The invention is an integrated process for treating residual oil of a hydrocarbon feedstock. The oil is first subjected to delayed coking and then oxidative desulfurization. Additional, optional steps including hydrodesulfurization, and hydrocracking, may also be incorporated in to the integrated process.

The hydroprocessing reactor internals (HRI) have reduced height compared to standard HRI designs. In this design, HRI height reduction is achieved by placing a mixing chamber above the collection tray. A ring quench distributor is located around the fluid collection tray between the mixing chamber and reactor shell to eliminate the vertical space occupied by the distributor. The hydroprocessing reactor quench zone internals comprise a collection tray, a mixing chamber, a ring distributor, a rough liquid distribution tray, and a vapor-liquid distribution tray. Fluid mixing occurs in the mixing chamber and above the rough liquid distribution tray.

The hydroprocessing reactor internals (HRI) have reduced height compared to standard HRI designs. In this design, HRI height reduction is achieved by placing a mixing chamber above the collection tray. A ring quench distributor is located around the fluid collection tray between the mixing chamber and reactor shell to eliminate the vertical space occupied by the distributor. The hydroprocessing reactor quench zone internals comprise a collection tray, a mixing chamber, a ring distributor, a rough liquid distribution tray, and a vapor-liquid distribution tray. Fluid mixing occurs in the mixing chamber and above the rough liquid distribution tray.

Processes and catalyst systems are disclosed for performing Fischer-Tropsch (FT) synthesis to produce C.sub.4.sup.+ hydrocarbons, such as gasoline boiling-range hydrocarbons and/or diesel boiling-range hydrocarbons. Advantageously, catalyst systems described herein have additional activity (beyond FT activity) for in situ hydroisomerization and/or hydrocracking of wax that is generated according to the distribution of hydrocarbons obtained from the FT synthesis reaction. This not only improves the yield of hydrocarbons (e.g., C.sub.4-19 hydrocarbons) that are useful for transportation fuels, but also allows for alternative reactor types, such as a fluidized bed reactor.

Device for distributing a light fluid phase (2) in a heavy phase (4) in the fluidized state in a reaction chamber (5), comprising: a pipe (1) for transporting the light fluid phase; first and second windows (7, 8) created in the pipe, the second windows opening into the reaction chamber; and branches (6) extending each first window and splitting into: a central passage opening into the reaction chamber via an intermediate window (9) created in the upper wall of the branch (6); and at least two distinct lateral branches forming two lateral passages (10) opening into the reaction chamber via end-of-branch windows (11).

Device for distributing a light fluid phase (2) in a heavy phase (4) in the fluidized state in a reaction chamber (5), comprising: a pipe (1) for transporting the light fluid phase; first and second windows (7, 8) created in the pipe, the second windows opening into the reaction chamber; and branches (6) extending each first window and splitting into: a central passage opening into the reaction chamber via an intermediate window (9) created in the upper wall of the branch (6); and at least two distinct lateral branches forming two lateral passages (10) opening into the reaction chamber via end-of-branch windows (11).

Device for distributing a light fluid phase (2) in a heavy phase (4) in the fluidized state in a reaction chamber (5), comprising: a pipe (1) for transporting the light fluid phase; first and second windows (7, 8) created in the pipe, the second windows opening into the reaction chamber; and branches (6) extending each first window and splitting into: a central passage opening into the reaction chamber via an intermediate window (9) created in the upper wall of the branch (6); and at least two distinct lateral branches forming two lateral passages (10) opening into the reaction chamber via end-of-branch windows (11).

Device for distributing a light fluid phase (2) in a heavy phase (4) in the fluidized state in a reaction chamber (5), comprising: a pipe (1) for transporting the light fluid phase; first and second windows (7, 8) created in the pipe, the second windows opening into the reaction chamber; and branches (6) extending each first window and splitting into: a central passage opening into the reaction chamber via an intermediate window (9) created in the upper wall of the branch (6); and at least two distinct lateral branches forming two lateral passages (10) opening into the reaction chamber via end-of-branch windows (11).

Disclosed herein is a phosphorus modified UZM-35 zeolite, methods of its preparation, and methods of its use in hydrocarbon conversion processes, e.g., as part of a catalyst component and/or as part of a catalyst composition. Catalyst components with phosphorus modified UZM-35, their methods of preparation, and their methods of use suitable for petroleum refining applications (e.g., hydrocarbon conversion processes such as fluid catalytic cracking and hydrocracking) are described herein. Also disclosed herein are catalyst compositions, which include phosphorus modified UZM-35 and catalyst components thereof along with at least one additional catalyst component. Methods of preparing and methods of using such catalyst compositions are also encompassed by the instant disclosure.

Disclosed herein is a phosphorus modified UZM-35 zeolite, methods of its preparation, and methods of its use in hydrocarbon conversion processes, e.g., as part of a catalyst component and/or as part of a catalyst composition. Catalyst components with phosphorus modified UZM-35, their methods of preparation, and their methods of use suitable for petroleum refining applications (e.g., hydrocarbon conversion processes such as fluid catalytic cracking and hydrocracking) are described herein. Also disclosed herein are catalyst compositions, which include phosphorus modified UZM-35 and catalyst components thereof along with at least one additional catalyst component. Methods of preparing and methods of using such catalyst compositions are also encompassed by the instant disclosure.