A process for the production of oligomerized olefins comprising the following steps: purification of an organic composition (OC1) in at least one adsorber to obtain an organic composition (OC2); oligomerization of organic composition (OC2) in the presence of a catalyst to obtain an organic composition (OC3); distillation of organic composition (OC3) in a distillation column (D1) to obtain an organic composition (OC4) from the upper part of (D1) and an organic composition (OC5) from the lower part of (D1); hydrogenation of organic composition (OC4) to obtain an organic composition (OC11) and regeneration of an adsorber (A1) employing organic composition (OC11) as regeneration media.

Spent zeolite equilibrium catalyst from the fluidized catalytic cracker has a useful function as an adsorbent for jet fuel. Redirecting such spent catalyst saves costs for refinery operations in two ways. The first is by avoiding the costs for disposing of such catalyst as hazardous waste. The second is to reduce the cost of procuring sorbent for the jet fuel decontamination process. Since zeolite is primarily silica and conventional sorbents are also silica, zeolite catalysts are chemically similar. And the equilibrium catalyst may be regenerated in the FCC after its becomes saturated with jet fuel contaminants and re-used.

Spent zeolite equilibrium catalyst from the fluidized catalytic cracker has a useful function as an adsorbent for jet fuel. Redirecting such spent catalyst saves costs for refinery operations in two ways. The first is by avoiding the costs for disposing of such catalyst as hazardous waste. The second is to reduce the cost of procuring sorbent for the jet fuel decontamination process. Since zeolite is primarily silica and conventional sorbents are also silica, zeolite catalysts are chemically similar. And the equilibrium catalyst may be regenerated in the FCC after its becomes saturated with jet fuel contaminants and re-used.

A method for removing contaminants from an process stream that includes the use of reticulated material to filter the process stream. The reticulated material also facilitate process stream flow distribution in process units. The reticulated material can be packed with a void space between a substantial number of the reticulated material that can be varied to enhance filtration and flow distribution. The method of filtering also provides a method of removing contaminants leaving process equipment. The methods can be used on a variety of process streams and process equipment. The reticulated material can include ceramics, metallic materials, and chemical vapor deposition elements. The reticulated material can be of various shapes and sizes, and can also be catalytically active.

A vehicular propulsion system, a vehicular fuel system and a method of producing fuel for an internal combustion engine. A separation unit that makes up a part of the fuel system includes one or more adsorbent-based reaction chambers to selectively receive and separate at least a portion of onboard fuel into octane-enhanced and cetane-enhanced components. Regeneration of an adsorbate takes place through interaction with a solvent, while subsequent separation allows the solvent to be reused. A controller may be used to determine a particular operational condition of the internal combustion engine such that the onboard fuel can be sent to one or more combustion chambers within the internal combustion engine without first passing through the separation unit, or instead to the separation unit in situations where the internal combustion engine may require an octane-rich or cetane-rich mixture.

A method is disclosed for synthesizing MTW framework type zeolites via interzeolite transformation in the presence of polyethyleneimine.

Systems and methods are provided for performing multistage naphtha reforming with intermediate separation of aromatics using a swing adsorption process. Use of a swing adsorption process can allow aromatics to be selectively removed from the intermediate reforming effluent while reducing or minimizing the energy costs for cooling and subsequent reheating of the intermediate reforming effluent. The resulting aromatics-rich stream generated from swing adsorption can have a substantially higher aromatics content than an aromatics-rich stream generated by conventional separation methods during multi-stage naphtha reforming. In some aspects, selective thermal purging (either hot or cold) can be used to further facilitate adsorption or desorption of components by the adsorbent in the swing adsorption vessel.

Systems and methods are provided for performing multistage naphtha reforming with intermediate separation of aromatics using a swing adsorption process. Use of a swing adsorption process can allow aromatics to be selectively removed from the intermediate reforming effluent while reducing or minimizing the energy costs for cooling and subsequent reheating of the intermediate reforming effluent. The resulting aromatics-rich stream generated from swing adsorption can have a substantially higher aromatics content than an aromatics-rich stream generated by conventional separation methods during multi-stage naphtha reforming. In some aspects, selective thermal purging (either hot or cold) can be used to further facilitate adsorption or desorption of components by the adsorbent in the swing adsorption vessel.

A vehicular propulsion system, a vehicular fuel system and a method of producing fuel for an internal combustion engine. A separation unit that makes up a part of the fuel system includes one or more adsorbent-based reaction chambers to selectively receive and separate at least a portion of onboard fuel into octane-enhanced and cetane-enhanced components. Regeneration of an adsorbate takes place through interaction with a solvent, while subsequent separation allows the solvent to be reused. A controller may be used to determine a particular operational condition of the internal combustion engine such that the onboard fuel can be sent to one or more combustion chambers within the internal combustion engine without first passing through the separation unit, or instead to the separation unit in situations where the internal combustion engine may require an octane-rich or cetane-rich mixture.

Disclosed are zeolitic imidazolate framework (ZIF) compositions in which at least a portion of the ligands in its shell have been exchanged with other ligands, and methods of making such shell-ligand-exchanged ZIFs. Also disclosed is the use of such shell-ligand-exchanged ZIFs in hydrocarbon separation processes.