C10G29/26

WATER-BASED FORMULATION OF H2S/MERCAPTAN SCAVENGER FOR FLUIDS IN OILFIELD AND REFINERY APPLICATIONS

Hydrogen sulfide (H.sub.2S) and/or mercaptan scavengers are chemicals that remove H.sub.2S and/or mercaptans from gas, oil and water. Water-based formulations may be made and used employing scavenging compounds having the formulae:

##STR00001##

wherein each R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different and are selected from the group consisting of hydrogen, an alkyl, an alkenyl, an aryl, an acyl, a halogen, a hydroxyl, a nitro, an alkyl ester, an aryl ester, an alkyl ether, an aryl ether, a hydroxymethyl, an anhydride group, an amino, and a sulfide. In one non-limiting embodiment the compounds (A) and (B) do not contain nitrogen atoms. Water-based formulations, such as those using a protic solvent with the above compounds, work well as H.sub.2S scavengers.

WATER-BASED FORMULATION OF H2S/MERCAPTAN SCAVENGER FOR FLUIDS IN OILFIELD AND REFINERY APPLICATIONS

Hydrogen sulfide (H.sub.2S) and/or mercaptan scavengers are chemicals that remove H.sub.2S and/or mercaptans from gas, oil and water. Water-based formulations may be made and used employing scavenging compounds having the formulae:

##STR00001##

wherein each R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different and are selected from the group consisting of hydrogen, an alkyl, an alkenyl, an aryl, an acyl, a halogen, a hydroxyl, a nitro, an alkyl ester, an aryl ester, an alkyl ether, an aryl ether, a hydroxymethyl, an anhydride group, an amino, and a sulfide. In one non-limiting embodiment the compounds (A) and (B) do not contain nitrogen atoms. Water-based formulations, such as those using a protic solvent with the above compounds, work well as H.sub.2S scavengers.

Water-based formulation of H2S/mercaptan scavenger for fluids in oilfield and refinery applications

Hydrogen sulfide (H.sub.2S) and/or mercaptan scavengers are chemicals that remove H.sub.2S and/or mercaptans from gas, oil and water. Water-based formulations may be made and used employing scavenging compounds having the formulae: ##STR00001##
wherein each R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different and are selected from the group consisting of hydrogen, an alkyl, an alkenyl, an aryl, an acyl, a halogen, a hydroxyl, a nitro, an alkyl ester, an aryl ester, an alkyl ether, an aryl ether, a hydroxymethyl, an anhydride group, an amino, and a sulfide. In one non-limiting embodiment the compounds (A) and (B) do not contain nitrogen atoms. Water-based formulations, such as those using a protic solvent with the above compounds, work well as H.sub.2S scavengers.

Water-based formulation of H2S/mercaptan scavenger for fluids in oilfield and refinery applications

Hydrogen sulfide (H.sub.2S) and/or mercaptan scavengers are chemicals that remove H.sub.2S and/or mercaptans from gas, oil and water. Water-based formulations may be made and used employing scavenging compounds having the formulae: ##STR00001##
wherein each R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different and are selected from the group consisting of hydrogen, an alkyl, an alkenyl, an aryl, an acyl, a halogen, a hydroxyl, a nitro, an alkyl ester, an aryl ester, an alkyl ether, an aryl ether, a hydroxymethyl, an anhydride group, an amino, and a sulfide. In one non-limiting embodiment the compounds (A) and (B) do not contain nitrogen atoms. Water-based formulations, such as those using a protic solvent with the above compounds, work well as H.sub.2S scavengers.

Process, method, and system for removing heavy metals from fluids

A process for removing non-volatile, particulate mercury from crudes and condensates is disclosed. Particulate mercury in crudes can be removed by a process of first adding a halogen, such as I.sub.2. The halogen converts at least 10% of the particulate mercury into an oil-soluble mercury compound that cannot be removed by filtration or centrifugation. This oil-soluble mercury compound can then be removed by adsorption onto a solid adsorbent. The process can operate at near ambient conditions. The adsorption step can be carried out by mixing a particulate adsorbent in the halogen-treated crude and then removing it by centrifugation, desalting, filtration, hydrocyclone or by settling.

Process, method, and system for removing heavy metals from fluids

A process for removing non-volatile, particulate mercury from crudes and condensates is disclosed. Particulate mercury in crudes can be removed by a process of first adding a halogen, such as I.sub.2. The halogen converts at least 10% of the particulate mercury into an oil-soluble mercury compound that cannot be removed by filtration or centrifugation. This oil-soluble mercury compound can then be removed by adsorption onto a solid adsorbent. The process can operate at near ambient conditions. The adsorption step can be carried out by mixing a particulate adsorbent in the halogen-treated crude and then removing it by centrifugation, desalting, filtration, hydrocyclone or by settling.