C10G3/52

METHOD OF PREPARATION OF HYDROCARBON FUELS FROM POLYOLEFIN WASTE MATERIALS

Method of producing hydrocarbon fuels from polyolefin waste materials, wherein: polyolefin waste materials are subjected to continuous depolymerisation in a tower flow reactor with a movable packing, which comprises a heating system for heating the lower half of the reaction chamber, where products of depolymerisation are collected in a gaseous state through an outlet in the upper half of the reaction chamber; and the obtained products of depolymerisation are subjected to catalytic hydrogenation and isomerization in an atmosphere of synthesis gas, under atmospheric pressure, to obtain a mixture of hydrocarbon fuels; characterised in that: polyolefin waste materials are mixed with heated elements constituting the packing of the reactor until the surface of the packing elements is coated with a thin layer of plasticised material, wherein in the depolymerisation process that obtained mixture is fed as a stream into the reaction chamber from the top of the chamber, whereas a synthesis gas is fed in a counter current from the bottom, the gas comprising carbon monoxide (CO) and hydrogen (H.sub.2) with the molar ratio CO:H.sub.2 being from 0.25 to 1.5: from 0.5 to 3.

Low temperature, low pressure upgrading and stabilization of bio-oil or bio-oil fractions

The present application discloses low temperature, low pressure methods (LTLP) for upgrading and/or stabilizing bio-oil or a bio-oil fraction. One method comprises providing a bio-oil or bio-oil fraction and hydrogen, which are reacted in the presence of a catalyst at a temperature of less than 150 C. and a pressure of less than 100 bar (absolute) to produce a hydrogenated liquid oil at a carbon yield of over 75%. Another method comprises providing a bio-oil or bio-oil fraction, providing oxygen reducing reaction conditions, and reacting the bio-oil or bio-oil fraction under the oxygen reducing reaction conditions at LTLP to produce an upgraded bio-oil product containing fewer carbonyls than the bio-oil or bio-oil fraction. Yet another method comprises providing a bio-oil or bio-oil fraction and a solution comprising one or more fermentation organisms and a sugar source. The solution and bio-oil or bio-oil fraction are combined to obtain a fermentation mixture, which is incubated at 15 C. to 30 C. for 16 to 72 hours to produce an upgraded bio-oil fermentation product containing fewer carbonyls than the bio-oil or bio-oil fraction.

Process and system for producing fuel
11946001 · 2024-04-02 · ·

A process and/or system for producing fuel using renewable hydrogen having a reduced carbon intensity. The renewable hydrogen is produced in a hydrogen production process comprising methane reforming, wherein at least a portion of the feedstock for the hydrogen production process comprises upgraded biogas sourced from a plurality of biogas plants. Each of the upgraded biogases is produced in a process that includes collecting biogas comprising methane and carbon dioxide, capturing at least 50% of the carbon dioxide originally present in the collected biogas and producing the upgraded biogas. Storage of the captured carbon dioxide reducing a carbon intensity of the fuel, without having to provide carbon capture and storage of carbon dioxide from hydrogen production.

METHOD AND SYSTEM FOR PRODUCING AROMATIC HYDROCARBONS FROM A RENEWABLE RESOURCE
20190367817 · 2019-12-05 · ·

Disclosed are a method and a system for producing bio-derived aromatic hydrocarbons from a renewable resource. More particularly, the disclosure provides for the co-location of a biomass reactor unit and an aromatization reactor unit to produce benzene from a renewable source such as plant mass. Hexane produced from cellulose in the biomass reactor unit can be converted to benzene in the aromatization reactor unit and hydrogen produced in the aromatization reactor unit can be used in the biomass reactor unit. Also described is the use of a mixture of bio-derived hexane produced from cellulose and naphtha in an aromatization process.

Method and system for producing aromatic hydrocarbons from a renewable resource

Disclosed are a method and a system for producing bio-derived aromatic hydrocarbons from a renewable resource. More particularly, the disclosure provides for the co-location of a biomass reactor unit and an aromatization reactor unit to produce benzene from a renewable source such as plant mass. Hexane produced from cellulose in the biomass reactor unit can be converted to benzene in the aromatization reactor unit and hydrogen produced in the aromatization reactor unit can be used in the biomass reactor unit. Also described is the use of a mixture of bio-derived hexane produced from cellulose and naphtha in an aromatization process.

Solvolysis process

The present disclosure relates to the thermal liquefaction of lignin, and more particularly to lignin solvolysis of a lignin feedstock chosen based on its molecular weight. The process comprises subjecting a feed mixture (30) of lignin feedstock (10) and solvent (20) to a thermal liquefaction step by heating (110) the feed mixture (30) at a temperature between 360 and 420? C., separating (120) a liquid product mix (50) from a product mix (40); and recirculating at least part of said liquid product mix (50) as an oil fraction of said solvent (20).

System and methods for renewable fuels

A method may include: hydropyrolyzing a bio feedstock in a hydropyrolysis unit to produce at least a hydropyrolysis oil; introducing at least a portion of the hydropyrolysis oil with a hydrocarbon co-feed into a fluidized catalytic cracking unit; and cracking the hydropyrolysis oil in the fluidized catalytic cracking unit to produce at least fuel range hydrocarbons.

Process for production of aviation kerosene from a stream rich in aromatic compounds of renewable source

The present invention refers to the processing of a 100% renewable load in FCC units, wherein the load comprises triglycerides of vegetable and animal source, free fatty acids, fatty acid esters, ketones, alcohols and long-chain aldehydes, using catalyst and appropriate operating conditions in order to obtain 100% renewable products with a high content of aromatic compounds, in the range of naphtha, kerosene, diesel and heavy gas oil. The product thus obtained complies with all the properties of the ASTM D1655 standard, even for contents of up to 10% renewable content. In addition, there is no need to reduce the freezing point of the fossil QAV for the introduction of the renewable component, with no impact on the yield and economy of the process.

Diesel-soluble lignin oils and methods of their production

Solvent consumption in supercritical ethanol, propanol or butanol treatment of either refined pre-extracted lignin or comparatively impure lignin-rich solid residual from hydrothermally pretreated lignocellulosic biomass can be minimized by conducting the reaction at very high loading of lignin to solvent. Comparatively impure, crude lignin-rich solid residual can be directly converted by supercritical alcohol treatment to significantly diesel-soluble lignin oil without requirement for pre-extraction or pre-solubilization of lignin or for added reaction promoters such as catalysts, hydrogen donor co-solvents, acids, based or H2 gas. O:C ratio of product oil can readily be obtained using crude lignin residual in such a process at levels 0.20 or lower.

Integrated hydrogen production and bio-renewable conversion process

A bio-renewable conversion process for making fuel from bio-renewable feedstocks is combined with a hydrogen production process that includes recovery of CO.sub.2. The integrated process uses a purge gas stream comprising hydrogen from the bio-renewable hydrocarbon production process in the hydrogen production process.