C10G1/086

Process for the Preparation of Low Molecular Weight Aromatics (BTX) and Biofuels from Biomass
20200181498 · 2020-06-11 ·

A process for the preparation of aromatic compounds from a feed stream containing biomass or mixtures of biomass, the process comprising: a) subjecting a feed stream containing biomass or mixtures of biomass to a process to afford a conversion product comprising aromatic compounds; b) recovering the aromatic compounds from said conversion product; c) separating a higher molecular weight fraction comprising polyaromatic hydrocarbons (PAH) from a lower molecular weight fraction comprising benzene, toluene and xylene (BTX) by distillation; d) reducing at least part of said higher molecular weight fraction to obtain a reduced fraction comprising polycyclic aliphatics (PCA); and e) subjecting the higher molecular weight fraction obtained in step c), the reduced fraction obtained in step d), or a mixture thereof, to a process to obtain lower molecular weight aromatics (BTX).

PROCESS FOR THE THERMO-CATALYTIC CONVERSION OF POLYMERIC MATERIALS
20200148957 · 2020-05-14 ·

A continuous process for the cracking of a polymeric material, includes the continuous introduction of the polymeric material in a stream or bath of molten catalyst. A plant for the cracking of a polymeric material is also related and includes a closed circuit/environment containing a molten catalyst, and an element adapted to keep the molten catalyst in continuous motion.

Use of a catalyst composition for the catalytic depolymerization of plastics waste

Use of a catalyst composition comprising A) a first component containing oxidic compounds comprising aluminum and silicon with a molar ratio of silicon to aluminum of more than 1) B) a second component containing an oxidic compound of silicon wherein the ratio of the number of acidic sites of component A, determined by temperature programmed desorption with ammonia as a base, to the number of acidic sites of component B, determined under the same conditions, is at least 3: in a process for the catalytic depolymerization of plastics waste.

METHOD OF PREPARATION OF HYDROCARBON FUELS FROM POLYOLEFIN WASTE MATERIALS

Method of producing hydrocarbon fuels from polyolefin waste materials, wherein: polyolefin waste materials are subjected to continuous depolymerisation in a tower flow reactor with a movable packing, which comprises a heating system for heating the lower half of the reaction chamber, where products of depolymerisation are collected in a gaseous state through an outlet in the upper half of the reaction chamber; and the obtained products of depolymerisation are subjected to catalytic hydrogenation and isomerization in an atmosphere of synthesis gas, under atmospheric pressure, to obtain a mixture of hydrocarbon fuels; characterised in that: polyolefin waste materials are mixed with heated elements constituting the packing of the reactor until the surface of the packing elements is coated with a thin layer of plasticised material, wherein in the depolymerisation process that obtained mixture is fed as a stream into the reaction chamber from the top of the chamber, whereas a synthesis gas is fed in a counter current from the bottom, the gas comprising carbon monoxide (CO) and hydrogen (H.sub.2) with the molar ratio CO:H.sub.2 being from 0.25 to 1.5: from 0.5 to 3.

AN FCC CATALYST ADDITIVE AND A PROCESS FOR PREPARATION THEREOF

The present disclosure relates to an FCC catalyst additive for cracking of petroleum feedstock and a process for its preparation. The FCC catalyst additive of the present disclosure comprises at least one zeolite, at least one clay, at least one binder, phosphorous in the form of P.sub.2O.sub.5, and at least one Group IVB metal compound. The FCC catalyst additive of the present disclosure is hydrothermally stable and has improved matrix surface area even after various hydrothermal treatments. The FCC catalyst additive of the present disclosure can be used in combination with the conventional FCC catalyst for catalytic cracking to selectively enhance the propylene and LPG yields.

Electrochemical conversion of lignin to industrial chemicals
10577699 · 2020-03-03 · ·

Lignin is electro-oxidized to commercially useful products using a binary transition metal catalyst. In particular, the transition metal catalyst includes nickel or cobalt as a first metal and any other transition metal as a second metal. The binary catalyst system prevents poisoning of the catalyst, extending the useful life of the catalyst.

Process for producing BTX and alcohols by catalytic pyrolysis of biomass and fermentation of the gaseous pyrolysis effluent

A process is described for producing BTX and alcohols from biomass, by a) catalytic pyrolysis of the biomass in a fluidized-bed reactor producing a gaseous pyrolysis effluent; b) separation of said gaseous pyrolysis effluent into at least one BTX fraction and a gaseous effluent containing at least carbon monoxide and carbon dioxide, c) sending all of the gaseous effluent from separation b) into fermentation producing a liquid fermentation stream containing at least one stream containing at least one oxygenated compound chosen from alcohols, diols, acid alcohols, carboxylic acids, aldehydes, ketones and esters, d) separating the fermentation stream obtained on conclusion of c) into at least the stream containing at least one oxygenated compound, an aqueous fraction, and an unreacted gaseous effluent, e) recycling at least part of unreacted gaseous effluent into the catalytic pyrolysis a).

HYDROLIQUEFACTION OF PETROLEUM COKE USING ALKALI METALS

The present disclosure is directed toward processes for the hydroliquefaction and hydrodesulfurization of petroleum coke using alkali metal catalysts and/or tin co-catalysts.

Conversion of biomass into methane

A process for producing methane from a biomass, biomass-containing and/or biomass-derived feedstock is provided. The process comprises: a) providing in a hydropyrolysis reactor vessel a hydropyrolysis catalyst composition, said composition comprising one or more active metals supported on an oxide-based support, said one or more active metals comprising at least one of cobalt and nickel and said one or more active metals being present in total in an amount in the range of from 2 to 75 wt % based on the overall weight of the catalyst composition; b) contacting the feedstock with said hydropyrolysis catalyst composition and molecular hydrogen in said hydropyrolysis reactor vessel, to produce a first product stream comprising char, catalyst fines and gases comprising hydrogen and hydrocarbons, of which hydrocarbons at least 70 wt % is methane and, optionally, CO and CO.sub.2; and c) removing said char and catalyst fines from said first product stream.

Pulping Liquors and Uses Thereof

The present invention relates generally to the generation of bio-products from organic matter feedstocks. More specifically, the present invention relates to the use of pulping liquors in the hydrothermal/thermochemical conversion of lignocellulosic and/or fossilised organic feedstocks into biofuels (e.g. bio-oils) and/or chemical products (e.g. platform chemicals).