An integrated hydrotreating and steam pyrolysis process for the direct processing of a crude oil to produce olefinic and aromatic petrochemicals by separating the crude oil into light components and heavy components.

An integrated hydrotreating and steam pyrolysis process for the direct processing of a crude oil to produce olefinic and aromatic petrochemicals by separating the crude oil into light components and heavy components.

A process for the refining of crude oil with at least one atmospheric distillation unit for separating the various fractions, a sub-atmospheric distillation unit, a conversion unit of the heavy fractions obtained, a unit for enhancing the quality of some of the fractions obtained by actions on the chemical composition of their constituents and a unit for the removal of undesired components, where the sub-atmospheric distillation residue is sent to one of the conversion units, the conversion unit includes at least one hydroconversion reactor in slurry phase, into which hydrogen or a mixture of hydrogen and H.sub.2S, is fed, in the presence of a suitable dispersed hydrogenation catalyst with dimensions ranging from 1 nanometer to 30 microns.

A process for the refining of crude oil with at least one atmospheric distillation unit for separating the various fractions, a sub-atmospheric distillation unit, a conversion unit of the heavy fractions obtained, a unit for enhancing the quality of some of the fractions obtained by actions on the chemical composition of their constituents and a unit for the removal of undesired components, where the sub-atmospheric distillation residue is sent to one of the conversion units, the conversion unit includes at least one hydroconversion reactor in slurry phase, into which hydrogen or a mixture of hydrogen and H.sub.2S, is fed, in the presence of a suitable dispersed hydrogenation catalyst with dimensions ranging from 1 nanometer to 30 microns.

The specification discloses a highly macroporous catalyst for hydroprocessing and hydroconversion of heavy hydrocarbon feedstocks. The high macroporosity catalyst incudes an inorganic oxide, molybdenum, and nickel components. It has a pore structure such that at least 18% of its total pore volume is in pores of a diameter greater than 5,000 angstroms and at least 25% of its total pore volume is in pores of a diameter greater than 1,000 angstroms. Preferably, the pore structure is bimodal. The catalyst is made by co-mulling the catalytic components with a high molecular weight polyacrylamide followed by forming the co-mulled mixture into a particle or an extrudate. The particle or extrudate is dried and calcined under controlled calcination temperature conditions to yield a calcined particle or extrudate of the high macroporosity catalyst composition.

A gas-liquid separator, adapted for separating liquid and gas in an ebullated bed reactor under operating conditions, is disclosed. The device may be used in the petroleum and chemical processing industries in catalytic reactions of hydrocarbonaceous feedstocks in the presence of hydrogen, at an elevated temperature and pressure, to separate gas and liquid from gas and liquid mixtures within the reactor. The device is generally vertically oriented and may be installed in the flow through pan of an ebullated bed reactor. The device comprises a transfer conduit for transferring a gas-liquid mixture stream from a lower section of an ebullated bed reactor to an upper section of the reactor, a vortex separation section having gas-rich and liquid-rich stream outlets, and a gas-rich stream outlet conduit located on top of and adjacent to the vortex separation section. The transfer conduit includes internal means to produce a spiral flow in the gas-liquid mixture, such as a helical or spiral insert. The vortex separation section is located at the top of the transfer conduit and includes separation means to separate the gas-liquid mixture stream into a liquid-rich stream and a gas-rich stream. A separator conduit extending from the top of the vortex separation section to the transfer conduit upper opening, aligned with and having substantially the same cross-sectional dimensions as the gas-rich stream outlet, may be used as the separation means. Among the benefits provided are improved efficiency of gas and liquid separation and reduced gas holdup within the reactor.

A process is provided to partially upgrade heavy oil using two or more reaction zones connected in series, each reaction zone being a continuous stirred tank maintained at hydrocracking conditions. The heavy oil feedstock and a solid particulate catalyst are stirred to form pumpable slurry which is heated to a target hydrocracking temperature and then continuously fed to the first reaction zone. Hydrogen is continuously introduced to the reaction zone to achieve hydrocracking and to produce a volatile vapor stream carried upwardly by the hydrogen to produce an overhead vapor stream. The hydrocracked heavy oil slurry from one reaction zone is fed to a next reaction zone also maintained under hydrocracking conditions with a continuous hydrogen feed to produce a volatile vapor stream. The overhead vapor stream from each reactor zone is continuously removed, and the hydrocracked heavy oil slurry from the last of the reaction zones is removed.

A process is provided to partially upgrade heavy oil using two or more reaction zones connected in series, each reaction zone being a continuous stirred tank maintained at hydrocracking conditions. The heavy oil feedstock and a solid particulate catalyst are stirred to form pumpable slurry which is heated to a target hydrocracking temperature and then continuously fed to the first reaction zone. Hydrogen is continuously introduced to the reaction zone to achieve hydrocracking and to produce a volatile vapor stream carried upwardly by the hydrogen to produce an overhead vapor stream. The hydrocracked heavy oil slurry from one reaction zone is fed to a next reaction zone also maintained under hydrocracking conditions with a continuous hydrogen feed to produce a volatile vapor stream. The overhead vapor stream from each reactor zone is continuously removed, and the hydrocracked heavy oil slurry from the last of the reaction zones is removed.

Biomass (e.g., plant biomass, animal biomass, and municipal waste biomass) is processed to produce useful products, such as fuels. For example, systems are described that can use feedstock materials, such as cellulosic and/or lignocellulosic materials, to produce ethanol and/or butanol, e.g., by fermentation.

Biomass (e.g., plant biomass, animal biomass, and municipal waste biomass) is processed to produce useful products, such as fuels. For example, systems are described that can use feedstock materials, such as cellulosic and/or lignocellulosic materials, to produce ethanol and/or butanol, e.g., by fermentation.