C10G69/04

Process for producing light olefins and low-sulfur fuel oil components

A process for producing propylene and a low-sulfur fuel oil component, comprising the steps of: i) contacting a hydrocarbon-containing feedstock oil with a catalytic conversion catalyst for reaction under effective conditions in a catalytic conversion reactor in the absence of hydrogen to obtain a reaction product comprising propylene; ii) separating the reaction product from step i) to obtain a catalytic cracking distillate oil, and iii) subjecting the catalytic cracking distillate oil to hydrodesulfurization to obtain a low-sulfur hydrogenated distillate oil suitable for use as a fuel oil component. The process can greatly improve the propylene selectivity and propylene yield while producing more fuel oil components, significantly reduce the yield of dry gas and coke, and thus has better economic and social benefits.

Process for producing light olefins and low-sulfur fuel oil components

A process for producing propylene and a low-sulfur fuel oil component, comprising the steps of: i) contacting a hydrocarbon-containing feedstock oil with a catalytic conversion catalyst for reaction under effective conditions in a catalytic conversion reactor in the absence of hydrogen to obtain a reaction product comprising propylene; ii) separating the reaction product from step i) to obtain a catalytic cracking distillate oil, and iii) subjecting the catalytic cracking distillate oil to hydrodesulfurization to obtain a low-sulfur hydrogenated distillate oil suitable for use as a fuel oil component. The process can greatly improve the propylene selectivity and propylene yield while producing more fuel oil components, significantly reduce the yield of dry gas and coke, and thus has better economic and social benefits.

PROCESS AND SYSTEM FOR HYDROTREATING DEOILED ASPHALT

Described are a process and a system for hydrotreating a deoiled asphalt. The process includes: (2) introducing a deoiled asphalt and an aromatics-containing stream into a first reaction unit for hydrogenation reaction, wherein the first reaction unit comprises a mineral-rich precursor material and/or a hydrogenation catalyst, and the first reaction unit is a fixed bed hydrogenation unit; (21) fractionating the liquid-phase product from the first reaction unit to provide a first light component and a first heavy component; (31) introducing the first light component into a second reaction unit for reaction, to provide a gasoline component, a diesel component and/or a BTX feedstock component; and (32) introducing the first heavy component to a delayed coking unit for reaction; or using the first heavy component as a low sulfur ship fuel oil component.

PROCESS FOR CONVERSION OF CRUDES AND CONDENSATES TO CHEMICALS UTILIZING A MIX OF HYDROGEN ADDITION AND CARBON REJECTION

Processes herein may be used to thermally crack various hydrocarbon feeds, and may eliminate the refinery altogether while making the crude to chemicals process very flexible in terms of crude. In embodiments herein, crude is progressively separated into light and heavy fractions utilizing convection heat from heaters used in steam cracking. Depending on the quality of the light and heavy fractions, these are routed to one of three upgrading operations, including a fixed bed hydroconversion unit, a fluidized catalytic conversion unit, or a residue hydrocracking unit that may utilize either an ebullated bed reactor with extrudate catalysts or a slurry hydrocracking reactor using a homogeneous catalyst system, such as a molybdenum based catalysts which may optionally be promoted with nickel. Products from the upgrading operations can be finished olefins and/or aromatics, or, for heavier products from the upgrading operations, may be used as feed to the steam cracker.

Conversion process for an inferior oil
11492563 · 2022-11-08 ·

Provided is a conversion process for an inferior oil, relating to the field of biomass utilization, energy and chemical industry. The conversion process is carried out in presence of a catalyst selected from the group consisting of an iron oxide compound, a desulfurization waste agent resulting from use of an iron oxide compound as desulfurizer, and a regeneration product of the desulfurization waste agent, under a controlled molar ratio of iron element to sulfur element. It is found that free radical condensation polymerization of inferior oil during cracking process can be blocked effectively by using carbonylation, and hydrogenation is achieved with active hydrogen produced from the conversion of CO and water. In the conversion process, inferior oil can be, directly converted, thereby increasing liquefaction yield and calorific value of the obtained oils. No large amount of waste water is generated after completion of the conversion.

Conversion process for an inferior oil
11492563 · 2022-11-08 ·

Provided is a conversion process for an inferior oil, relating to the field of biomass utilization, energy and chemical industry. The conversion process is carried out in presence of a catalyst selected from the group consisting of an iron oxide compound, a desulfurization waste agent resulting from use of an iron oxide compound as desulfurizer, and a regeneration product of the desulfurization waste agent, under a controlled molar ratio of iron element to sulfur element. It is found that free radical condensation polymerization of inferior oil during cracking process can be blocked effectively by using carbonylation, and hydrogenation is achieved with active hydrogen produced from the conversion of CO and water. In the conversion process, inferior oil can be, directly converted, thereby increasing liquefaction yield and calorific value of the obtained oils. No large amount of waste water is generated after completion of the conversion.

Method for converting residues incorporating deep hydroconversion steps and a deasphalting step

The invention concerns a method for converting heavy hydrocarbon feedstocks of which at least 50% by weight boils at a temperature of at least 300° C., and in particular vacuum residues. The feedstocks are subjected to a first step a) of deep hydroconversion, optionally followed by a step b) of separating a light fraction, and a heavy residual fraction is obtained from step b) of which at least 80% by weight has a boiling temperature of at least 250° C. Said fraction from step b) or the effluent from step a) is then subjected to a second step c) of deep hydroconversion. The overall hourly space velocity for steps a) to c) is less than 0.1 h.sup.−1. The effluent from step c) is fractionated to separate a light fraction. The heavy fraction obtained, of which 80% by weight boils at a temperature of at least 300° C., is sent to a deasphalting step e). The deasphalted fraction DAO is then preferably converted in a step f) chosen from ebullated bed hydroconversion, fluidised bed catalytic cracking and fixed bed hydrocracking.

Method for converting residues incorporating deep hydroconversion steps and a deasphalting step

The invention concerns a method for converting heavy hydrocarbon feedstocks of which at least 50% by weight boils at a temperature of at least 300° C., and in particular vacuum residues. The feedstocks are subjected to a first step a) of deep hydroconversion, optionally followed by a step b) of separating a light fraction, and a heavy residual fraction is obtained from step b) of which at least 80% by weight has a boiling temperature of at least 250° C. Said fraction from step b) or the effluent from step a) is then subjected to a second step c) of deep hydroconversion. The overall hourly space velocity for steps a) to c) is less than 0.1 h.sup.−1. The effluent from step c) is fractionated to separate a light fraction. The heavy fraction obtained, of which 80% by weight boils at a temperature of at least 300° C., is sent to a deasphalting step e). The deasphalted fraction DAO is then preferably converted in a step f) chosen from ebullated bed hydroconversion, fluidised bed catalytic cracking and fixed bed hydrocracking.

Systems and methods including hydroprocessing and high-severity fluidized catalytic cracking for processing petroleum-based materials

According to at least one aspect of the present disclosure, a method for processing a heavy oil includes introducing the heavy oil to a hydroprocessing unit, the hydroprocessing unit being operable to hydroprocess the heavy oil to form a hydroprocessed effluent by contacting the heavy oil feed with an HDM catalyst, an HDS catalyst, and an HDA catalyst. The hydroprocessed effluent is passed directly to a HS-FCC unit, the HS-FCC unit being operable to crack the hydroprocessed effluent to form a cracked effluent comprising at least one product. The cracked effluent is passed out of the HS-FCC unit. The heavy oil has an API gravity of from 25 degrees to 50 degrees and at least 20 wt. % of the hydroprocessed effluent passed to the HS-FCC unit has a boiling point less than 225 degrees ° C.

Systems and methods including hydroprocessing and high-severity fluidized catalytic cracking for processing petroleum-based materials

According to at least one aspect of the present disclosure, a method for processing a heavy oil includes introducing the heavy oil to a hydroprocessing unit, the hydroprocessing unit being operable to hydroprocess the heavy oil to form a hydroprocessed effluent by contacting the heavy oil feed with an HDM catalyst, an HDS catalyst, and an HDA catalyst. The hydroprocessed effluent is passed directly to a HS-FCC unit, the HS-FCC unit being operable to crack the hydroprocessed effluent to form a cracked effluent comprising at least one product. The cracked effluent is passed out of the HS-FCC unit. The heavy oil has an API gravity of from 25 degrees to 50 degrees and at least 20 wt. % of the hydroprocessed effluent passed to the HS-FCC unit has a boiling point less than 225 degrees ° C.