Disclosed herein are processes, systems, and catalysts for improving pyrolysis technology. The disclosed processes and systems utilize a catalyst to increase pyrolysis gas (py-gas) and decrease bio-oil yields in pyrolysis reactions. The disclosed catalysts may include biochar derived from pyrolysis of industrial residuals, such as pyrolysis of wastewater biosolids (WB) and paper mill sludge (PMS). The disclosed catalysts also may include ash derived from incineration of wastewater biosolids (biosolids incineration ash (BIA)).

Processes for using pyrolysis gas as a feedstock or a co-feedstock for making a variety of chemicals, for example, circular ethylene, circular ethylene polymers and copolymers, and other circular products. In these processes, pyrolysis reactor conditions can be selected to increase or optimized the production of pyrolysis gas over pyrolysis oil, and the pyrolysis gas which is usually used as fuel or flared can be fed downstream of the steam cracker furnace for economic use to form circular chemicals. Operating parameters of the pyrolysis unit may be adjusted to increase or decrease the proportion of pyrolysis gas relative to pyrolysis liquid as a function of their relative economic values.

An apparatus for processing a mixture of solid and/or liquid hydrocarbons for recycling without using hydrogen gas, the apparatus including a heating system including a heating chamber for receiving solid and/or liquid hydrocarbons, a feed system for transferring hydrocarbons into the heating chamber, and heating means for removing water from the mixture of solid and/or liquid hydrocarbons outside the heating chamber and configured for subsequently, in the absence of air and the water, gasifying or vapourising at least some of the solid and/or liquid hydrocarbons in heating chamber into hydrocarbon gas, a reactor or conduit connected to and downstream from the heating chamber for receiving the hydrocarbon gas, the reactor or conduit including a catalyst for breaking down higher molecular weight hydrocarbons into lower molecular weight hydrocarbons, in which the catalyst includes a zirconium sulfate, and a carbide.

Pyrolysis processes comprise contacting a waste polyolefin with a solid catalyst at a pyrolysis temperature to form a pyrolysis product containing C.sub.1-C.sub.10 hydrocarbons. In some instances, the solid catalyst can be a silica-coated alumina, a fluorided silica-coated alumina, or a sulfated alumina, while in other instances, the solid catalyst can be any suitable solid oxide or chemically-treated solid oxide that is characterized by a d50 average particle size from 5 to 12 m and a particle size span from 0.7 to 1.7. Hydrocarbon compositions are formed from the pyrolysis of waste polyolefins with specific amounts of methane and higher carbon number hydrocarbons.

The present invention refers to a process for catalytic fractionation of peat, coir, peat-like materials or mosses into a non-pyrolytic bio-oil and a sterile solid fraction with similar volume and structural function to the starting material. The inventive process is useful for a variety of interesting applications, starting from raw peat with a water content of up to 80% resulting in a an oil, rich in polyols and aliphatic molecules.

A composition comprising an inorganic particulate material adapted to convert a biomass material into hydrolysis products is provided. The inorganic particulate material comprises at least 0.1 wt. % of at least one impurity in its crystal structure based on the total weight of the inorganic particulate material. Methods of convert a biomass material into hydrolysis products using the compositions comprising an inorganic particulate material are also provided.

A method for producing a hydrocarbon enriched bio-oil can include producing lignin from equal proportions of wheat straw and corn stover, pyrolyzing the lignin in the presence of an inert gas to provide a bio-oil; adding a nickel-impregnated carbon nanotube (Ni-CNT) catalyst to the bio-oil to provide a mixture; and heating the mixture to provide a hydro-carbon enriched bio-oil.

A method for solubilizing a carbonaceous feedstock. The method includes steps of reacting a mixture of the carbonaceous feedstock with a metal oxide including a metal at a first, higher oxidation state to reduce the metal of the metal oxide to a second, lower oxidation state by releasing at least one oxygen atom from the metal oxide. The released oxygen from the metal oxide is used to oxidize the carbonaceous feedstock. At least a portion of the metal or metal oxide containing the metal at the second, lower oxidation state is then oxidized to the metal oxide containing the metal at the first, higher oxidation state for reuse in the reaction step.

The present subject matter describes a method and apparatus for operating a delayed coker. The method comprises contacting a vapour produced in a delayed coker-drum with a catalyst maintained in form of a bed, and maintaining a level of said catalyst-bed within pre-defined limits during catalytic-cracking of the vapour. Thereafter, the cracked-vapour is routed to a coker-fractionator column to trigger conversion into one or more hydrocarbon products.

The present invention relates to a solvothermal process for producing high quality fuels and chemicals from a biomass feedstock using lignin containing bioliquor as a solvent for hydrothermal liquefaction. The lignin containing bioliquor of the present invention is obtained as a waste stream from 2G-ethanol manufacturing plants.