The chemical conversion of renewable oil to obtain a hydrocarbon product suitable as a fuel, includes (i) renewable oil including corn distillers oil (CDO), fatty acid glyceryl esters (FAGE), triacylglycerols (TAG), lipids, and free fatty acids (FFA), which are derived from non-fossil-fuel sources that include animals, plants, vegetables, fruits, grains, algae, and plankton (collectively “oil”); (ii) the chemical transformation of the oil by substantially reducing or eliminating the carboxylate functionality and native unsaturations of fatty acids contained therein; (iii) wherein the hydrocarbon product is substantially a mixture of saturated hydrocarbons, or alkanes, originating from corresponding structures in the oil, e.g., the hydrocarbon chains of fatty acids; and (iv) the product mixture is suitable as fuel that may be blended with or be used in place of fuel such as diesel derived from petroleum.

A method for producing a pyrolysis oil is described. In said method, a feedstock to be treated is first pyrolyzed in a pyrolysis zone, in which the feedstock is heated to a temperature of 250 degrees Celsius to 700 degrees Celsius; and pyrolyzed solids and pyrolysis vapors are formed. The pyrolysis vapors are then reformed at a temperature of 450 degrees Celsius to 1,200 degrees Celsius in a post-conditioning zone, in which the pyrolysis vapors are brought into contact with a catalyst bed, wherein the pyrolysis oil is formed. In this case, the catalyst comprises a pyrolyzed solid, which can be obtained according to the pyrolysis, described above. Finally the pyrolysis oil is separated from the additional pyrolysis products, which are formed, in a separation unit.

The present disclosure relates to a method for producing renewable ketones, paraffin waxes, base oil components and alkenes from a feedstock of biological origin, wherein the method includes ketonisation of esters of fatty acids and monohydric alcohols wherein the alcohols have carbon chain length of two or more.

A process is provided for the catalytic cracking of a glyceride oil feedstock with a catalyst composition containing a phosphorus-containing ZSM-5 light olefins additive.

The present invention relates to processes for the preparation of biofuel from biomass by fast hydropyrolysis or fast pyrolysis, using hydrogen generated by sorption enhanced steam reforming. The present invention also relates to fixed bed tandem catalytic-upgrading processes, and reactors and hydrodeoxygenation (HDO) catalysts useful in those processes.

Methods for eliminating environmental contaminants using biomass are disclosed. The methods may include combining at least a portion of a biomass and a solvent within a reactor of a hydrothermal liquefaction system, where at least the portion of the biomass having absorbed and includes an environmental contaminant. The method may also include heating the combination of at least the portion of the biomass and the solvent under predetermined operational characteristics, and generating a plurality of byproducts free of the environmental contaminant.

A process for preparing a catalyst comprises coating substantial internal surfaces of porous inorganic powders with titanium oxide to form titanium oxide-coated inorganic powders. After the coating, an extrudate comprising the titanium oxide-coated inorganic powders is formed and calcined to form a catalyst support. Then, the catalyst support is impregnated with a solution containing one or more salts of metal selected from the group consisting of molybdenum, cobalt, and nickel.

A number of different branched hydrocarbon compounds (formula I) having a star-like configuration (S) are prepared from renewable oils containing fatty acids or derivatives containing fatty acids. The branched hydrocarbon compounds may be isolated individually or in mixtures, and may be used as part of base oils, such as renewable base oils (RBOs). A process for preparing the branched hydrocarbon compounds of formula I involve conditions that favour a trimerisation reaction followed by hydrotreating conditions. The compounds of formula I may be made by catalytically treating renewable material in a process, and the compounds have desirable qualities relating to lubrication, cold flow as well as having a low Noack volatility.

Hydrotreatment of biological oil is disclosed for producing renewable base oil and a diesel oil from low value biological oils. Low value biological oils containing free fatty acids and fatty acid esters can be processed into a renewable base oil and a renewable diesel oil in an efficient manner by first separating at least part of the free fatty acids from the feedstock and then processing separately this free acid feed in a ketonisation reaction followed by hydrodeoxygenation and hydroisomerisation reactions to yield a renewable base oil stream. The remaining free fatty acid depleted feed is processed in a separate hydrodeoxygenation and hydroisomerisation step to yield a renewable diesel stream.

Described is a novel process for disaggregating biomass pyrolysis oil quantitatively into energy dense hydrophobic aromatic fraction (HAF), fermentable pyrolytic sugars and phenolics based products in a highly economical and energy efficient manner. Phase separation of the esterified pyrolysis oil after an oxidative pre-treatment and the quantitative recovery of the separate fractions is described. Phase separation uses batch as well as continuous reactor systems. The resulting HAF is an energy dense, thermally stable, water free, non-corrosive to carbon steel, and is a free flowing liquid suitable for combustion and for upgrading to transportation fuels. Pyrolytic sugars which are mainly anhydrosugars can be further converted by fermentation to ethanol or other products. Monomeric phenols are useful industrial intermediates and the organic acids in the original pyrolysis oil are mainly recovered as esters of the separation solvents.