially deoxygenated hydropyrolysis product, H.sub.2O, H.sub.2, CO.sub.2, CO, C.sub.1-C.sub.3 gases, char and catalyst fines; c) removing said char and catalyst fines from said product stream; d) hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor vessel in the presence of one or more hydroconversion catalyst and of the H.sub.2O, CO.sub.2, CO, H.sub.2, and C.sub.1-C.sub.3 gas generated in step a), to produce a vapor phase product comprising substantially fully deoxygenated hydrocarbon product, H.sub.2O, CO, CO.sub.2, and C.sub.1-C.sub.3 gases.

A hydropyrolysis catalyst and a process using that catalyst are described. The catalyst comprises a support and an active metal component wherein the catalyst is an eggshell type catalyst having the active metal component located in the outer portion of the support.

The present invention provides a process for producing liquid hydrocarbon products from a solid biomass feedstock, said process comprising the steps of: a) providing in a first hydropyrolysis reactor vessel a first hydropyrolysis catalyst composition; b) contacting the solid biomass feedstock with said first hydropyrolysis catalyst composition and molecular hydrogen in said first hydropyrolysis reactor vessel to produce a product stream comprising partially deoxygenated hydropyrolysis product, H2O, H2, CO2, CO, C1-C3 gases, char and catalyst fines; c) removing said char and catalyst fines from said product stream; d) hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor vessel in the presence of one or more hydroconversion catalyst and of the H.sub.2O, CO.sub.2, CO, H.sub.2, and C.sub.1-C.sub.3 gas generated in step a), to produce a vapor phase product comprising substantially fully deoxygenated hydrocarbon product, H.sub.2O, CO, CO.sub.2, and C.sub.1-C.sub.3 gases.

An IBTL system having a low GHG footprint for converting biomass to liquid fuels in which a biomass feed is converted to liquids by direct liquefaction and the liquids are upgraded to produce premium fuels. Biomass residues from the direct liquefaction, and optionally additional biomass is pyrolyzed using microwave pyrolysis to produce structured biochar, hydrogen for the liquefaction and upgrading, and CO.sub.2 for conversion to algae, including blue green algae (cyanobacteria) in a photobioreactor (PBR). Produced algae and diazotrophic microorganisms are used to produce a biofertilizer that also contains structured biochar. The structured biochar acts as a nucleation agent for the algae in the PBR, as a absorption agent to absorb inorganics from the biomass feed to direct liquefaction or from the liquids produced thereby, and as a water retention agent in the biofertilizer. The ratio of cyanobacteria to diazotrophic microorganisms in the biofertilizer can be selected so as to achieve desired total chemically active carbon and nitrogen contents in the soil for a given crop.

The present invention relates to a process for converting mixed waste plastic into liquid fuels by catalytic cracking. The process comprises the steps of introducing mixed waste plastic and a catalyst comprising an amorphous-type catalyst within a reactor; allowing at least a portion of the mixed waste plastic to be converted to liquid fuels within the reactor; and removing a product stream containing said liquid fuels from the reactor.