A method for removing alkali metal from a hydrocarbon feedstock comprising alkali metal, non-alkali metal and sulfur. The method includes separating out at least a portion of any alkali metal sulfide and a portion of any non-alkali metal from the hydrocarbon feedstock. Hydrogen sulfide can be added to the remaining hydrocarbon feedstock to form alkali hydrosulfide from any alkali metal remaining in the hydrocarbon feedstock. The alkali hydrosulfide is then separated from the hydrocarbon feedstock. Alkali metal may be removed from the alkali metal sulfide separated out from the hydrocarbon feedstock. Alkali hydrosulfide may be treated to form alkali metal sulfide, and alkali metal may also be removed from the formed alkali metal sulfide.

In accordance with one or more embodiments of the present disclosure, a continuous catalytic deasphalting process includes introducing a feed comprising crude oil and solvent to a first reactor to deasphalt the feed, producing polymerized asphaltene adsorbed to the catalyst and deasphalted oil; introducing solvent to a second reactor to regenerate catalyst in the second reactor while the deasphalting step is performed in the first reactor; introducing a wash solvent to the first reactor after deasphalting to remove the polymerized asphaltene, thereby regenerating the catalyst in the first reactor and producing a mixture comprising solvent and polymerized asphaltene; passing the mixture to a separator downstream of the reactor system to separate the wash solvent from the polymerized asphaltenes; and reintroducing at least a portion of the separated wash solvent to at least one of the first and second reactors.

In accordance with one or more embodiments of the present disclosure, a continuous catalytic deasphalting process includes introducing a feed comprising crude oil and solvent to a first reactor to deasphalt the feed, producing polymerized asphaltene adsorbed to the catalyst and deasphalted oil; introducing solvent to a second reactor to regenerate catalyst in the second reactor while the deasphalting step is performed in the first reactor; introducing a wash solvent to the first reactor after deasphalting to remove the polymerized asphaltene, thereby regenerating the catalyst in the first reactor and producing a mixture comprising solvent and polymerized asphaltene; passing the mixture to a separator downstream of the reactor system to separate the wash solvent from the polymerized asphaltenes; and reintroducing at least a portion of the separated wash solvent to at least one of the first and second reactors.

Kerosene boiling range or jet fuel boiling range compositions are provided that are formed from crude oils with unexpected combinations of high naphthenes to aromatics weight and/or volume ratio and a low sulfur content. The resulting kerosene boiling range fractions can have an unexpected combination of a high naphthenes to aromatics weight ratio, a low but substantial aromatics content, and a low sulfur content. Such fractions can potentially be used as fuel after a reduced or minimized amount of additional refinery processing. By reducing, minimizing, or avoiding the amount of refinery processing needed to meet fuel and/or fuel blending product specifications, the fractions derived from the high naphthenes to aromatics ratio and low sulfur crudes can provide fuels and/or fuel blending products having a reduced or minimized carbon intensity.

Kerosene boiling range or jet fuel boiling range compositions are provided that are formed from crude oils with unexpected combinations of high naphthenes to aromatics weight and/or volume ratio and a low sulfur content. The resulting kerosene boiling range fractions can have an unexpected combination of a high naphthenes to aromatics weight ratio, a low but substantial aromatics content, and a low sulfur content. Such fractions can potentially be used as fuel after a reduced or minimized amount of additional refinery processing. By reducing, minimizing, or avoiding the amount of refinery processing needed to meet fuel and/or fuel blending product specifications, the fractions derived from the high naphthenes to aromatics ratio and low sulfur crudes can provide fuels and/or fuel blending products having a reduced or minimized carbon intensity.

In accordance with one or more embodiments of the present disclosure, a continuous catalytic deasphalting process includes introducing a feed comprising crude oil and solvent to a first reactor to deasphalt the feed, producing polymerized asphaltene adsorbed to the catalyst and deasphalted oil; introducing solvent to a second reactor to regenerate catalyst in the second reactor while the deasphalting step is performed in the first reactor; introducing a wash solvent to the first reactor after deasphalting to remove the polymerized asphaltene, thereby regenerating the catalyst in the first reactor and producing a mixture comprising solvent and polymerized asphaltene; passing the mixture to a separator downstream of the reactor system to separate the wash solvent from the polymerized asphaltenes; and reintroducing at least a portion of the separated wash solvent to at least one of the first and second reactors.

In accordance with one or more embodiments of the present disclosure, a continuous catalytic deasphalting process includes introducing a feed comprising crude oil and solvent to a first reactor to deasphalt the feed, producing polymerized asphaltene adsorbed to the catalyst and deasphalted oil; introducing solvent to a second reactor to regenerate catalyst in the second reactor while the deasphalting step is performed in the first reactor; introducing a wash solvent to the first reactor after deasphalting to remove the polymerized asphaltene, thereby regenerating the catalyst in the first reactor and producing a mixture comprising solvent and polymerized asphaltene; passing the mixture to a separator downstream of the reactor system to separate the wash solvent from the polymerized asphaltenes; and reintroducing at least a portion of the separated wash solvent to at least one of the first and second reactors.

A process, a system, and an apparatus for separation of an oxygenate from a stream is provided. More specifically, a stream comprising the oxygenate is introduced to a quench tower along with a caustic outlet stream comprising a metal salt. Contact between the oxygenate and the metal salt results in conversion of a portion of the oxygenate into a derivative salt. The derivative salt and unconverted oxygenate are condensed by quenching and substantially removed from the quench tower as an oxygenate outlet stream. The gaseous components of the stream, minus a substantial portion of the oxygenate, are removed from the quench tower as a quench outlet stream.

A process, a system, and an apparatus for separation of an oxygenate from a stream is provided. More specifically, a stream comprising the oxygenate is introduced to a quench tower along with a caustic outlet stream comprising a metal salt. Contact between the oxygenate and the metal salt results in conversion of a portion of the oxygenate into a derivative salt. The derivative salt and unconverted oxygenate are condensed by quenching and substantially removed from the quench tower as an oxygenate outlet stream. The gaseous components of the stream, minus a substantial portion of the oxygenate, are removed from the quench tower as a quench outlet stream.

Treatment of a biodiesel composition to remove impurities such as glycerol from the biodiesel composition using a membrane support. The biodiesel composition flows on one side of the membrane support and an acidic washing solution flows on the opposite side of the membrane support. Glycerol and other low molecular weight impurities having an affinity towards water are transported from the biodiesel composition to the acidic washing solution through the membrane support. The membrane support may include a plurality of hydrophilic polymer hollow fibers disposed in a support module.