The invention relates to a pipe for thermal cracking of hydrocarbons in the presence of steam, in which the feed mixture is guided through externally heated pipes, wherein the pipe extends along a longitudinal axis and has a number N.sub.T of grooves that have been introduced into the inner surface of the pipe and extend in a helix around the longitudinal axis along the inner surface, the inner surface into which the grooves have been introduced, in a cross section at right angles to the longitudinal axis, has a diameter Di and a radius r.sub.1=Di/2, the grooves in the cross section at right angles to the longitudinal axis, in their groove base, each have the form of a circular arc and the circular arc has a radius r.sub.2, and
the grooves each have a groove depth TT which, in the cross section at right angles to the longitudinal axis, corresponds in each case to the smallest distance between the circle having the diameter Di on which the inner surface lies and the center of which lies on the longitudinal axis, and the furthest removed point of the groove base of the grooves from the longitudinal axis.

An anti-coking equipment, a preparation method therefor, and the use thereof. The preparation method comprises: bringing a low-oxygen partial pressure gas into contact with an equipment for reaction to obtain an anti-coking equipment containing an oxide film on the inner surface, wherein the dew point of the low-oxygen partial pressure gas is -40° C. to 40° C.

A dense and stable oxide film is formed on the inner surface of the equipment prepared by the method, which can inhibit or slow down the catalytic coking phenomenon, reduce the degree of equipment carburization, and prolong the service life of the equipment.

Processes herein may be used to thermally crack various hydrocarbon feeds, and may eliminate the refinery altogether while making the crude to chemicals process very flexible in terms of crude. In embodiments herein, crude is progressively separated into at least light and heavy fractions. Depending on the quality of the light and heavy fractions, these are routed to one of three upgrading operations, including a fixed bed hydroconversion unit, a fluidized catalytic conversion unit, or a residue hydrocracking unit that may utilize an ebullated bed reactor. Products from the upgrading operations may be used as feed to a steam cracker.

A method of mitigating fouling in a delayed coking unit heater may include forming a plastic mixture including a plastic material and a carrier. The plastic mixture may be combined with a coker feedstock upstream of a coke drum.

A method of mitigating fouling in a delayed coking unit heater may include forming a plastic mixture including a plastic material and a carrier. The plastic mixture may be combined with a coker feedstock upstream of a coke drum.

A process for producing hydrocarbons includes providing a component mixture containing hydrocarbons and a feed mixture containing hydrocarbons having two or more carbon atoms and lower boiling compounds using a portion of the component mixture, and forming a heavy fraction and a light fraction using the feed mixture. The heavy fraction contains a portion of the hydrocarbons from the feed mixture and is at least poor in the lower boiling components. The light fraction contains a portion of the lower boiling components from the feed mixture and is at least poor in the hydrocarbons from the feed mixture. The heavy fraction and a first intermediate fraction are formed using some of the feed mixture in low-temperature separation. Some of the first intermediate fraction is subjected to non-cryogenic separation while obtaining the light fraction and a second intermediate fraction. A portion of the second intermediate fraction is recycled to the process.

Processes herein may be used to thermally crack various hydrocarbon feeds, and may eliminate the refinery altogether while making the crude to chemicals process very flexible in terms of crude. In embodiments herein, crude is progressively separated into at least light and heavy fractions. Depending on the quality of the light and heavy fractions, these are routed to one of three upgrading operations, including a fixed bed hydroconversion unit, a fluidized catalytic conversion unit, or a residue hydrocracking unit that may utilize an ebullated bed reactor. Products from the upgrading operations may be used as feed to a steam cracker.

A reactor shell for producing olefins via steam cracking from a fed reactive mixture stream composed of steam and hydrocarbons comprising: at least one reactive stream duct formed within said reactor shell, at least one structured ceramic bed having a plurality of hollow flow paths, at least one electrical resistance heating element for heating the reactive mixture stream up to a predetermined reaction temperature and a coating provided on a surface contacting with the reactive mixture stream is provided. The reactor shell is characterized by that said electrical resistance heating element that is arranged inside at least some of said hollow flow paths in a manner that there still remains a flowing passage inside the hollow flow paths.

A reactor shell for producing olefins via steam cracking from a fed reactive mixture stream composed of steam and hydrocarbons comprising: at least one reactive stream duct formed within said reactor shell, at least one structured ceramic bed having a plurality of hollow flow paths, at least one electrical resistance heating element for heating the reactive mixture stream up to a predetermined reaction temperature and a coating provided on a surface contacting with the reactive mixture stream is provided. The reactor shell is characterized by that said electrical resistance heating element that is arranged inside at least some of said hollow flow paths in a manner that there still remains a flowing passage inside the hollow flow paths.

In some examples, a flow of hydrocarbon feed can be introduced into a pyrolysis furnace that includes a first radiant coil and a second radiant coil. At least a portion of the hydrocarbon feed can be pyrolysed in the first radiant coil and the second radiant coil to produce a pyrolysis effluent and to deposit coke on an inner surface of each of the first radiant coil and the second radiant coil. The flow of the hydrocarbon feed can be decreased into the first radiant coil and the flow of the hydrocarbon feed into the second radiant coil can be maintained, wherein the flow of the hydrocarbon feed into the pyrolysis furnace can be decreased by about 10 vol. % to about 90 vol. %. A decoking feed including steam at a pressure of ≥690 kPag can be introduced into the first radiant coil of the pyrolysis furnace to remove at least a portion of the coke deposited on the inner surface of the first radiant coil.