A method for preparing hydrocarbons includes subjecting a renewable feedstock comprising lipophilic phosphorus compounds to a hydrotreatment process to form hydrocarbons from the renewable feedstock. In some embodiments, the content of the lipophilic phosphorus compounds in the renewable feedstock can be in a range of between 2 parts per million by weight (wppm) and 0.1 wppm so that deactivation of a catalyst used in the hydrotreatment process is reduced or avoided. In some embodiments, a feedstock can be determined to include an amount of difficult to remove phosphorus and the result thereof can be used for selecting a suitable pretreatment to which the feedstock can then be subjected. The pretreated renewable feedstock can then be hydrotreated catalytically.

A method for preparing hydrocarbons includes subjecting a renewable feedstock comprising lipophilic phosphorus compounds to a hydrotreatment process to form hydrocarbons from the renewable feedstock. In some embodiments, the content of the lipophilic phosphorus compounds in the renewable feedstock can be in a range of between 2 parts per million by weight (wppm) and 0.1 wppm so that deactivation of a catalyst used in the hydrotreatment process is reduced or avoided. In some embodiments, a feedstock can be determined to include an amount of difficult to remove phosphorus and the result thereof can be used for selecting a suitable pretreatment to which the feedstock can then be subjected. The pretreated renewable feedstock can then be hydrotreated catalytically.

The present invention deals with activation and start-up procedures of catalysts for the deep HDS of middle distillates for producing ultra low sulfur diesel (ULSD), consisting of two in situ activation stages: at stage 1, TGA is applied, and at stage 2, DMDS is used; kerosene is the transport means at these stages, which are carried out under given temperature and pressure conditions, and feedstock and hydrogen flows at established times. After the activation of the catalyst in situ, the stabilization stage takes place under selected temperature and pressure conditions, feedstock and hydrogen flow at established times, with which the stabilization of the highly dispersed metallic sulfides is achieved and, in this way, the activity of the catalysts removing contaminants for the production of ULSD is increased.

The present invention deals with activation and start-up procedures of catalysts for the deep HDS of middle distillates for producing ultra low sulfur diesel (ULSD), consisting of two in situ activation stages: at stage 1, TGA is applied, and at stage 2, DMDS is used; kerosene is the transport means at these stages, which are carried out under given temperature and pressure conditions, and feedstock and hydrogen flows at established times. After the activation of the catalyst in situ, the stabilization stage takes place under selected temperature and pressure conditions, feedstock and hydrogen flow at established times, with which the stabilization of the highly dispersed metallic sulfides is achieved and, in this way, the activity of the catalysts removing contaminants for the production of ULSD is increased.

A multi-stage process for transforming a high sulfur ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a core desulfurizing process that produces a Product Heavy Marine Fuel Oil that can be used as a feedstock for subsequent refinery process such as anode grade coking, needle coking and fluid catalytic cracking. The Product Heavy Marine Fuel Oil exhibits multiple properties desirable as a feedstock for those processes including a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process is also disclosed.

A multi-stage process for transforming a high sulfur ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a core desulfurizing process that produces a Product Heavy Marine Fuel Oil that can be used as a feedstock for subsequent refinery process such as anode grade coking, needle coking and fluid catalytic cracking. The Product Heavy Marine Fuel Oil exhibits multiple properties desirable as a feedstock for those processes including a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process is also disclosed.

The invention relates to a process for purifying hydrocarbon mixtures, in which a contaminated hydrocarbon mixture comprising olefins having three to eight carbon atoms is at least partly freed of sulphur-containing contaminants by contacting it with a solid sorbent, the hydrocarbon mixture being exclusively in the liquid state during the contact with the sorbent. The problem that it addressed was that of virtually completely removing sulphur compounds present in the mixture without forming new sulphur compounds again at the same time. At the same time, 1-butene present therein was not to be lost in the purification of the mixture. Finally, the sorbent used was to have a high sorption capacity, be very substantially free of carcinogenic constituents and be readily available. This problem is solved by using a sorbent based on copper oxide, zinc oxide and aluminium oxide in a particular composition, and by conducting the purification in the presence of a small amount of hydrogen.

The invention relates to a process for purifying hydrocarbon mixtures, in which a contaminated hydrocarbon mixture comprising olefins having three to eight carbon atoms is at least partly freed of sulphur-containing contaminants by contacting it with a solid sorbent, the hydrocarbon mixture being exclusively in the liquid state during the contact with the sorbent. The problem that it addressed was that of virtually completely removing sulphur compounds present in the mixture without forming new sulphur compounds again at the same time. At the same time, 1-butene present therein was not to be lost in the purification of the mixture. Finally, the sorbent used was to have a high sorption capacity, be very substantially free of carcinogenic constituents and be readily available. This problem is solved by using a sorbent based on copper oxide, zinc oxide and aluminium oxide in a particular composition, and by conducting the purification in the presence of a small amount of hydrogen.

A multi-stage process for reducing the environmental contaminants in a ISO8217 compliant Feedstock Heavy Marine Fuel Oil involving a core desulfurizing process and an Oxidative desulfurizing process as either a pre-treating step or post-treating step to the core process. The Product Heavy Marine Fuel Oil is compliant with ISO 8217A for residual marine fuel oils and has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05% wt. to 0.5% wt. A process plant for conducting the process is also disclosed.

The present invention relates to a device and a process for hydroconversion or hydrotreatment of a hydrocarbon feedstock, comprising in particular at least one coil-wound heat exchanger (S-1), said coil-wound exchanger being a single-pass heat exchanger formed by a vertical chamber in which one or more bundles of tubes are helically wound around a central core, as numerous superposed layers, for: heating and directly distributing a hydrocarbon feedstock/hydrogen stream mixture to a hydrotreatment or hydroconversion reaction section (R-1), and cooling the reaction effluent from the hydrotreatment or hydroconversion reaction section (R-1). The present invention also relates to a use of a coil-wound heat exchanger (S-1) in a process for hydroconversion or hydrotreatment of a hydrocarbon feedstock.