Apparatus and processes herein provide for converting hydrocarbon feeds to light olefins and other hydrocarbons. The processes and apparatus include, in some embodiments, feeding a hydrocarbon, a first catalyst and a second catalyst to a reactor, wherein the first catalyst has a smaller average particle size and is less dense than the second catalyst. A first portion of the second catalyst may be recovered as a bottoms product from the reactor, and a cracked hydrocarbon effluent, a second portion of the second catalyst, and the first catalyst may be recovered as an overhead product from the reactor. The second portion of the second catalyst may be separated from the overhead product, providing a first stream comprising the first catalyst and the hydrocarbon effluent and a second stream comprising the separated second catalyst, allowing return of the separated second catalyst in the second stream to the reactor.

Methods for making higher-octane fuel components from a feed stream of C8+ paraffins, including catalytically cracking the C8+ paraffins using a Zeolite catalyst to produce a reaction product of mid-chain paraffins and olefins and short-chain paraffins and olefins. The reaction product comprises liquid phase paraffins having an increased Octane Value over the feed stream paraffins. The reaction product further comprises a gas phase of short-chain paraffins which are separated from the liquid phase. In embodiments, the short chain olefins are hydrogenated to form mid-chain paraffins and a gas phase containing short-chain paraffins.

Methods of producing propylene and/or ethylene. The methods can include contacting a mixture of C4+ compounds with a catalyst, such as a fixed bed catalyst, that includes a phosphorus treated zeolite. The mixture of C4+ compounds can include a plurality of C4 olefins, a plurality of C5 olefins, and/or a plurality of C6+ olefins.

The present invention relates to a process for obtaining fuel from biomass which comprises the introduction of the catalyst (3) in the base of an cracking section (4), wherein said catalyst (3) at high temperature comes in contact with a gas stream of light hydrocarbons rich in hydrogen (1), wherein the catalyst (3) and hydrocarbon (1) then come in contact with a lignocellulosic liquid stream (2) in the same cracking section (4), creating the reaction mixture (5) that, soon after, comes into contact with the main stream containing the traditional fossil load of a FCC (6) in a second cracking section (7).

The present disclosure relates to a catalytic cracking process comprising the following steps: i) subjecting a heavy feedstock oil to a catalytic cracking reaction to obtain a catalytic cracking reaction product; ii) separating the catalytic cracking reaction product to obtain a catalytic cracking gasoline and a catalytic cracking light cycle oil; iii) splitting the catalytic cracking gasoline to obtain a light gasoline fraction, a medium gasoline fraction and a heavy gasoline fraction; iv) subjecting the catalytic cracking light cycle oil to hydrogenation to obtain a hydrogenated light cycle oil); v) mixing a portion of the light gasoline fraction with at least a portion of the hydrogenated light cycle oil to obtain a mixed fraction; vi) subjecting the mixed fraction to a catalytic cracking reaction; and vii) subjecting a portion of the medium gasoline fraction to a catalytic cracking reaction. The process of the present application is capable of producing more catalytic cracking gasoline, reducing the olefin content of the catalytic cracking gasoline, and increasing its octane number.

The invention relates to a process for the catalytic treatment of a hydrocarbon feedstock with continuous catalytic regeneration, in which process said feedstock is successively circulated in a plurality of reaction zones in series (R1, R2, R3, R4), the catalyst circulating as a moving bed successively in the plurality of reaction zones and flowing from the upstream end to the downstream end of each of the reaction zones and being transported by a carrier gas phase g1 from the downstream end of one reaction zone to the upstream end of the next reaction zone, characterized in that said carrier gas phase g1 has a density of greater than or equal to 1 kg/m.sup.3.

A fluid catalytic cracking apparatus and process is disclosed, providing for efficient conversion of heavy hydrocarbon feeds to light olefins, aromatics, and gasoline. A countercurrent flow reactor operating in bubbling or turbulent fluidization regimes is integrated with a fluid catalytic cracking riser reactor. A heavy hydrocarbon feed is catalytically cracked to naphtha and light olefins in the riser reactor, a co-current flow reactor. To enhance the yields and selectivity to light olefins, cracked hydrocarbon products from the riser reactor, such as C.sub.4 and naphtha range hydrocarbons, may be recycled and processed in the countercurrent flow reactor. The integration of the countercurrent flow reactor with a conventional FCC riser reactor and catalyst regeneration system may overcome heat balance issues commonly associated with two-stage cracking processes, may substantially increase the overall conversion and light olefins yield, and/or may increases the capability to process heavier feedstocks.

Methods for making higher-octane fuel components from a feed stream of C8+ paraffins, including catalytically cracking the C8+ paraffins using a Zeolite catalyst to produce a reaction product of mid-chain paraffins and olefins and short-chain paraffins and olefins. The reaction product comprises liquid phase paraffins having an increased Octane Value over the feed stream paraffins. The reaction product further comprises a gas phase of short-chain paraffins which are separated from the liquid phase. In embodiments, the short chain olefins are hydrogenated to form mid-chain paraffins and a gas phase containing short-chain paraffins.

Supercritical upgrading reactors and reactor systems for upgrading a petroleum-based compositions comprising one or more catalyst layers and, in some embodiments, one or more purging fluid inlets, where one or more catalyst layers at least partially sift and convert heavy hydrocarbon fractions to light hydrocarbon fractions to produce an upgraded supercritical reactor product. In some embodiments, upgrading reactor systems comprise one or more supercritical upgrading reactors and one or more supercritical standby reactors alternating functions such that a supercritical upgrading reactor is converted to a supercritical standby reactor and the supercritical standby reactor is converted to a supercritical upgrading reactor, where the supercritical upgrading reactor upgrades a combined feed stream while a supercritical standby reactor delivers a cleaning fluid into the supercritical standby reactor.

A method of controlling cooling in an aircraft system includes endothermically cracking a fuel to increase its cooling capacity using a catalyst that includes at least one transition metal compound of at least one of carbides, nitrides, oxynitrides, oxycarbonitrides, oxycarbides, phosphides, and combinations, and the transition metal includes at least one of zirconium, hafnium, tantalum, niobium, molybdenum, tungsten, platinum, palladium, rhodium, iridium, ruthenium, osmium, rhenium, and combinations thereof. The cracked fuel is used to cool a heat source that includes an aircraft component.