C10G65/12

METHOD FOR THE PRODUCTION OF SYNTHETIC JET FUEL

A method to produce a fuel product such as jet fuel, diesel or single battlefield fuel from a Fischer Tropsch syncrude comprising the steps of: 1) Separating the HFTL product from the reactor effluent gasses at reactor temperature and partially cooling the reactor effluent gas before transferring it to the enhanced hot separator; 2) enhancing the hot separator downstream of the Fischer Tropsch reactor with trays or packing and also adding reflux of the LFTL product, to improve separation efficiency and substantially reduce the C16+ portion of the hydrocarbons in the LFTL product; 3) combining the HFTL and MFTL product to from a combined HFTL product and further processing the combined HFTL in a hydroprocessing reactor that has a stacked bed with a layer of hydrocracking catalyst to crack the waxy C20+ hydrocarbons and a layer of hydroisomerization catalyst to isomerize the light fraction to increase the iso to n-paraffin ratio of the hydroprocessed product; 4) the LFTL product that is not recycled to the hot separator as reflux, bypasses the hydroprocessing reactor and is blended with the hydroprocessed product before distillation; and 5) the combined raw LFTL product and the hydroprocessed product is distilled to make naphtha, a fuel product, and a baseoil product. The method may be modified to make a single fuel product, preferably a jet fuel product.

Manufacture of a synthetic fuel

The present invention provides a process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, the process comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; sequentially removing ammoniacal, sulphurous and carbon dioxide impurities from the raw synthesis gas to form desulphurised gas and recovering carbon dioxide in substantially pure form; converting at least a portion of the desulphurised synthesis gas to a useful product. Despite having selected a more energy intensive sub-process i.e. physical absorption for removal of acid gas impurities, the overall power requirement of the facility is lower on account of lower steam requirements and thereby leading to a decrease in the carbon intensity score for the facility.

Manufacture of a synthetic fuel

The present invention provides a process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, the process comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; sequentially removing ammoniacal, sulphurous and carbon dioxide impurities from the raw synthesis gas to form desulphurised gas and recovering carbon dioxide in substantially pure form; converting at least a portion of the desulphurised synthesis gas to a useful product. Despite having selected a more energy intensive sub-process i.e. physical absorption for removal of acid gas impurities, the overall power requirement of the facility is lower on account of lower steam requirements and thereby leading to a decrease in the carbon intensity score for the facility.

Method To Prepare An Aviation Fuel Component

The present disclosure relates to methods for preparing aviation fuel component from a feedstock containing fossil hydrotreating feed and a second feed containing esters of fatty acids and rosins, free fatty acids and resin acids. The method includes subjecting the feedstock to hydrotreatment reaction conditions to produce a hydrotreated stream, separating the hydrotreated stream to three fractions from which at least part the highest boiling fraction is subjected to hydrocracking reaction to produce a hydrocracked stream. At least part of the hydrocracked stream is admixed with at least part of the hydrotreated stream, and their admixture is processed further until desired conversion of the feedstock to the aviation fuel component is obtained.

DEEP HYDROCONVERSION PROCESS USING AN EXTRACTION OF AROMATICS AND RESINS, WITH UPGRADING OF THE HYDROCONVERSION EXTRACT AND RAFFINATE IN DOWNSTREAM UNITS
20170369796 · 2017-12-28 · ·

Process for deep conversion of heavy hydrocarbon feed, which includes: a) ebullated bed hydroconverting the feed in at least one three-phase reactor containing at least one supported hydroconversion catalyst; b) atmospheric fractionating effluent from a) producing gasoline fraction, gas oil cut, and atmospheric residue; c) vacuum fractionation of at least a portion of the atmospheric residue to obtain a vacuum gas oil fraction and an unconverted vacuum residue fraction; d) deasphalting at least a portion of the unconverted vacuum residue fraction with an organic solvent obtaining a hydrocarbon cut depleted in asphaltenes, termed deasphalted oil, and residual asphalt; and e) liquid/liquid extraction on the hydrocarbon cut depleted in asphaltenes extracting aromatics by a polar solvent producing an extract enriched in aromatics and resins and a raffinate depleted in aromatics and resins, at least a portion of the extract sent to the inlet of the hydroconversion as an aromatic diluent.

DEEP HYDROCONVERSION PROCESS USING AN EXTRACTION OF AROMATICS AND RESINS, WITH UPGRADING OF THE HYDROCONVERSION EXTRACT AND RAFFINATE IN DOWNSTREAM UNITS
20170369796 · 2017-12-28 · ·

Process for deep conversion of heavy hydrocarbon feed, which includes: a) ebullated bed hydroconverting the feed in at least one three-phase reactor containing at least one supported hydroconversion catalyst; b) atmospheric fractionating effluent from a) producing gasoline fraction, gas oil cut, and atmospheric residue; c) vacuum fractionation of at least a portion of the atmospheric residue to obtain a vacuum gas oil fraction and an unconverted vacuum residue fraction; d) deasphalting at least a portion of the unconverted vacuum residue fraction with an organic solvent obtaining a hydrocarbon cut depleted in asphaltenes, termed deasphalted oil, and residual asphalt; and e) liquid/liquid extraction on the hydrocarbon cut depleted in asphaltenes extracting aromatics by a polar solvent producing an extract enriched in aromatics and resins and a raffinate depleted in aromatics and resins, at least a portion of the extract sent to the inlet of the hydroconversion as an aromatic diluent.

METHOD FOR LIGHTENING HEAVY OIL BY USING COKE PRODUCTION BYPRODUCT

A method for upgrading heavy oil by using a coke production byproduct comprises the steps of: producing a mixed solution by mixing a coke production byproduct and heavy oil; and hydrogenating the mixed solution under a hydrogenation catalyst, wherein the present disclosure is economical and effective by being able to reduce the amount of coke formation and significantly reduce the partial pressure of added hydrogen by using the coke production byproduct as a hydrogen donor.

APPARATUS AND METHOD FOR PRODUCING DIESEL FUEL AND JET FUEL USING FISCHER-TROPSCH SYNTHETIC OIL
20170362518 · 2017-12-21 ·

An apparatus for producing diesel fuel and jet fuel using Fischer-Tropsch synthetic oil, the apparatus including a hydrofining reactor, a hot separator, a first rectifying column, a hydrocracking reactor, a hydroisomerization reactor, a second rectifying column, a first mixing chamber and a second mixing chamber. The hydrofining reactor includes a raw material inlet and a hydrofining product outlet. The hot separator includes a separated oil outlet and a hydrofining product inlet which is connected to the hydrofining product outlet. The first rectifying column includes a tail oil fraction outlet, a diesel fraction outlet and a separated oil inlet which is connected to the separated oil outlet. The first mixing chamber includes a circulating hydrogen inlet, a first mixture outlet and a tail oil fraction inlet which is connected to the tail oil fraction outlet.

Method for the production of synthetic jet fuel

A method to produce a fuel product such as jet fuel, diesel or single battlefield fuel from a Fischer Tropsch syncrude comprising the steps of: 1) Separating the HFTL product from the reactor effluent gasses at reactor temperature and partially cooling the reactor effluent gas before transferring it to the enhanced hot separator; 2) enhancing the hot separator downstream of the Fischer Tropsch reactor with trays or packing and also adding reflux of the LFTL product, to improve separation efficiency and substantially reduce the C16+ portion of the hydrocarbons in the LFTL product; 3) combining the HFTL and MFTL product to from a combined HFTL product and further processing the combined HFTL in a hydroprocessing reactor that has a stacked bed with a layer of hydrocracking catalyst to crack the waxy C20+ hydrocarbons and a layer of hydroisomerization catalyst to isomerize the light fraction to increase the iso to n-paraffin ratio of the hydroprocessed product; 4) the LFTL product that is not recycled to the hot separator as reflux, bypasses the hydroprocessing reactor and is blended with the hydroprocessed product before distillation; and 5) the combined raw LFTL product and the hydroprocessed product is distilled to make naphtha, a fuel product, and a baseoil product. The method may be modified to make a single fuel product, preferably a jet fuel product.

PROCESS AND APPARATUS FOR HYDROCRACKING A HYDROCARBON STREAM IN TWO STAGES WITH AROMATIC SATURATION
20170362516 · 2017-12-21 ·

A process and apparatus for two stage hydrocracking saturates aromatics from the first stage hydrocracking unit to prevent production of HPNA's. The saturated HPNA's can be hydrocracked in the second stage to minimize or eliminate purged unconverted oil to approach or obtain maximum conversion. In an aspect, the second stage hydrocracking reactor and hydrotreating reactor may be located in the same vessel.