C10G51/023

CIRCULAR ECONOMY FOR PLASTIC WASTE TO POLYETHYLENE VIA REFINERY CRUDE UNIT
20210189248 · 2021-06-24 · ·

Provided is a continuous process for converting waste plastic into a feedstock for polyethylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene, and then passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is then separated into offgas, a pyrolysis oil comprising a naphtha/diesel/heavy fraction, and char. The pyrolysis oil is passed to a crude unit in a refinery from which a naphtha fraction (C.sub.5-C.sub.8), or a propane and butane (C.sub.3-C.sub.4) fraction, is recovered. The naphtha fraction, or propane and butane (C.sub.3-C.sub.4) fraction, is then passed to a steam cracker for ethylene production.

CIRCULAR ECONOMY FOR PLASTIC WASTE TO POLYPROPYLENE VIA REFINERY FCC AND ALKYLATION UNITS
20210189249 · 2021-06-24 · ·

Provided is a continuous process for converting waste plastic into recycle for polypropylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. Pyrolysis oil and wax, comprising the naphtha/diesel fraction and heavy fraction, is sent to a refinery FCC unit. A liquid petroleum gas C.sub.3-C.sub.5 olefin/paraffin mixture is recovered from the FCC unit and passed to a refinery alkylation unit. A propane fraction is recovered from the alkylation unit and passed to a dehydrogenation unit to produce propylene. The propylene is passed to a propylene polymerization reactor.

CIRCULAR CHEMICALS OR POLYMERS FROM PYROLYZED PLASTIC WASTE AND THE USE OF MASS BALANCE ACCOUNTING TO ALLOW FOR CREDITING THE RESULTANT PRODUCTS AS CIRCULAR

This disclosure relates to the production of chemicals and plastics using pyrolysis oil from the pyrolysis of plastic waste as a co-feedstock along with a petroleum-based, fossil fuel-based, or bio-based feedstock. In an aspect, the polymers and chemicals produced according to this disclosure can be certified under International Sustainability and Carbon Certification (ISCC) provisions as circular polymers and chemicals at any point along complex chemical reaction pathways. The use of a mass balance approach which attributes the pounds of pyrolyzed plastic products derived from pyrolysis oil to any output stream of a given unit has been developed, which permits ISCC certification agency approval.

Method for quenching pyrolysis product

A method for quenching a pyrolysis product, including: supplying a discharge stream from a liquid decomposition furnace to a first quench tower; supplying an upper discharge stream from the first quench tower to a second quench tower; supplying a discharge stream from a first gas decomposition furnace to the second quench tower; and supplying a discharge stream from a second gas decomposition furnace to the second quench tower.

Method for upgrading a hydrocarbon feed
10870803 · 2020-12-22 ·

A method for upgrading a hydrocarbon feed is disclosed. The method may be carried out in a pyrolysis furnace that may have at least two coils and at least two thermal zones. The method may include two operating or run modes that may be repeated in a cycle. In one run, upgrading may be carried out in one coil while decoking may be carried out in the other coil. After a predetermined amount of time, the streams of the two coils may be switched for a second run, such that decoking may be carried out in the coil in which upgrading was done in the first run and upgrading may be carried out in the coil in which decoking was done in the first run. The first and the second run are cyclically repeated one after the other.

Two stage thermal cracking process with multistage separation system

The present invention relates to Delayed Coking of heavy petroleum residue producing petroleum coke and lighter hydrocarbon products. The invented process utilizes a pre-cracking reactor for mild thermal cracking of the feedstock and intermediate multistage separation system before being subjected to higher severity thermal cracking in delayed coking process, resulting in reduction in overall coke yield.

Method of delayed coking of petroleum residues
10808176 · 2020-10-20 · ·

The delayed coking method includes directing a heated secondary feedstock, which contains heated primary feedstock and recirculate, from a reaction furnace to a coking chamber. Vapor-liquid coking products formed in the coking chamber are then directed to a fractionation column, which fractionates hydrocarbon gas, gasoline, light and heavy gas oils, and bottom residues. Heavy gas oil from the fractionation column is directed to a thermal cracking furnace, the products of which are cooled by cooled light gas oil and directed to an evaporator for separation. In the evaporator, gases and light boiling products are removed by evaporation and returned to the fractionation column, and the remaining distillate cracking residue is separated and used as a component of the recirculate, along with bottom residues from the fractionation column. The resulting process produces high quality and high yield needle and anode cokes.

Delayed coking process with pre-cracking reactor

The present invention relates to delayed coking of heavy petroleum residue producing petroleum coke and lighter hydrocarbon products. The invented process utilize a pre-cracking reactor and a reactor furnace for mild thermal cracking of the feedstock and an intermediate separator, before being subjected to higher severity thermal cracking treatment in a coker furnace and a coking drums, resulting in reduction in overall coke yield.

Device and method for processing hydrocarbon feedstocks

Disclosed are methods and modular devices for processing hydrocarbon feedstocks. In particular, the methods and modular devices disclosed herein provide for increasing the amounts of light fractions obtainable from a hydrocarbon feedstock.

INTEGRATED SUPERCRITICAL WATER AND STEAM CRACKING PROCESS

A method for producing a supercritical water (SCW)-treated product is provided. The method comprising the steps of introducing a crude oil stream and a water stream to a supercritical water process, wherein the crude oil stream can undergo conversion reactions to produce the supercritical water (SCW)-treated product, wherein the SCW-treated product includes an increased paraffin concentration as compared to crude oil stream. The method further includes the step of introducing the SCW-treated product to a steam cracking process, wherein the SCW-treated product can undergo conversion reactions to produce furnace effluent.