C10G67/12

Integrated process for the production of isononanol and paraffins for producing stable / lubricating gasoline and diesel blending components

In accordance with one or more embodiments of the present disclosure, a method for producing epoxide gasoline blending components includes cracking, in a steam cracker, a hydrocarbon feed to form a first ethylene stream, a first propylene stream, and a C.sub.4 stream comprising isobutene and butadiene; reacting, in a methyl tertiary butyl ether (MTBE) unit, the C.sub.4 stream with a methanol stream to form MTBE and a butadiene-rich C.sub.4 stream; selectively hydrogenating, in a butadiene unit, the butadiene-rich C.sub.4 stream to form a butene-rich C.sub.4 stream including butene-1, cis-butene-2, and trans-butene-2; producing, in an isononanol unit, isononanol and an olefin-rich stream from the butene-rich C.sub.4 stream; and hydrogenating the olefin-rich stream by combining the olefin-rich stream with a hydrogen stream and a catalyst composition to produce the paraffins.

HYDROCRACKING PROCESS AND SYSTEM INCLUDING SEPARATION OF HEAVY POLY NUCLEAR AROMATICS FROM RECYCLE BY OXIDATION
20210130702 · 2021-05-06 ·

Hydrocracked bottoms fractions are treated to separate HPNA compounds and/or HPNA precursor compounds and produce a reduced-HPNA hydrocracked bottoms fraction effective for recycle, in a configuration of a single-stage hydrocracking reactor, series-flow once through hydrocracking operation, or two-stage hydrocracking operation. A process for separation of HPNA and/or HPNA precursor compounds from a hydrocracked bottoms fraction of a hydroprocessing reaction effluent comprises contacting the hydrocracked bottoms fraction with an effective quantity of a oxidizing agent to produce corresponding oxidized HPNA compounds and/or oxidized HPNA precursor compounds, and to form an oxidized hydrocracked bottoms fraction. The oxidized hydrocracked bottoms fraction is separated into an HPNA-reduced hydrocracked bottoms portion and an oxidized HPNA portion. All or a portion of the HPNA-reduced hydrocracked bottoms portion is recycled within the hydrocracking operation.

HYDROCRACKING PROCESS AND SYSTEM INCLUDING SEPARATION OF HEAVY POLY NUCLEAR AROMATICS FROM RECYCLE BY OXIDATION
20210130702 · 2021-05-06 ·

Hydrocracked bottoms fractions are treated to separate HPNA compounds and/or HPNA precursor compounds and produce a reduced-HPNA hydrocracked bottoms fraction effective for recycle, in a configuration of a single-stage hydrocracking reactor, series-flow once through hydrocracking operation, or two-stage hydrocracking operation. A process for separation of HPNA and/or HPNA precursor compounds from a hydrocracked bottoms fraction of a hydroprocessing reaction effluent comprises contacting the hydrocracked bottoms fraction with an effective quantity of a oxidizing agent to produce corresponding oxidized HPNA compounds and/or oxidized HPNA precursor compounds, and to form an oxidized hydrocracked bottoms fraction. The oxidized hydrocracked bottoms fraction is separated into an HPNA-reduced hydrocracked bottoms portion and an oxidized HPNA portion. All or a portion of the HPNA-reduced hydrocracked bottoms portion is recycled within the hydrocracking operation.

Integrated process for solvent deasphalting and gas phase oxidative desulfurization of residual oil
10894923 · 2021-01-19 · ·

The invention is an integrated process for treating residual oil of a hydrocarbon feedstock. The oil is first subjected to solvent deasphalting then gas phase oxidative desulfurization. Additional, optional steps including hydrodesulfurization, and hydrocracking, may also be incorporated into the integrated process.

Integrated process for solvent deasphalting and gas phase oxidative desulfurization of residual oil
10894923 · 2021-01-19 · ·

The invention is an integrated process for treating residual oil of a hydrocarbon feedstock. The oil is first subjected to solvent deasphalting then gas phase oxidative desulfurization. Additional, optional steps including hydrodesulfurization, and hydrocracking, may also be incorporated into the integrated process.

Method and device for lightening heavy oil by utilizing a suspension-bed hydrogenation process

A method and device for lightening heavy oil by utilizing a suspension-bed hydrogenation process are provided. In the process, a part of a raw oil is mixed with a suspension-bed hydrocracking catalyst to form a first mixture, then the first mixture is subjected to first shear and second shear in sequence so as to realize high dispersion and mixing of the catalyst and the raw oil; through pretreatment of the raw oil, the device can prevent the raw oil from coking in the hydrogenation process; through the adoption of a suspension-bed reactor with a liquid phase self-circulation function or a cold-wall function; and light and heavy components are separated from the suspension-bed hydrogenated product in advance and only medium component is subjected to fixed-bed hydrogenation, thereby reducing the load of the fixed-bed hydrogenation, prolonging the service life of the fixed-bed catalyst, improving the yield and quality of gasoline and diesel, and being beneficial for energy conservation and emission reduction of the whole system.

ULTRASONIC OXIDATIVE DESULFURIZATION OF HEAVY FUEL OILS

The invention relates to systems and methods for ultrasonic oxidative desulfurization of heavy fuel oils. In various embodiments, the methods include combinations of ultrasonic sulfone decomposition processes and/or catalytic decomposition processes.

ULTRASONIC OXIDATIVE DESULFURIZATION OF HEAVY FUEL OILS

The invention relates to systems and methods for ultrasonic oxidative desulfurization of heavy fuel oils. In various embodiments, the methods include combinations of ultrasonic sulfone decomposition processes and/or catalytic decomposition processes.

Process and device for hydrogenation of heavy oil using a suspension-bed

A process and device for hydrogenation of heavy oil using a suspension-bed are provided. In the process, a part of a raw oil is mixed with a suspension-bed hydrocracking catalyst to form a first mixture, the first mixture is subjected to first and second shear in sequence so as to realize high dispersion and mixing of the catalyst and the raw oil to obtain a catalyst slurry; through pretreatment of the raw oil, the device can prevent the raw oil from coking in the hydrogenation process; through the adoption of a suspension-bed reactor with a liquid phase self-circulation function or a cold-wall function; and light and heavy components are separated from the suspension-bed hydrogenated product in advance and only medium component is subjected to fixed-bed hydrogenation, thereby greatly reducing the load of the fixed-bed hydrogenation, prolonging the service life of the fixed-bed catalyst, improving the yield and quality of gasoline and diesel, and being beneficial for energy conservation and emission reduction of the system.

DIRECT OXIDATION OF HYDROGEN SULFIDE IN A HYDROPROCESSING RECYLCE GAS STREAM WITH HYDROGEN PURIFICATION
20200353409 · 2020-11-12 ·

A process and system for treating a hydroprocessing unit effluent gas stream for recycling includes introducing the effluent gas stream into a hydrogen purification zone and recovering a hydrogen-rich gas stream and a liquid stream containing a mixture that includes C1 to C4 hydrocarbons and H.sub.2S which is then mixed with an oxidant and fed to an oxidation unit containing catalyst for conversion of the H.sub.2S to elemental sulfur vapors that is separated for recovery of the elemental sulfur, and recovering a sweetened mixture that includes C1 to C4 hydrocarbons. Alternatively, the hydroprocessing unit effluent gas stream containing H.sub.2S is cooled, contacted with a solvent to absorb the C1 to C4 hydrocarbons and H.sub.2S, with the hydrogen-rich stream being recovered for recycling to the hydroprocessing unit, and the rich liquid solvent being flashed to produce a lean solvent stream for recycling to the adsorption zone and a mixed gas stream that includes the C1 to C4 hydrocarbons and H.sub.2S that is passed to an oxidation zone and is reacted with an oxidant in the presence of a catalyst to complete the process as described above for the recovery of elemental sulfur and a mixture that includes the sweetened C1 to C4 hydrocarbons.