This disclosure pertains to the use of black liquors from kraft pulp mills as a source of catalysts for the thermochemical conversion of organic matter feedstocks to bio oils. More particularly, some embodiments pertain to integrated kraft pulp mill and thermochemical conversion systems, which include: a Kraft pulp mill comprising a digester for digesting a lignocellulosic material with white liquor to produce pulp and black liquors; a thermochemical conversion subsystem comprising: at least one mixing tank for combining pulping liquors received from the pulp mill with an organic matter feedstock and water to produce a reaction mixture; a reactor vessel for treating the reaction mixture received from the mixing tank at a reaction temperature and pressure suitable for conversion of all or a portion of the organic matter in the reaction mixture into a product mixture comprising a bioproduct and an aqueous stream containing both organic and inorganic compounds; and a depressurizer for depressurizing product mixture received from the reactor vessel; and one or more conveyors for conveying the pulping liquors from the pulp mill to the mixing tank.

A lignocellulosic starting material can be converted into an aqueous phase and a hydrocarbon phase in a one-step process by subjecting a mixture of the lignocellulosic starting material, an amorphous and unsupported sulfided nickel-molybdenum catalyst, and optionally a co-feed, to not less than a stoichiometric amount of hydrogen, elevated pressure and a temperature in the interval of 350-450° C. A novel catalyst for use in said process and a method for its production are also disclosed.

The present invention relates generally to the generation of bio-products from organic matter feedstocks. More specifically, the present invention relates to the use of pulping liquors in the hydrothermal/thermochemical conversion of lignocellulosic and/or fossilised organic feedstocks into biofuels (e.g. bio-oils) and/or chemical products (e.g. platform chemicals).

The present invention relates to a process for manufacturing an upgraded bio-oil derived from black liquor, comprising the following steps: —Providing black liquor, which comes from the pulp and paper manufacturing industry; —Subjecting black liquor to a pyrolysis treatment with formation of a pyrolyzed black liquor gas and a solid mass, which comprises char and salts; —Catalytic conversion of said pyrolyzed black liquor gas by contacting at least part of the latter with a bi-metallic modified zeolite catalyst with formation of the upgraded bio-oil, which comprises benzene, toluene, xylene (BTX), naphthalene and non-BTX products.

The present invention provides a process of catalytic depolymerization of polystyrene involving a spherical catalyst, an apparatus for carrying out the depolymerization, recovering the aromatic rich liquid product and recycling the catalyst without any decrease in the catalytic performance. Further, the present invention provides that the aromatic rich liquid product includes styrene, xylene, benzene, ethyl benzene, with styrene content greater than 65%. Additionally, the catalyst involved in the depolymerization process is a spherical catalyst that is easily recovered from coke/char formed during the process and is recycled and reused without any decrease in the catalytic performance.

A method of upcycling polymers to useful hydrocarbon materials. A catalyst with nanoparticles on a substrate selectively docks and cleaves longer hydrocarbon chains over shorter hydrocarbon chains. The nanoparticles exhibit an edge to facet ratio to provide for more interactions with the facets.

A catalyst composition includes a metal catalyst dispersed in a molten eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides. A process for the catalytic cracking of hydrocarbons includes contacting in a reactor system a carbon-containing feedstock with at least one catalyst in the presence of oxygen to generate olefinic and/or aromatic compounds; and collecting the olefinic and/or aromatic compounds; wherein: the at least one catalyst includes a metal catalyst dispersed in a molten eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides. A process for preparing the catalyst includes mixing metal catalyst precursors selected from transition metal compounds and rare-earth metal compounds and a eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides and heating it. A use of the catalyst in the catalytic cracking process of hydrocarbons.

This disclosure pertains to the use of black liquors from kraft pulp mills as a source of catalysts for the thermochemical conversion of organic matter feedstocks to bio oils. More particularly, some embodiments pertain to integrated kraft pulp mill and thermochemical conversion systems, which include: a Kraft pulp mill comprising a digester for digesting a lignocellulosic material with white liquor to produce pulp and black liquors; a thermochemical conversion subsystem comprising: at least one mixing tank for combining pulping liquors received from the pulp mill with an organic matter feedstock and water to produce a reaction mixture; a reactor vessel for treating the reaction mixture received from the mixing tank at a reaction temperature and pressure suitable for conversion of all or a portion of the organic matter in the reaction mixture into a product mixture comprising a bioproduct and an aqueous stream containing both organic and inorganic compounds; and a depressurizer for depressurizing product mixture received from the reactor vessel; and one or more conveyors for conveying the pulping liquors from the pulp mill to the mixing tank.

A method provides for valorization of naturally abundant organic solid biomass under a specified gas atmosphere with the existence of a catalyst structure. The method effectively converts the organic solid feedstock while producing valuable liquid hydrocarbon products, as well as utilizing methane rich resources, providing an economical and environmental benefit in the oil & gas industry.

The present disclosure relates to a method of treating hydrocarbon materials with thermoplastic nature that are liquid at room temperature or become liquid upon heating, to increase their softening point temperature up to 400° C. The method includes the steps of mixing a sulfur-containing gaseous catalyst with the hydrocarbon material in an environmentally controlled reactor, Heating the mixture to a temperature between 280° C. and 480° C. in a flowing gas environment and holding the mixture at this temperature for a period of time from 2 hours to 5 hours and stirring the mixture and maintaining stirring until the hydrocarbon material becomes solid.