The present invention relates to an improved CuAl.sub.2O.sub.4 spinel based catalyst additive composition having bi-modal pore size for improving gasoline sulfur removal activity by maintaining high gasoline selectivity and maintaining research octane number (RON) while cracking heavier hydrocarbon feedstocks in the fluid catalytic cracking unit. More particularly, present invention relates to a gasoline sulfur reduction (GSR) additive comprising copper aluminate spinel, acidic alumina matrix; and clay, wherein the additive having bimodal pore distribution. Present invention also relates to a process for preparing the gasoline sulfur reduction (GSR) additive.

The present invention relates to an improved CuAl.sub.2O.sub.4 spinel based catalyst additive composition having bi-modal pore size for improving gasoline sulfur removal activity by maintaining high gasoline selectivity and maintaining research octane number (RON) while cracking heavier hydrocarbon feedstocks in the fluid catalytic cracking unit. More particularly, present invention relates to a gasoline sulfur reduction (GSR) additive comprising copper aluminate spinel, acidic alumina matrix; and clay, wherein the additive having bimodal pore distribution. Present invention also relates to a process for preparing the gasoline sulfur reduction (GSR) additive.

A paraffin having 2-8 carbon atoms may be dehydrogenated by contacting the paraffin with metal oxide catalyst(s) to produce light olefins, such as propylene, under certain reaction conditions in a riser, fluidized bed, or fixed-bed swing reactor. The resulting metal oxide catalyst fines contained in the reactor effluent stream formed by the dehydrogenation reaction may be recovered by contacting the reactor effluent stream with a wash fluid to form a catalyst effluent stream that is subsequently slurried and filtered to capture the catalyst fines for potential reuse.

A hydroprocessing catalyst has been developed. The catalyst is a crystalline transition metal molybdotungstate material or metal sulfides derived therefrom, or both. The hydroprocessing using the crystalline transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

A hydroprocessing catalyst has been developed. The catalyst is a crystalline transition metal molybdotungstate material or metal sulfides derived therefrom, or both. The hydroprocessing using the crystalline transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

A hydroprocessing catalyst has been developed. The catalyst is a crystalline transition metal molybdotungstate material or metal sulfides derived therefrom, or both. The hydroprocessing using the crystalline transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. A data system comprising at least one processor; at least one memory storing computer-executable instructions; and at least one receiver configured to receive data of at least one unit or stream in fluid communication with and downstream from or upstream to a conversion process comprising at least one reaction catalyzed by the catalyst or a metal sulfide decomposition product of the catalyst has been developed.

A hydroprocessing catalyst has been developed. The catalyst is a crystalline transition metal molybdotungstate material or metal sulfides derived therefrom, or both. The hydroprocessing using the crystalline transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. A data system comprising at least one processor; at least one memory storing computer-executable instructions; and at least one receiver configured to receive data of at least one unit or stream in fluid communication with and downstream from or upstream to a conversion process comprising at least one reaction catalyzed by the catalyst or a metal sulfide decomposition product of the catalyst has been developed.

A hydroprocessing catalyst has been developed. The catalyst is a crystalline transition metal molybdotungstate material or metal sulfides derived therefrom, or both. The hydroprocessing using the crystalline transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. A data system comprising at least one processor; at least one memory storing computer-executable instructions; and at least one receiver configured to receive data of a conversion process comprising at least one reaction catalyzed by the catalyst or a metal sulfide decomposition product of the catalyst has been developed.

A hydroprocessing catalyst has been developed. The catalyst is a crystalline transition metal molybdotungstate material or metal sulfides derived therefrom, or both. The hydroprocessing using the crystalline transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. A data system comprising at least one processor; at least one memory storing computer-executable instructions; and at least one receiver configured to receive data of a conversion process comprising at least one reaction catalyzed by the catalyst or a metal sulfide decomposition product of the catalyst has been developed.

Methods of treating hydroconversion catalysts used for cracking of hydrocarbons are described. A method can include mixing an inactive hydroconversion catalyst with a solid hydrocarbon containing material having a melting point of 50 C. or greater. The inactive hydroconversion catalyst/solid hydrocarbon containing material mixture can be contacted with a gaseous stream that includes hydrogen (H.sub.2) and a sulfur-containing compound under conditions sufficient to sulfide the catalyst and carbonize at least a portion of the hydrocarbon containing material on the sulfided catalyst to obtain a treated sulfided hydroconversion catalyst.