In chemical processes for cracking hydrocarbons, reactors are subject to coking During the decoke process carburization of the metal substrate can occur, negatively impacting reactor life. Decokes are also costly due to down-time where costs are incurred without production of commercial products. Reducing the frequency of decokes provides an opportunity to reduce the financial impacts of downtimes. A start-up procedure is described herein that limits initial coke deposition, leading to a reduced tendency for carburization of the metal substrate, improving reactor life, and more importantly, extending reactor run length.

A system and a method for steam cracking hydrocarbons are disclosed. The system includes a steam cracking furnace that includes ceramic radiant coils. The system is configured to heat the radiant coils by oxy-fuel combustion in the firebox. The system further includes an oxygen production unit configured to produce pure oxygen used for the oxy-fuel combustion. The effluent from the steam cracking furnace can be further separated into various product streams or fed into a polymerization unit.

A system and a method for steam cracking hydrocarbons are disclosed. The system includes a steam cracking furnace that includes ceramic radiant coils. The system is configured to heat the radiant coils by oxy-fuel combustion in the firebox. The system further includes an oxygen production unit configured to produce pure oxygen used for the oxy-fuel combustion. The effluent from the steam cracking furnace can be further separated into various product streams or fed into a polymerization unit.

Processes and systems for pyrolysing a hydrocarbon feed for a predetermined period of time, e.g., by steam cracking. The process can include determining a first amount of silicon material present in the hydrocarbon feed that is to be steam cracked to produce a steam cracker effluent. The process can also include determining a second amount of silicon material that will be present in a steam cracker naphtha that is to be separated from the steam cracker effluent.

A system and method for processing pyrolysis gasoline is disclosed. The system and method involves separating a pyrolysis gasoline stream to produce a first stream comprising primarily un-hydrogenated C.sub.9+ compounds. The separating of the pyrolysis e gasoline occurs without hydrogenation being carried out on the pyrolysis gasoline before the separating.

A system and method for processing pyrolysis gasoline is disclosed. The system and method involves separating a pyrolysis gasoline stream to produce a first stream comprising primarily un-hydrogenated C.sub.9+ compounds. The separating of the pyrolysis e gasoline occurs without hydrogenation being carried out on the pyrolysis gasoline before the separating.

A method of depolymerizing polymeric material including the steps of: (a) feeding a polymeric material to a depolymerization reactor maintained at a temperature in the range of from 400° C. to 600° C. and operated under a pressure in the range of from 4 to 15 barg; and (b) depolymerizing at least a portion of the polymeric material thereby forming a first gaseous product and a first liquid product.

The invention relates to C.sub.5+ hydrocarbon conversion. More particularly, the invention relates to separating a vapor phase product and a liquid phase product from a heated mixture that includes steam and C.sub.5+ hydrocarbons, catalytically cracking the liquid phase product and steam cracking the vapor phase product.

The invention relates to an ethylene plant, comprising a cracking furnace for converting a hydrocarbon feedstock into a cracked gas stream; a separation section to provide at least an ethylene-enriched product stream, a hydrogen-enriched fuel stream and a methane-enriched fuel stream from the cracked gas stream; a passage way for feeding at least part of the hydrogen-enriched fuel from the separation section to a burner of the cracking furnace and/or a passage way for feeding at least part of the hydrogen-enriched fuel from the separation section to a burner of a waste heat recovery boiler of a combined cycle gas turbine power plant(CCGT); a methane storage configured for storing methane-enriched fuel and a passage way for feeding at least part of the methane-enriched fuel from the separation section to the storage; the CCGT, comprising a gas turbine—comprising a combustor—and a passage way for feeding at least part of the methane-enriched fuel from the storage to the combustor of the gas turbine of the CCGT, which CCGT is configured to generate electric power and/or to generate high pressure steam to drive a steam turbine forming part of a steam generation circuit of the ethylene plant; and an electric power connection for providing part of the power for operating the plant, which is a connection to an electric power system to produce electric power from a renewable source.

The present application relates to a process for cracking a hydrocarbon feedstock, using to the largest extent electrically powered equipment where the power is obtained from renewable sources or low-carbon sources. In particular, it relates to a furnace for steam cracking a hydrocarbon feedstock, wherein the furnace comprises one or more tubes for transporting the hydrocarbon feedstock and dilution steam; and an electrically heated infrared emitter for transferring heat to the tubes. It also relates to a process for steam cracking a hydrocarbon feedstock using infrared radiation.