Patent classifications
C10G55/04
UMO-SOURCED, CLEAN, EFFICIENT, NON-CATALYTIC CRACKING AND RE-REFINING METHODS AND APPARATUS
A process for re-refining used lubricating oil (ULO), much of which is used motor oil (UMO) relies on more rapid heating, turbulent flows, higher peak temperatures, to achieve rapid thermal cracking, even including metal-bearing additives without catalysts, compared to conventional refining of crude oil and conventional recycling processing of UMO. By thermally cracking this way and scrubbing with recycled, processed liquids from the flow stream, a process readily removes metal-bearing hydrocarbons in typical lubricating oil additives. Those bonded metals consigned to heavy fraction “bottoms,” are commonly non-removable by other recycling schemes. Long chain polymers including paraffins are broken into lighter hydrocarbons with properties typical of fuels containing olefins, naphthenes, and the like. Data and analysis reveal low solids, effective metal removal, comparatively low viscosity and boiling points, and greatly reduced sulfur content in fuel and oil products resulting.
Demetallization by delayed coking and gas phase oxidative desulfurization of demetallized residual oil
The invention is an integrated process for treating residual oil of a hydrocarbon feedstock. The oil is first subjected to delayed coking and then oxidative desulfurization. Additional, optional steps including hydrodesulfurization, and hydrocracking, may also be incorporated in to the integrated process.
Demetallization by delayed coking and gas phase oxidative desulfurization of demetallized residual oil
The invention is an integrated process for treating residual oil of a hydrocarbon feedstock. The oil is first subjected to delayed coking and then oxidative desulfurization. Additional, optional steps including hydrodesulfurization, and hydrocracking, may also be incorporated in to the integrated process.
System and process for steam cracking and PFO treatment integrating selective hydrogenation, FCC and naphtha reforming
A process for treatment of PFO from a steam cracking zone includes selectively hydrogenating PFO or a portion thereof for conversion of polyaromatics compounds contained in the PFO into aromatic compounds with one benzene ring to produce a selectively hydrogenated stream. The selectively hydrogenated stream is reacted in a fluid catalytic cracking reactor for selective ring opening and dealkylation to produce fluid catalytic cracking including light cycle oil. In addition, a naphtha reformer is integrated, so that light cycle oil and a reformate stream are separated into BTX compounds. Optionally the PFO is separated into a first stream containing C9+ aromatics compounds with one benzene ring, and a second stream containing C10+ aromatic compounds, whereby the first stream containing C9+ aromatics compounds with one benzene ring is passed to the fluid catalytic cracking reactor, and the feed to the selective hydrogenation step comprises all or a portion of the second stream containing C10+ aromatic compounds.
System and process for steam cracking and PFO treatment integrating selective hydrogenation and FCC
A process for treatment of PFO from a steam cracking zone includes selectively hydrogenating PFO or a portion thereof for conversion of polyaromatics compounds contained in the PFO into aromatic compounds with one benzene ring to produce a selectively hydrogenated stream. The selectively hydrogenated stream is reacted in a fluid catalytic cracking reactor for selective ring opening and dealkylation to produce fluid catalytic cracking including light cycle oil. The light cycle oil is separated into BTX compounds. Optionally the PFO is separated into a first stream containing C9+ aromatics compounds with one benzene ring, and a second stream containing C10+ aromatic compounds, whereby the first stream containing C9+ aromatics compounds with one benzene ring is passed to the fluid catalytic cracking reactor, and the feed to the selective hydrogenation step comprises all or a portion of the second stream containing C10+ aromatic compounds.
Solvent and Temperature Assisted Dissolution of Solids from Steam Cracked Tar
Processes for preparing a low particulate liquid hydrocarbon product are provided and include blending a tar stream containing particles with a fluid and heating to a temperature of 250° C. or greater to produce a fluid-feed mixture that contains tar, the particles, and the fluid. The fluid-feed mixture contains about 20 wt % or greater of the fluid, based on a combined weight of the tar stream and the fluid. Also, about 25 wt % to about 99 wt % of the particles in the tar stream are dissolved or decomposed when producing the fluid-feed mixture.
Solvent and Temperature Assisted Dissolution of Solids from Steam Cracked Tar
Processes for preparing a low particulate liquid hydrocarbon product are provided and include blending a tar stream containing particles with a fluid and heating to a temperature of 250° C. or greater to produce a fluid-feed mixture that contains tar, the particles, and the fluid. The fluid-feed mixture contains about 20 wt % or greater of the fluid, based on a combined weight of the tar stream and the fluid. Also, about 25 wt % to about 99 wt % of the particles in the tar stream are dissolved or decomposed when producing the fluid-feed mixture.
A PROCESS OF COPROCESSING A LIGNOCELLULOSIC LIQUID STREAM AND AN INTERMEDIATE FOSSIL STREAM IN AN OIL REFINING PROCESS AND A PROCESS FOR PRODUCING FUEL FROM A DEASPHALTED OIL STREAM
The present invention describes the coprocessing of a lignocellulosic liquid stream and an intermediate fossil stream in the oil refining process comprising the steps of (a) contacting said intermediate fossil stream and said lignocellulosic liquid stream with a stream of solvent of C.sub.3-C.sub.10 hydrocarbons in an extraction section, obtaining a stream of extract with solvent and a stream of raffinate with solvent; and (b) sending said stream of extract with solvent to a separation section, obtaining a deasphalted oil stream comprising solvent-free carbon of renewable origin and a stream of recovered solvent. The present invention further relates to a process for producing fuels from the deasphalted oil stream comprising carbon of renewable origin, wherein the process comprises sending the deasphalted oil stream to a conversion section of an oil refinery. The conversion section is selected from catalytic hydrocracking unit, thermal cracking, fluidized-bed catalytic cracking, visbreaking, delayed coking and catalytic reforming.
A PROCESS OF COPROCESSING A LIGNOCELLULOSIC LIQUID STREAM AND AN INTERMEDIATE FOSSIL STREAM IN AN OIL REFINING PROCESS AND A PROCESS FOR PRODUCING FUEL FROM A DEASPHALTED OIL STREAM
The present invention describes the coprocessing of a lignocellulosic liquid stream and an intermediate fossil stream in the oil refining process comprising the steps of (a) contacting said intermediate fossil stream and said lignocellulosic liquid stream with a stream of solvent of C.sub.3-C.sub.10 hydrocarbons in an extraction section, obtaining a stream of extract with solvent and a stream of raffinate with solvent; and (b) sending said stream of extract with solvent to a separation section, obtaining a deasphalted oil stream comprising solvent-free carbon of renewable origin and a stream of recovered solvent. The present invention further relates to a process for producing fuels from the deasphalted oil stream comprising carbon of renewable origin, wherein the process comprises sending the deasphalted oil stream to a conversion section of an oil refinery. The conversion section is selected from catalytic hydrocracking unit, thermal cracking, fluidized-bed catalytic cracking, visbreaking, delayed coking and catalytic reforming.
METHOD AND SYSTEM FOR SEPARATING LIGHT HYDROCARBONS
A method and system for separating light hydrocarbons are disclosed, wherein the method comprises compression, cooling, absorption, desorption, rectification, cracking, and recycling cracked gas to the compression step.