Organosilica materials, which are a polymer of at least one independent monomer of Formula [Z.sup.1OZ.sup.2OSiCH.sub.2].sub.3 (I), wherein each Z.sup.1 and Z.sup.2 independently represent a hydrogen atom, a C.sub.1-C.sub.4 alkyl group or a bond to a silicon atom of another monomer and at least one other trivalent metal oxide monomer are provided herein. Methods of preparing and processes of using the organosilica materials, e.g., for catalysis etc., are also provided herein.

This present invention relates to the preparation of hydrocarbon-soluble molybdenum catalyst precursors by reacting molybdenum compounds with carboxylic acids. During the reaction, vacuum was applied to accelerate removal of the water produced and to improve the conversion of reactants when reaction was carried out at low temperatures, in the range of 100-200 C. A high controlled heating temperature was employed to increase the conversion of the reactants. Vacuum was also used after the reaction process to accelerate the removal of non-reacted carboxylic acid so as to increase the concentration of produced catalyst precursors. The catalyst precursors can generate, in situ, a hydroprocessing molybdenum sulphide catalyst during heavy oil or residue upgrading.

This present invention relates to the preparation of hydrocarbon-soluble molybdenum catalyst precursors by reacting molybdenum compounds with carboxylic acids. During the reaction, vacuum was applied to accelerate removal of the water produced and to improve the conversion of reactants when reaction was carried out at low temperatures, in the range of 100-200 C. A high controlled heating temperature was employed to increase the conversion of the reactants. Vacuum was also used after the reaction process to accelerate the removal of non-reacted carboxylic acid so as to increase the concentration of produced catalyst precursors. The catalyst precursors can generate, in situ, a hydroprocessing molybdenum sulphide catalyst during heavy oil or residue upgrading.

In a process for hydrotreatment of a gas stream containing both olefins and diolefins as well as organic sulfur compounds, the gas stream is introduced into a pre-treatment reactor, where diolefins are reacted with hydrogen in the presence of a supported Mo-catalyst not containing Co or Ni, whereby the diolefins are substantially converted to olefins. Then the gas stream is introduced into a hydrotreater reactor having a higher inlet temperature than the pre-treatment reactor, in which the gas stream is reacted with hydrogen in the presence of a hydrotreating catalyst under hydrodesulfurisation process conditions, whereby the olefins are substantially converted to paraffins and the organic sulfur compounds are converted to H.sub.2S, which is removed by subjecting the hydrotreated gas to a chemisorption or physisorption treatment.

A method for selective hydrogenation of a C2 steam cracking fraction comprising acetylene, in the presence of a catalyst comprising an active phase based on at least one group VIII metal and a support provided in the form of a ceramic or metal monolith, characterized in that said support comprises a number of channels per unit length, CPSI, of between 300 and 1200, and in that the active phase is provided in the form of a layer on the walls of said support, the thickness of said layer of active phase being between 30 m and 150 m.

This invention relates in certain aspects to a process for removing oxygenates from a stream, preferably a hydrocarbon stream comprising contacting an organosilica material with the hydrocarbon steam, where the organosilica material is a polymer of at least one monomer of Formula [Z.sup.1OZ.sup.2SiCH.sub.2].sub.3, wherein Z.sup.1 represents a hydrogen atom, a C.sub.1-C.sub.4 alkyl group, or a bond to a silicon atom of another monomer and Z.sup.2 represents a hydroxyl group, a C.sub.1-C.sub.4 alkoxy group, a C.sub.1-C.sub.6 alkyl group or an oxygen atom bonded to a silicon atom of another monomer.

A catalyst system comprising a combination of: 1) an activator; 2) one or more metallocene catalyst compounds; 3) a support comprising an organosilica material, which may be a mesoporous organosilica material. The organosilica material may be a polymer of at least one monomer of Formula [Z.sup.1OZ.sup.2SiCH.sub.2].sub.3 (I), where Z.sup.1 represents a hydrogen atom, a C.sub.1-C.sub.4 alkyl group, or a bond to a silicon atom of another monomer and Z.sup.2 represents a hydroxyl group, a C.sub.1-C.sub.4 alkoxy group, a C.sub.1-C.sub.6 alkyl group, or an oxygen atom bonded to a silicon atom of another monomer. This invention further relates to processes to polymerize olefins comprising contacting one or more olefins with the above catalyst system.

Methods are provided for modifying hydrogenation catalysts having silica supports (or other non-alumina supports) with additional alumina, and using such catalysts to achieve unexpectedly superior hydrogenation of feedstocks. The modified hydrogenation catalysts can have a relatively low cracking activity while providing an increased activity for hydrogenation.

Methods are provided for modifying hydrogenation catalysts having silica supports (or other non-alumina supports) with additional alumina, and using such catalysts to achieve unexpectedly superior hydrogenation of feedstocks. The modified hydrogenation catalysts can have a relatively low cracking activity while providing an increased activity for hydrogenation.

A new crystalline aluminosilicate zeolite comprising a MTT framework has been synthesized that has been designated UZM-53. This zeolite is represented by the empirical formula:
M.sup.+.sub.mR.sub.rAl.sub.1-xE.sub.xSi.sub.yO.sub.z
where M represents sodium, potassium or a combination of sodium and potassium cations, R is the organic structure directing agent or agents derived from reactants R1 and R2 where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-53 have utility in various hydrocarbon conversion reactions.