A method of upgrading a petroleum feedstock, the method comprising the steps of introducing a disulfide oil, a water feed, and a petroleum feedstock to a supercritical water upgrading unit, and operating the supercritical water upgrading unit to produce a product gas stream, a product oil stream, and a used water stream.

A process for increasing conversion and selectivity to normal paraffins is achieved by reducing the hydrogen to hydrocarbon ratio for paraffin feeds with substantial butanes. A separator may be used to remove excess hydrogen from a first isomerate before a second isomerization step that may isomerize additional butanes perhaps generated in the first isomerization step.

A process for increasing conversion and selectivity to normal paraffins is achieved by reducing the hydrogen to hydrocarbon ratio for paraffin feeds with substantial butanes. A separator may be used to remove excess hydrogen from a first isomerate before a second isomerization step that may isomerize additional butanes perhaps generated in the first isomerization step.

A high-pressure steam stream produced from the waste heat recovery system of a syngas producing unit may be superheated and then supplied to a steam turbine in a hydrocarbon production plant to produce an expanded steam stream and shaft power. A portion of the expanded stream can be fed into the reforming reactor in the syngas producing unit. The shaft power can be used to drive compressors and pumps in an olefins production plant. Considerable energy efficiency and capital investment savings can be realized by such steam integration compared to running the olefins production plant separately.

A high-pressure steam stream produced from the waste heat recovery system of a syngas producing unit may be superheated and then supplied to a steam turbine in a hydrocarbon production plant to produce an expanded steam stream and shaft power. A portion of the expanded stream can be fed into the reforming reactor in the syngas producing unit. The shaft power can be used to drive compressors and pumps in an olefins production plant. Considerable energy efficiency and capital investment savings can be realized by such steam integration compared to running the olefins production plant separately.

A method of upgrading oil using supercritical fluids generated by a fuel cell. The process uses supercritical carbon dioxide to control the specific gravity of the oil and supercritical water, the amount of which is controlled to achieve a desired oil/water ratio in processing oils to be upgraded. The process recovers the GHG emission stream from a fuel cell anode exhaust to produce supercritical fluids.

A method of upgrading oil using supercritical fluids generated by a fuel cell. The process uses supercritical carbon dioxide to control the specific gravity of the oil and supercritical water, the amount of which is controlled to achieve a desired oil/water ratio in processing oils to be upgraded. The process recovers the GHG emission stream from a fuel cell anode exhaust to produce supercritical fluids.

A hydrocarbon conversion process comprises pyrolysing at a temperature ≥700° C. a feedstock comprising hydrocarbon to produce a pyrolysis effluent comprising at least one C.sub.2 to C.sub.4 olefin and C.sub.5+ aliphatic and aromatic hydrocarbons. The pyrolysis effluent is contacted with an oleaginous quench stream to reduce the temperature of the pyrolysis effluent to ≤400° C. At least first and second streams are separated from the cooled effluent. The first stream comprises at least one C.sub.2 to C.sub.4 olefin, and the second stream comprises a quench oil having an average boiling point at atmospheric pressure of at least 120° C. At least a portion of the second stream is catalytically hydroprocessed to produce a hydroprocessed stream, which is combined with at least a portion of any remainder of the second stream to form the quench stream.

A hydrocarbon conversion process comprises pyrolysing at a temperature ≥700° C. a feedstock comprising hydrocarbon to produce a pyrolysis effluent comprising at least one C.sub.2 to C.sub.4 olefin and C.sub.5+ aliphatic and aromatic hydrocarbons. The pyrolysis effluent is contacted with an oleaginous quench stream to reduce the temperature of the pyrolysis effluent to ≤400° C. At least first and second streams are separated from the cooled effluent. The first stream comprises at least one C.sub.2 to C.sub.4 olefin, and the second stream comprises a quench oil having an average boiling point at atmospheric pressure of at least 120° C. At least a portion of the second stream is catalytically hydroprocessed to produce a hydroprocessed stream, which is combined with at least a portion of any remainder of the second stream to form the quench stream.

Integrated pyrolysis and hydrocracking systems and processes for efficiently cracking of hydrocarbon mixtures, such as mixtures including compounds having a normal boiling temperature of greater than 450° C., 500° C., or even greater than 550° C., such as whole crudes for example, are disclosed.