Patent classifications
C10G9/36
METHODS FOR OPERATING ACETYLENE HYDROGENATION UNITS IN INTEGRATED STEAM CRACKING AND FLUIDIZED CATALYTIC DEHYDROGENATION SYSTEMS
A method for operating an acetylene hydrogenation unit in an integrated steam cracking-fluidized catalytic dehydrogenation (FCDh) system may include separating a cracked gas from a steam cracking system and an FCDh effluent from an FCDh system into a hydrogenation feed and an acetylene-depleted stream, the hydrogenation feed comprising at least hydrogen, CO, and acetylene. During normal operating conditions, at least 20% of the CO in the hydrogenation feed is from the cracked gas. The method may include contacting the hydrogenation feed with an acetylene hydrogenation catalyst to hydrogenate at least a portion of the acetylene in the hydrogenation feed to produce a hydrogenated effluent. The steam cracking is operated under conditions that increase CO production such that a concentration of CO in the cracked gas is great enough that when a flowrate of the FCDh effluent is zero, a CO concentration in the hydrogenation feed is at least 100 ppmv.
APPARATUS AND PROCESS FOR THE ENHANCED PRODUCTION OF AROMATIC COMPOUNDS
Embodiments of the present disclosure are directed to a process for the upgrading of petroleum products comprising subjecting a diesel feed to a hydrocracking process, thereby producing a hydrocrackate fraction; subjecting the hydrocrackate fraction to a catalytic reforming process, thereby producing a reformate; and recovering aromatics from the reformate. In accordance with another embodiment of the present disclosure, a method of producing aromatics may comprise introducing a diesel feed to a hydrocracking unit to produce a hydrocrackate fraction, passing the hydrocrackate fraction to a catalytic reforming unit to produce a reformate, and passing the reformate to an aromatic recovery complex to produce an aromatic fraction. In accordance with yet another embodiment of the present disclosure, an apparatus for the upgrading of petroleum products may comprise a hydrocracker, a catalytic reformer, and an aromatic recovery complex. The hydrocracker may be in fluid communication with the catalytic reformer, the catalytic reformer may be in fluid communication with an aromatic recovery complex, and the hydrocracker may be structurally configured to receive a diesel feed.
APPARATUS AND PROCESS FOR THE ENHANCED PRODUCTION OF AROMATIC COMPOUNDS
Embodiments of the present disclosure are directed to a process for the upgrading of petroleum products comprising subjecting a diesel feed to a hydrocracking process, thereby producing a hydrocrackate fraction; subjecting the hydrocrackate fraction to a catalytic reforming process, thereby producing a reformate; and recovering aromatics from the reformate. In accordance with another embodiment of the present disclosure, a method of producing aromatics may comprise introducing a diesel feed to a hydrocracking unit to produce a hydrocrackate fraction, passing the hydrocrackate fraction to a catalytic reforming unit to produce a reformate, and passing the reformate to an aromatic recovery complex to produce an aromatic fraction. In accordance with yet another embodiment of the present disclosure, an apparatus for the upgrading of petroleum products may comprise a hydrocracker, a catalytic reformer, and an aromatic recovery complex. The hydrocracker may be in fluid communication with the catalytic reformer, the catalytic reformer may be in fluid communication with an aromatic recovery complex, and the hydrocracker may be structurally configured to receive a diesel feed.
Process for converting a feedstock containing pyrolysis oil
The invention relates to a process for converting a feedstock comprising pyrolysis oil and a heavy hydrocarbon-based feedstock, with: a) a step of hydroconversion in a reactor; b) a step of separating the liquid effluent obtained from step a) into a naphtha fraction, a gas oil fraction, a vacuum gas oil fraction and an unconverted residue fraction; c) a step of hydrocracking of the vacuum gas oil fraction; d) a step of fractionating the hydrocracked liquid effluent obtained from step c) into a naphtha fraction, a gas oil fraction and a vacuum gas oil fraction; e) a step of steam cracking of a portion of the naphtha fraction obtained from step d); f) a step of fractionating at least a portion of the steam-cracked effluent obtained from step e); g) a step in which the pyrolysis oil fraction obtained from step f) is sent into step a).
Process for converting a feedstock containing pyrolysis oil
The invention relates to a process for converting a feedstock comprising pyrolysis oil and a heavy hydrocarbon-based feedstock, with: a) a step of hydroconversion in a reactor; b) a step of separating the liquid effluent obtained from step a) into a naphtha fraction, a gas oil fraction, a vacuum gas oil fraction and an unconverted residue fraction; c) a step of hydrocracking of the vacuum gas oil fraction; d) a step of fractionating the hydrocracked liquid effluent obtained from step c) into a naphtha fraction, a gas oil fraction and a vacuum gas oil fraction; e) a step of steam cracking of a portion of the naphtha fraction obtained from step d); f) a step of fractionating at least a portion of the steam-cracked effluent obtained from step e); g) a step in which the pyrolysis oil fraction obtained from step f) is sent into step a).
PRODUCTION OF LINEAR OLEFINS FROM HEAVY OIL
A process for producing olefins comprising the steps of separating the liquid oil in the fractionator to produce a light oil product; separating the light oil product in the extractor to produce a paraffin fraction stream; increasing a pressure of the paraffin fraction stream in a paraffin pump to produce a pressurized paraffin stream; mixing the pressurized paraffin stream with a pressurized water feed in the water mixer to produce a paraffin-containing water stream; heating the paraffin-containing water stream in the water heater to produce a hot paraffin-water stream, wherein a temperature of the hot paraffin-water stream is greater than 450 deg C, wherein the short chain paraffins are operable to crack at the temperature of the hot paraffin-water stream; mixing the hot paraffin-water stream and the hot feedstock in the feed mixer to produce a mixed feed stream; and introducing the mixed feed stream to the supercritical unit.
Method and system for obtaining polymerizable aromatic compounds
The invention relates to a process (100) for deriving polymerizable aromatic compounds having nine carbon atoms (S) in which a component mixture (B) is formed at least partially by steam cracking, in which the component mixture (B) is subjected to a workup (2, 3, 4, 5) comprising a gasoline removal (5) and thereafter is a compression (8) and a fractionation (10), and wherein one or more pyrolysis gasoline fractions (H, L) is or are formed in the gasoline removal (5) and/or the compression (8). The invention provides that a separation feed is formed which comprises predominantly exclusively pyrolysis gasoline from the or at least one of the pyrolysis gasoline fractions (H, L) and that the separation feed is subjected to a separation (7), wherein in the separation (7) at least one fraction (P) enriched in aromatic compounds having nine carbon atoms compared to the separation feed is formed. A corresponding plant likewise forms part of the subject matter of the invention.
Method and system for obtaining polymerizable aromatic compounds
The invention relates to a process (100) for deriving polymerizable aromatic compounds having nine carbon atoms (S) in which a component mixture (B) is formed at least partially by steam cracking, in which the component mixture (B) is subjected to a workup (2, 3, 4, 5) comprising a gasoline removal (5) and thereafter is a compression (8) and a fractionation (10), and wherein one or more pyrolysis gasoline fractions (H, L) is or are formed in the gasoline removal (5) and/or the compression (8). The invention provides that a separation feed is formed which comprises predominantly exclusively pyrolysis gasoline from the or at least one of the pyrolysis gasoline fractions (H, L) and that the separation feed is subjected to a separation (7), wherein in the separation (7) at least one fraction (P) enriched in aromatic compounds having nine carbon atoms compared to the separation feed is formed. A corresponding plant likewise forms part of the subject matter of the invention.
Ultrasonic oxidative desulfurization of heavy fuel oils
The invention relates to systems and methods for ultrasonic oxidative desulfurization of heavy fuel oils. In various embodiments, the methods include combinations of ultrasonic sulfone decomposition processes and/or catalytic decomposition processes.
Process for C5+ Hydrocarbon Conversion
In some examples, hydrocarbon feed and a diluent such as steam are mixed, and heated. A vapor phase product and a liquid phase product can be separated from the heated mixture. The liquid phase product can be hydroprocessed to produce a first hydroprocessed product. A pitch and one or more hydrocarbon products can be separated from the first hydroprocessed product. The pitch can be contacted with a diluent to produce a pitch-diluent mixture. The pitch-diluent mixture can be hydroprocessed to produce a second hydroprocessed product. A hydroprocessor heavy product and a utility fluid product can be separated from the second hydroprocessed product. The diluent can be or include at least a portion of the utility fluid product. The vapor phase product can be steam cracked to produce a steam cracker effluent. A tar product and a process gas that can include ethylene and propylene can be separated from the steam cracker effluent.